Effect of Platinum Oxide in Enhancing EMI Shielding Effectiveness of Silver Doped Polyaniline-Platinum Oxide Composites

Article Preview

Abstract:

In this study, we used green tea extract to prepare Silver-PANI nanocomposites and incorporated varying percentages of platinum oxide through in-situ chemical polymerization. The synthesized Ag-PANI/PtO2 conducting polymer nanocomposites were characterized using FT-IR, XRD, and SEM analysis, which showed uniform incorporation of PtO2 in the nanocomposites. EMI shielding effectiveness results demonstrated that the Ag-PANI/PtO2 (10%) composite effectively shields electromagnetic interference. The EMI SE results showed that PtO2 exhibited good absorption in the range of 2-3 GHz, indicating its conducting behaviour. Additionally, the Ag-PANI/PtO2 (6%) and Ag-PANI/PtO2 (10%) composites demonstrated good absorption in this range, likely due to the proper mixing of platinum oxide and silver-decorated polyaniline within the polymer matrix. Therefore, silver polyaniline decorated conducting polymer composites are a promising material for effectively shielding electromagnetic radiation in electronic devices.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1099)

Pages:

51-59

Citation:

Online since:

October 2023

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2023 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K.Vanitha, K.A Vijayalakshmi, M. Revansidddappa, S.B. Chalvaraju, K.Sadasivam and M. Thirumoorthy "Electrical Conductivity of DC, AC of Polyaniline/NLS FA/Silver Nano Particle with Low Temperature Plasma" Journal of Xidian University, 17(3),446-461, (2023).

Google Scholar

[2] Kadar, C. H. Abdul, Faisal, Muhammad, Maruthi, N, Raghavendra, Narasimha, Prasanna, B. P, Nandan, K. R, Manohara, S. R, Revanasiddappa M, and Madhusudhan, C. K. "Anticorrosive Polypyrrole/Barium Ferrite (PPy/BaFe12O19) Composites with Tunable Electrical Response for Electromagnetic Wave Absorption and Shielding Performance" Journal of Electronic Materials vol. 52, no. 3, p.2080–2093, (2023).

DOI: 10.1007/s11664-022-10179-8

Google Scholar

[3] B.M. Basavaraja Patel, M. Revanasiddappa, S. Yallappa1, and D. R. Rangaswamy, "Iron nanoparticles embedded in polypyrrole and tellurium oxide ternary nanocomposites for electrical conductivity and electromagnetic interference shielding" J Mater Sci: Mater Electron, 34, 1-16, (2023).

DOI: 10.1007/s10854-023-10298-w

Google Scholar

[4] Reka. U, Sonima Mohan, M. Revanasiddappa, Mini Vellakkat, "Conducting polymer/transition metal carbide nanocomposite treated graphite felt as positive electrode in all-vanadium redox flow battery" Synthetic Metals, Volume 294,(2023).

DOI: 10.1016/j.synthmet.2023.117311

Google Scholar

[5] Basavaraja Patel B M, Revanasiddappa M, Rangaswamy D R, Manjunatha S and Ravikiran Y T, "Synthesis characterization DC conductivity and EMI shielding studies of Iron-decorated Polypyrrole-fly ash nanocomposites" Materials Today proceedings Volume 49, Part 5, P 2253-2259, (2022).

DOI: 10.1016/j.matpr.2021.09.337

Google Scholar

[6] B M Basavaraja Patel, M Revanasiddappa, D R Rangaswamy , S Manjunatha, Y T Ravikiran "DC conductivity studies of iron decorated polypyrrole" J. Phys.: Conf. Ser. 2070, 012070, (2021).

DOI: 10.1088/1742-6596/2070/1/012070

Google Scholar

[7] N. Maruthi, Muhammad Faisal, Narasimha Raghavendra, B.P. Prasanna, S. R. Manohara, and M. Revanasiddappa "Promising EMI shielding effectiveness and anticorrosive properties of PANI-Nb2O5 nanocomposites: Multifunctional approach" Synthetic Metals Volume 275, (2021).

DOI: 10.1016/j.synthmet.2021.116744

Google Scholar

[8] N. Maruthi, Muhammad Faisal, Narasimha Raghavendra, B.P. Prasanna, S. R. Manohara, M. Revanasiddappa, "Anticorrosive polyaniline-coated copper oxide (PANI/CuO) nanocomposites with tunable electrical properties for broadband electromagnetic interference shielding" Colloids and Surfaces A: Physicochemical and Engineering Aspects, 621, (2021).

DOI: 10.1016/j.colsurfa.2021.126611

Google Scholar

[9] A. Sunilkumar, S. Manjunatha, Y. T. Ravikiran, M. Revanasiddappa, M. Prashantkumar and T. Machappa "AC conductivity and dielectric studies in polypyrrole wrapped tungsten disulphide composites" Polym. Bull. (2021).

