Materials Science Forum Vol. 1068

Abstract: Polyethylene, elastomer, and date palm fibre are all readily available, it have an positive impact on growth of new composite materials with desirable features and characteristics. There are many different types of composites, but they all have the same goal: to create a new material with greater qualities than the constituent materials. Date palm fibre was employed to reinforce a composite matrix made of polyethylene (PE) plastic and elastomer. To find out the tensile, impact, and bending strength values of composites by weight fractions of 25% (75:25), 35% (65:35), and 45% (55:45), this research set out to find (55:45). Composites with a weight percentage of 25% (75:25) had less Tensile strength (TS) 1.213 MPa, though mixtures with weightage proportion of 45% (55:45) had the maximum TS of 2.613 MPa. The minimum tensile strain value was discovered in composites with a weight fraction of 25% (75:25), while the maximum tensile strain value was identified in composites with weight fraction of 45 percent (0.0067). (55:45). 45 % (45-55) weight ratio mixture had the minimum impact strength of 45321 kJ/mm², while the 25 percent (75-25) weight ratio mixture had the maximum impact strength of 17721.41 kJ/mm². A 25 percent weight fraction (75:25) composite had the lowest bending strength measurement result (1.816 MPa), whereas a 35 percent weight fraction (65:35) composite had the highest measurement result (4.9 MPA) in this category. At 75:25 (75:25), the bending strain of the composite was at its highest, with a value of 0.0216

Abstract: Shape memory alloys (SMAs) are smart materials that have the ability to recover large strain. The shape memory and superelasticity in these alloys is due to stress induced martensitic transformation that strongly depends upon the phase transformation temperatures. These alloys are being investigated for a number of applications due to their remarkable properties such as improved impact and damage resistance, vibration damping, seismic damping, shape morphing and crack closure properties. In this work, these alloys were integrated in fiber reinforced polymers (FRPs) to develop hybrid composite structures that can benefit from both fiber strength and intrinsic properties of SMAs resulting in weight efficient smart materials with better mechanical properties. The experimental investigation on impact performance of nitinol SMAs wire reinforced glass fiber composites (GFRP) showed 18% increase in toughness, as compared to steel wire reinforced glass fiber composites. In this paper, the effect of shape memory alloys wires in composite materials and their targeted applications especially for aerospace industry is presented.

Abstract: This paper introduces the braided helically wrapped yarns with negative Poisson’s ratio (NPR) exhibiting a stable structure and good practicability to avoid slippage of wrapped component from the core. The geometry and auxetic behavior of the braided helical structure for two different combinations of core materials with similar combination of wrap materials and different braiding angles have been analyzed. Two elastomeric materials i.e. Polyurethane (PU) and Polyester, were used as monofilament cores whereas two stiffer multifilament wrap yarns employed were, ultra-high molecular weight polyethylene (UHMWPE) and polyethylene terephthalate (PET). Multiple braided yarns were investigated to analyze materials’ behavior towards NPR. It was observed that the NPR strongly depended on the inherent properties of the core and wrap materials in addition to the braiding angle. The NPR value was higher for a core with relatively higher elasticity (e.g., PU elastomer compared with polyester). It was also noticed that a lower wrap angle and lower braiding speed exhibited higher NPR. The maximum NPR value using PU core wrapped at a low angle of 9° was-1.70, when tested at a low strain rate of 0.5%.

Abstract: Being very strong fibers, carbon nanotubes (CNTs) are excellent choice for various metal matrix composites (MMCs). Many researchers have reported amelioration in mechanical and thermal characteristics of the MMCs driven by CNTs addition. However, the effect of multi-walled carbon nanotubes (MWCNTs) addition on the formability of the MMC is relatively less addressed area. In present study, 0.2 wt. % MWCNTs were added in aluminum matrix using induction melting technique and their effect on the various aspect of metal forming characteristics were studied. Two different type of MMC were prepared i.e., re-melting flux (RM) MMC using re-melting flux and multi-functional flux (MF) MMC using multifunctional flux.The experimental results showed that the MF Flux MMC had ultimate tensile strength 65% more than pure aluminum. An analogous behavior was seen in true stress-true strain characteristics along with necking stress and tensile toughness. Contrarily, the hardening factor, strength coefficient, necking strain and strain rate sensitivity values decreased in case of RM Flux MMC and increased for MF Flux MMC as compare to the pure aluminum. This behavior of the materials could be attributed to the process variation used for the incorporation of nanotubes in aluminum matrix.

Abstract: This study reports the ballistic penetration performance of a composite material composed of woven Kevlar® fabric impregnated with a colloidal shear thickening fluid (STF). STF comprised of Nanosized silica particles suspended in polyethylene glycol. The impregnated Kevlar fabric offers equivalent low velocity ballistic performance, on an areal density basis, to neat Kevlar fabric. Compared to neat Kevlar fabric, however, the STF-impregnated composites require fewer layers of Kevlar, resulting in a more flexible and less bulky body armor material. Possible mechanisms responsible for the enhanced ballistic and stab performance of the STF-Kevlar composite are identified.

