Improvement of the Polyvinilydene Fluoride Membrane by Incorporating of Cellulose Nanocrystals as Modifying Agent

Article Preview

Abstract:

Modification of polymer solution with various additive is generally conducted to improve the membrane performance. In this study, we investigate the modification of Polyvinylidene fluoride (PVDF) membranes by addition of cellulose nanocrystals (CNC) into polymer solution. The effect of the addition of 0.5 wt% of CNC was studied in detail on the membrane structure, water content, and its filtration performance. The water content of the modified PVDF membrane with CMCs was higher than that of the pristine PVDF membrane. Pure water flux shows a similar trend with the addition of 0.5wt% CNC, which correlates with the results of porosity and membrane swelling tests. The increase in water content, permeability, porosity, and swelling indicates an improvement in the antifouling properties of the membrane. This research provides insight that the addition of CNC enhances the performance of PVDF polymer membranes for use in water treatment.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1136)

Pages:

61-68

Citation:

Online since:

December 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Tang, Y. Lin, W. Ma, and X. Wang, "A review on microporous polyvinylidene fluoride membranes fabricated via thermally induced phase separation for MF/UF application," J. Memb. Sci., vol. 639, no. August, p.119759, 2021.

DOI: 10.1016/j.memsci.2021.119759

Google Scholar

[2] H. Nawaz, M. Umar, A. Ullah, H. Razzaq, K. M. Zia, and X. Liu, "Polyvinylidene fluoride nanocomposite super hydrophilic membrane integrated with Polyaniline-Graphene oxide nano fillers for treatment of textile effluents," J. Hazard. Mater., vol. 403, no. February 2020, p.123587, 2021.

DOI: 10.1016/j.jhazmat.2020.123587

Google Scholar

[3] F. Liu, M. R. M. Abed, and K. Li, "Preparation and characterization of poly(vinylidene fluoride) (PVDF) based ultrafiltration membranes using nano γ-Al2O3," J. Memb. Sci., vol. 366, no. 1–2, p.97–103, 2011.

DOI: 10.1016/j.memsci.2010.09.044

Google Scholar

[4] P. Boruah, R. Gupta, and V. Katiyar, "Fabrication of cellulose nanocrystal (CNC) from waste paper for developing antifouling and high-performance polyvinylidene fluoride (PVDF) membrane for water purification," Carbohydr. Polym. Technol. Appl., vol. 5, Jun. 2023.

DOI: 10.1016/j.carpta.2023.100309

Google Scholar

[5] E. Yuliwati and A. F. Ismail, "Effect of additives concentration on the surface properties and performance of PVDF ultrafiltration membranes for refinery produced wastewater treatment," Desalination, vol. 273, no. 1, p.226–234, 2011.

DOI: 10.1016/j.desal.2010.11.023

Google Scholar

[6] J. E. Lee, Y. E. Shin, G. H. Lee, J. Kim, H. Ko, and H. G. Chae, "Polyvinylidene fluoride (PVDF)/cellulose nanocrystal (CNC) nanocomposite fiber and triboelectric textile sensors," Compos. Part B Eng., vol. 223, no. May, p.109098, 2021.

DOI: 10.1016/j.compositesb.2021.109098

Google Scholar

[7] A. K. Sari et al., "Effect of acid treatments on thermal properties of bacterial cellulose produced from cassava liquid waste," Mater. Today Proc., vol. 57, p.1174–1178, 2022.

DOI: 10.1016/j.matpr.2021.10.130

Google Scholar

[8] A. Karimian et al., "Nanocrystalline cellulose: Preparation, physicochemical properties, and applications in drug delivery systems," Int. J. Biol. Macromol., vol. 133, p.850–859, 2019.

DOI: 10.1016/j.ijbiomac.2019.04.117

Google Scholar

[9] K. K. Sadasivuni, D. Ponnamma, H. U. Ko, H. C. Kim, L. Zhai, and J. Kim, "Flexible NO2 sensors from renewable cellulose nanocrystals/iron oxide composites," Sensors Actuators, B Chem., vol. 233, no. 2, p.633–638, 2016.

DOI: 10.1016/j.snb.2016.04.134

Google Scholar

[10] A. Santamaria-Echart, L. Ugarte, C. García-Astrain, A. Arbelaiz, M. A. Corcuera, and A. Eceiza, "Cellulose nanocrystals reinforced environmentally-friendly waterborne polyurethane nanocomposites," Carbohydr. Polym., vol. 151, p.1203–1209, 2016.

DOI: 10.1016/j.carbpol.2016.06.069

Google Scholar

[11] C. Gomri, M. Cretin, and M. Semsarilar, "Recent progress on chemical modification of cellulose nanocrystal (CNC) and its application in nanocomposite films and membranes-A comprehensive review," Carbohydr. Polym., vol. 294, Oct. 2022.

DOI: 10.1016/j.carbpol.2022.119790

Google Scholar

[12] L. Bai, A. Ding, G. Li, and H. Liang, "Application of cellulose nanocrystals in water treatment membranes: A review," Chemosphere, vol. 308. Elsevier Ltd, Dec. 2022.

DOI: 10.1016/j.chemosphere.2022.136426

Google Scholar

[13] X. Zhang, H. Li, M. Ye, H. Zhang, G. Wang, and Y. Zhang, "Bacterial cellulose hybrid membrane grafted with high ratio of adipic dihydrazide for highly efficient and selective recovery of gold from e-waste," Sep. Purif. Technol., vol. 292, Jul. 2022.

DOI: 10.1016/j.seppur.2022.121021

Google Scholar

[14] M. M. Aji, S. Narendren, M. K. Purkait, and V. Katiyar, "Biopolymer (gum arabic) incorporation in waste polyvinylchloride membrane for the enhancement of hydrophilicity and natural organic matter removal in water," J. Water Process Eng., vol. 38, no. June, p.101569, 2020.

DOI: 10.1016/j.jwpe.2020.101569

Google Scholar

[15] W. Y. Bang et al., "Influence of cellulose nanocrystal addition on the production and characterization of bacterial nanocellulose," Int. J. Biol. Macromol., vol. 193, p.269–275, Dec. 2021.

DOI: 10.1016/j.ijbiomac.2021.10.092

Google Scholar

[16] W. Deng and Y. Li, "Novel superhydrophilic antifouling PVDF-BiOCl nanocomposite membranes fabricated via a modified blending-phase inversion method," Sep. Purif. Technol., vol. 254, Jan. 2021.

DOI: 10.1016/j.seppur.2020.117656

Google Scholar

[17] D. Zhang et al., "Fabrication of antifouling and antibacterial polyethersulfone (PES)/cellulose nanocrystals (CNC) nanocomposite membranes," J. Memb. Sci., vol. 549, no. November 2017, p.350–356, 2018.

DOI: 10.1016/j.memsci.2017.12.034

Google Scholar

[18] P. Shrestha, M. B. Sadiq, and A. K. Anal, "Development of antibacterial biocomposites reinforced with cellulose nanocrystals derived from banana pseudostem," Carbohydr. Polym. Technol. Appl., vol. 2, p.100112, 2021.

DOI: 10.1016/j.carpta.2021.100112

Google Scholar

[19] M. Kadhom and B. Deng, "Thin film nanocomposite membranes filled with bentonite nanoparticles for brackish water desalination: A novel water uptake concept," Microporous Mesoporous Mater., vol. 279, no. November 2018, p.82–91, 2019.

DOI: 10.1016/j.micromeso.2018.12.020

Google Scholar