Conducting Behavior of Bischalcone Derivatives

Abstract:

With the scope of bischalcone-based copolyesters can be used as semiconductors; two copolyesters were synthesized by the solution polycondensation method. The Bischalcone diol was analyzed by UV-Visible, FTIR, NMR (¹H, ¹³C NMR) spectroscopy. Using the UV-Visible data, the bandgap energy of the Bischalcone diol was calculated and found to be 2.82 eV. The Physico-chemical properties like Inherent viscosity and refractive index of the copolyesters were determined. Spectral studies such as FTIR, ¹H and ¹³C NMR spectroscopy. The thermal property of the copolyesters was analyzed by differential scanning calorimetry. The melting temperature of the PTMI is observed at 320°C, and PTMT exhibits 360°C. The PTMT shows higher stability than the PTMT copolyester. The highest ionic conductivity for PTMI is 3.50 x 10^-4 (S cm^-1). The PTMT copolyester shows -0.0035 KJ mol^-1 whereas the PTMI copolyester shows 0.0005 KJ mol^-1. The electrochemical impedance analysis and conductivity measurement were examined for the two copolyesters expecting semi-conducting behavior which can be a good candidate for the optoelectronics application.

• Periodical: Materials Science Forum (Volume 1079)
• Pages: 103-113
• DOI: https://doi.org/10.4028/p-1993t4
• Online since: December 2022
• Authors: R. Aswini*, D. Lakshmi Devi, S. Kothai
• Keywords: Bandgap Energy, Conductivity Behavior, Copolyesters, Polycondensation, Thermal Behavior

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