Abstract: The objects of the current study will analyze to determine the effect of the let- -down ratios (LDR) with different materials are blended in a specified ratio, the ratio typically up to 100:1 (pure resin to masterbatch). The considered design level for a (masterbatch) depends on the preferred color, pigment loading, and expected processing parameters. Intended experimentations were carried to determine the effects of different processing factors on the same formulations of a red polycarbonate letdown pigment. In addition, historic data for formulation and parameters were collected and analyzed. This research uses design expert software to study the parameter interactions effects. As a result, improve First Pass Color Production and reduce wastages.

Abstract: Kenaf fiber-reinforced beech plywood was evaluated with 5variantmanufacturing adhesive methods in order to increase its acceptance in the wider industrial use. We aimed in enhancing the mechanical characteristics of beech wood kenaf fiber-reinforced using epoxy resin, Urea-formaldehyde, Melamine urea-formaldehyde, isocyanate MDI prepolymer and polyurethane and exhibited diverse effects. Tensile strength, Modulus of Elasticity, Modulus of Rupture, Shear Strength and Screw withdrawal resistance were enhanced by urea formaldehyde, while tensile strength was decreased by Urea Formaldehyde, Melamine Urea-Formaldehyde and isocyanate prepolymer. Epoxy resin, on the other hand, is well suited for kenaf fibre reinforcing. For example, polyurethane reduced the mechanical characteristics of kenaf fibre reinforced beech wood. Shear strength, Modulus of Elasticity and Modulus of Rupture were all superior than glass fibre reinforced epoxy resin bound beech wood.

Abstract: This paper discusses Copper Metal Matrix Composites. It is obvious that copper matrix composites have been heavily relied upon by many industries because of their high wear resistance, corrosion resistance, excellent electrocatalytic properties, and high strength. The excellent electrical conductivity of copper-based materials also enables these materials to function as lubricants and anti-frictional materials. These materials were widely used in transportation, electrical contact transmission, and aerospace. Copper-based metal matrix composites have wide application due to their excellent mechanical, electrical, and thermal characteristics. Copper based metal matrix composites are also corrosion resistant and have a high strength. A contemporary study evaluated the effects of different parameters on powder metallurgy fabricated copper matrix metal composites. The focus was on understanding the applications and mechanical properties of copper-based composite materials.

Abstract: Synthesis and antioxidant assay of 4-phenoxyquinoline derivative namely, (E)-7-chloro-4-(2-methoxy-4-(prop-1-en-1-yl)phenoxy)quinoline, from clove leaf oil have been conducted. This compound can be prepared from eugenol (isolated from clove leaf oil) in either two-step or one-pot synthesis. In two-step synthesis, eugenol was subjected to base-catalyzed-isomerization to give isoeugenol, which in turn underwent aromatic nucleophilic aromatic nucleophilic substitution with 4,7-dichloroquinoline to generate (E)-7-chloro-4-(2-methoxy-4-(prop-1-en-1-yl)phenoxy)quinoline in 57% total yields. By combining these two reactions, the 4-phenoxyquinoline derivative can be furnished in one-pot fashion in 63%. The results showed that the synthesized 4-phenoxyquinoline derivative, however, did not show strong antioxidant activity.

Abstract: Most chemotherapeutic drugs are unable to distinguish between healthy and cancerous cells, resulting in the risk of side effects and drug resistance. There is a continuous effort to find new agents to help bring this disease under control. Compounds with bioactive natural product scaffolds have been of great interest due to their low toxicity and high efficacy. In this study, new naphthalene-based chalcone 1 and pyrazoline 1A compounds were synthesized via a Claisen-Schmidt condensation and cyclo-condensation reaction, respectively. These compounds were characterized using the Fourier Transform Infrared (FT-IR), ¹H, and ¹³C Nuclear Magnetic Resonance (NMR) spectroscopy. The molecular docking activities were performed to study the interactions between these new compounds with breast cancer protein, 3ERT as estrogen receptor-α (ERα). Chalcone 1 and pyrazoline 1A compounds obey Lipinski's rule whereby pyrazoline 1A showed the lowest binding energy of -9.47 kcal/mol, inhibition constant of 113.93 mM and log P of 2.30. Interaction of pyrazoline 1A with 3ERT protein exhibited the hydrogen bonding with GLY521 amino acid, while the hydrophobic interactions were observed with LEU346, LEU384, LEU391, LEU525, LEU387, MET343, ALA350, and MET421 amino acids. Pyrazoline 1A is expected to show promising activities as an anticancer agent.