Study of the Properties of Dust from the Production of Prebaked Anodes for its Use as a Reducing Agent in Silicon Smelting

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Abstract:

The production of metallurgical silicon is carried out in ore-thermal furnaces by reducing silica-containing raw materials with a carbon reducing agent, the most reactive of which is expensive and scarce charcoal. For the purpose of possible partial replacement of charcoal in the charge for silicon smelting, we conducted studies on the properties of carbon-containing technogenic raw materials formed in the process of obtaining pre-fired anodes for aluminium production. The object of research was 2 samples of dust from the mixing and pressing compartment: from the aspiration units and from the cleaning of the shop. The characteristics of these samples (carbon content, granulometric composition, humidity) were determined. To activate these carbon materials, ultrahigh-frequency processing was used at various capacities and durations. When studying the reactivity of the dust samples by the method of heteroelement analysis using the Vario MICRO cube analyzer, it was found that a sample of dust from aspiration plants treated with ultrahigh-frequency radiation at a power of 80 W and a duration of 40 min more actively interacts with oxygen to form CO2, which makes it possible to recommend this carbon-containing technogenic material as a reducing agent for smelting metallurgical silicon.

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Materials Science Forum (Volume 1081)

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167-172

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March 2023

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© 2023 Trans Tech Publications Ltd. All Rights Reserved

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[1] V.M. Sizyakov, A.A. Vlasov and V.Yu. Bazhin, Tsvetnye Metally. 1 (2016) 1-10.

Google Scholar

[2] S.K. Nosov, A.V. Roshchin, V.E. Roshchin and B.P. Chernyakhovskii, Russ. Metall. 2012, 1007-1013.

DOI: 10.1134/s0036029512120099

Google Scholar

[3] C. Ocheri, O.O. Ajani, A. Daniel and N. Agbo, J. Powder Metallurgy & Mining. 6 (2017) 156-160.

Google Scholar

[4] O.A. Romanova and D.V. Sirotin, KnE Materials Science. 5(1) (2019) 15-28.

Google Scholar

[5] S. Tsyb, Metals of Eurasia. 4 (2017) 4-5.

Google Scholar

[6] M.I. Gasik and M.M. Gasik, Electrothermics of silicon (Physics-chemistry and technology), Dnepropetrovsk: National Metallurgical Academy of Ukraine, 2011, р. 487.

Google Scholar

[7] A. Schei, J.Kr.Tuset and H. Tveit, Production of High Silicon Alloys, Trondheim: Tapir Academic Press, 1998, p.363.

Google Scholar

[8] O.M. Katkov, Smelting of technical silicon, Irkutsk: ZAO Kremniy, 1999, р. 244.

Google Scholar

[9] E. Ringdalen and M. Tangstad, The Minerals, Metals & Materials Society (TMS), 2012, pp.195-203.

Google Scholar

[10] R.I. Ragulina and B.I. Emlin, Electrothermics of silicon and silumin, Moscow: Metallurgiya, 1972, р. 239.

Google Scholar

[11] K. Grjotheim and B. Welch, Aluminium Smelter Technology, Dusseldorf: Aluminium-Verlag, 1993, р. 260.

Google Scholar

[12] S. Prasad, J. Braz. Chem. Soc. 11 (2000) 245-251.

Google Scholar

[13] E.A. Yanko, Anodes of Aluminium Electrolyzers, Moskow: Ore and Metals, 2001, р. 672.

Google Scholar

[14] A.A. Tyutrin, N.V. Nemchinova and A.A. Volodkina, Proceedings of Irkutsk State Techn. Univ. 24(4) (2020) 906-918.

Google Scholar

[15] N.V. Nemchinova, A.A. Tyutrin, N.A. Korepina and S.S. Belskii, IOP Conf. Series: Materials Science and Engineering. 411(1) (2018) 012052.

DOI: 10.1088/1757-899x/411/1/012052

Google Scholar

[16] N.V. Nemchinova, Universities' Proceedings, Non-Ferrous Metallurgy. 1 (2006) 4-8.

Google Scholar

[17] A.N. Didenko and B.V. Zverev, Microwave energy, Moscow: Nauka, 2000, р. 264.

Google Scholar

[18] E.A. Zauer, Elemental analysis of organic compounds, Volgograd: VSTU Publ., 2017, р. 128.

Google Scholar

[19] N.V. Nemchinova, M.S. Leonova and A.A. Tyutrin, Proceedings of Irkutsk State Techn. Univ. 21(1) (2017) 209-217.

Google Scholar

[20] N.V. Nemchinova, M.S. Leonova and A.K. Timofeev, Proceedings of Irkutsk State Techn. Univ. 7 (2016) 162-171.

Google Scholar

[21] N.V. Nemchinova, M.S. Leonova, A.A. Tyutrin and S.S. Belskii, Metallurgist. 63 (2019) 115-122.

Google Scholar

[22] N.V. Nemchinova, T.S. Mineeva and A.V. Nikanorov, Modern Problems of Science and Education. 3 (2013) 93.

Google Scholar

[23] L.I. Leontyev and V.G. Dyubanov, Ecology and Industry of Russia. 4 (2011) 32-35.

Google Scholar