Suitability of Novel Titanium Powder for Metal Injection Moulding Application

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Abstract:

A new technology of titanium metal powder production by means of two stages reduction of titanium dioxide, using magnesium and calcium, has been developed and patented by VELTA, Ukraine. In addition to the grades of pure metal titanium, the proposed technological scheme makes it possible to obtain various titanium alloys powders by joint reduction of titanium dioxide with oxides of alloying elements. The powder consists of compact particles with a low content of interstitial elements oxygen, nitrogen and carbon under the levels of standard for Ti Grade 1. A particle size measurement shows a broad distribution with D50 near 50 µm with a large number of very fine, almost spherical particles under 2 µm. A classification of the produced powder by a relatively cheap sieving technology into fractions makes it suitable for different powder metallurgical applications, particularly in Metal Injection Moulding (MIM) technology. The fraction of the powder under 45 µm (35 wt.% of the product) has been tested for MIM technology. Two types of feedstock (catalytic and water-soluble) were used in the study. Sintered samples comply with Ti-400 standard for MIM components used in medical, chemical, aerospace and other industries.

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Materials Science Forum (Volume 1146)

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83-91

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March 2025

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© 2025 Trans Tech Publications Ltd. All Rights Reserved

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[1] Titanium Powder for Additive Manufacturing in 2023, A Custom Research Study, 3DR Holdings, (2024)

Google Scholar

[2] Dr Q (Y.H. Chiou), A year of change: Turbulence in China's MIM industry as markets evolve, PIM International, 18 (2024), 1, 69-77

Google Scholar

[3] X. Goso and A. Kale, Production of titanium metal powder by the HDH process, Journal of the South African Institute of Mining and Metallurgy 111.3 (2011), 203-210

Google Scholar

[4] Ryohei Kumagae et al., Study on the Operation Practice of Plasma Rotating Electrode Process (PREP), Journal of the Japan Society of Powder and Powder Metallurgy, 43 (1996), 7, 907-912

DOI: 10.2497/jjspm.43.907

Google Scholar

[5] P.G. Tsantrizos, F. Allaire, M. Entezarian, U.S. Patent 5,707,419 (1998)

Google Scholar

[6] S. Pleier et al., EIGA - An innovative production method for metal powder from reactive and refractory alloys, In: International conference, Powder metallurgy and particulate materials, 2004. 2-49

Google Scholar

[7] M. Hohmann and S. Pleier, Production methods and applications for high-quality metal powders and sprayformed products, Acta Metall. Sinica, 18 (2005), 1, 15–23

Google Scholar

[8] M. Entezarian et al., Plasma atomization: A new process for the production of fine, spherical powders, Jom 48 (1996), 53-55

DOI: 10.1007/bf03222969

Google Scholar

[9] W. Kroll, Patent DE674625C (1939)

Google Scholar

[10] Chunxiang Cui et al., Titanium alloy production technology, market prospects and industry development, Materials & Design, 32 (2011), 3, 1684-1691

DOI: 10.1016/j.matdes.2010.09.011

Google Scholar

[11] A. Gonchar et al., Development of a technology to produce titanium powder with a low carbon footprint, Eastern-European Journal of Enterprise Technologies, 122 (2023), 12, 42–54

DOI: 10.15587/1729-4061.2023.276746

Google Scholar

[12] A. Brodskyy et al., U.S. Patent 11,440,096 (2022)

Google Scholar

[13] A. Brodskyy et al., Patent of Ukraine No. 127000 (2023)

Google Scholar

[14] R. Vert et al., Induction plasma technology applied to powder manufacturing: Example of titanium-based materials, Key Engineering Materials 704 (2016), 282-286

DOI: 10.4028/www.scientific.net/kem.704.282

Google Scholar

[15] Jun-ll Song et al., Compaction behavior of bimodal iron nanopowder agglomerate, Powder technology, 338 (2018), 333-341.

DOI: 10.1016/j.powtec.2018.06.041

Google Scholar

[16] H. Zhang et al., Improving an easy-to-debind PEG/PPC/PMMA-based binder, Polymer, 262 (2022), 125465

DOI: 10.1016/j.polymer.2022.125465

Google Scholar

[17] M.D. Hayat et al., Modification of PEG/PMMA binder by PVP for titanium metal injection moulding, Powder technology, 315 (2017), 243-249

DOI: 10.1016/j.powtec.2017.04.004

Google Scholar

[18] S. Guo et al., Powder Injection Moulding of Pure Titanium, Rare Met., 28 (2009), 261-265.

Google Scholar

[19] Hayat M. D. et al., A novel PEG/PMMA based binder composition for void-free metal injection moulding of Ti components, Powder technology 382 (2021), 431-440

DOI: 10.1016/j.powtec.2021.01.009

Google Scholar

[20] A. Dehghan-Manshadi et al., Metal injection moulding of titanium and titanium alloys: Challenges and recent development, Powder Technology, 319 (2017), 289–301

DOI: 10.1016/j.powtec.2017.06.053

Google Scholar

[21] Zhao, D. et al, Trace Carbon in Biomedical Beta-Titanium Alloys: Recent Progress, JOM, 67 (2015), 2236–2243

DOI: 10.1007/s11837-015-1590-6

Google Scholar