DOI: 10.1007/s00289-021-03552-w

Google Scholar

[10] C.C. Inagaki, M.M. Oliveira, A.J.G. Zarbin, Direct and one-step synthesis of polythiophene/gold nanoparticles films through liquid/liquid interfacial polymerization. Colloid Interface Sci.516,498-510, (2018).

DOI: 10.1016/j.jcis.2018.01.076

Google Scholar

[11] A.T. Mthew, K.B. Akshaya, T.P. Vinod, A. Varghese, L. George, TEMPO-mediated aqueous phase electrooxidation of pyridyl methanol at palladium-decorated PANI on carbon fibre paper electrode. Chem.Select,5,3283-3294, (2020).

DOI: 10.1002/slct.201904432

Google Scholar

[12] N. Bouzayen, H. Sadki, M. Mbarek et al., "Synthesis, characterization, DFT and TD-DFT studies of novel carbazolebased copolymer used in high efficient dye-sensitized solar cells," Polymer Testing, vol. 66, pp.78-86, (2018).

DOI: 10.1016/j.polymertesting.2017.12.023

Google Scholar

[13] Y. Cai, X. Xue, G. Han et al., "Novel π-conjugated polymer based on an extended thienoquinoid," Chemistry of Materials, vol. 30, no. 2, pp.319-323, (2018).

Google Scholar

[14] D. Keles, M.C. Erer, E. Bolayir et al., "Conjugated polymers with benzothiadiazole and benzotriazole moieties for polymer solar cells," Renewable Energy, vol. 139, pp.1184-1193, (2019).

DOI: 10.1016/j.renene.2019.03.018

Google Scholar

[15] Z.M.E. Fahim, S.M. Bouzzine, Y. Ait Aicha, M. Bouachrine, and M. Hamidi, "The bridged effect on the geometric, optoelectronic and charge transfer properties of the triphenylamine–bithiophene-based dyes: a DFT study," Research on Chemical Intermediates, vol. 44, no. 3, pp.2009-2023, (2018).

DOI: 10.1007/s11164-017-3211-1

Google Scholar

[16] R. Megha, Y.T. Ravikiran, S.C. Vijaya Kumari, S. Thomas, Influence of n-type nickel ferrite in enhancing the AC conductivity of optimized polyaniline-nickel ferrite nanocomposite, Appl. Phys. A 123, 245 (2017).

DOI: 10.1007/s00339-017-0866-9

Google Scholar

[17] S. Manjunatha, T. Machappa, A. Sunilkumar, Y.T. Ravikiran, Tungsten disulfide: An efficient material in enhancement of AC conductivity and dielectric properties of polyaniline, J. Mater. Sci. 29, 11581 (2018)

DOI: 10.1007/s10854-018-9255-1

Google Scholar

[18] R. Megha, Y.T. Ravikiran, S.C.V. Kumari, H.G.R. Prakash, CH.V.V. Ramana, S. Thomas, Compos. Interfaces 26, 309 (2019)

Google Scholar

[19] K.S. Siddiqi and A. Husen, Green synthesis, characterization and uses of Palladium/Platinum nanoparticles, Nanoscale research letters 11,482 (2016).

DOI: 10.1186/s11671-016-1695-z

Google Scholar

[20] Koohpeima F, Mokhtarai M J and Khalafi S, The effect of silver nanoparticles on composite shear bond strength to dentin with different adhesion protocols, J Appl Oral Sci,25(4),367-73 (2017)

DOI: 10.1590/1678-7757-2016-0391

Google Scholar

[21] M.K. Nasrabadi, A.E. Moghadam, R. Kumar and N. Nabipour, Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes, International Journal of Chemical Engineering V-2021, 8 pages Article ID 8894768, (2021).

DOI: 10.1155/2021/8894768

Google Scholar

[22] G.C. Marjanovic, Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications, Synth. Met. 177, 1 (2013).

Google Scholar

[23] M. Rahaman, T.K. Chaki, D. Khastgir, Development of high-performance EMI shielding material from EVA, NBR, and their blends: effect of carbon black structure, J Mater Sci, 46, 3989-3999, (2011).

DOI: 10.1007/s10853-011-5326-x

Google Scholar

[24] A. Ahmed. A. Ghamdi, A. Omar, A. Hartomy, R. Falleh, A. Solamy, T. Nikolay. Dishovsky, P. Malinova, Atanasov, L. Gabriela, Correlation between Electrical Conductivity and Microwave Shielding Effectiveness of Natural Rubber Based Composites, Containing Different Hybrid Fillers Obtained by Impregnation Technology, Materials Sciences and Applications, 7, 496-509, (2016).

DOI: 10.4236/msa.2016.79043

Google Scholar