Enrichment of Rare Earth Elements and Noble Metals in Thermal Treatment Residues of Different Base Materials – A Review

Article Preview

Abstract:

Rare Earth Elements (REEs) and Noble Metals (NMs) are critical resources in modern technologies, including electronics, renewable energy systems, and advanced materials. Even though REEs are moderately abundant in the Earth’s crust, their inhomogeneous distribution and difficult extraction procedures represent serious technical and environmental challenges. The increasing demand for these materials and the environmental problems associated with their primary extraction have led to an intensive search for sustainable recovery methods from secondary sources, such as contaminated biomass, electronic waste (e-waste), and mining residues. This overview article provides a critical analysis of the literature on the enrichment and recovery of REEs and NMs from secondary sources, with a special focus on thermal treatment technologies, including combustion, pyrolysis, and gasification. These technologies transform waste materials into solid residues enriched in valuable metals, which can be extracted more efficiently. The existing recovery methods are presented in terms of efficiency, environmental friendliness, and economic viability, and the main knowledge gaps are also discussed.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1197)

Pages:

73-84

Citation:

Online since:

July 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. Jha, U.S.V. Sanskrit, and B.K. Dubey, "Recovery of Precious Metals and Rare Earth Elements from e-Waste," in Waste-to-Wealth: Resource Recovery and Value-Added Products for Sustainable Development, CRC Press, 2024, pp.282-292.

DOI: 10.1201/9781003327646-19

Google Scholar

[2] J. Yadav et al., "Greening the supply chain: Sustainable approaches for rare earth element recovery from neodymium iron boron magnet waste," J Environ Chem Eng, vol. 12, no. 4, Aug. 2024.

DOI: 10.1016/j.jece.2024.113169

Google Scholar

[3] V. Balaram, "Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact," Geoscience Frontiers, vol. 10, no. 4, p.1285–1303, Jul. 2019.

DOI: 10.1016/j.gsf.2018.12.005

Google Scholar

[4] T. Dinh, Z. Dobo, and H. Kovacs, "Phytomining of noble metals – A review," Jan. 01, 2022, Elsevier Ltd.

DOI: 10.1016/j.chemosphere.2021.131805

Google Scholar

[5] T. Dutta et al., "Global demand for rare earth resources and strategies for green mining," Oct. 01, 2016, Academic Press Inc.

DOI: 10.1016/j.envres.2016.05.052

Google Scholar

[6] K. Binnemans et al., "Recycling of rare earths: A critical review," Jul. 15, 2013, Elsevier Ltd.

DOI: 10.1016/j.jclepro.2012.12.037

Google Scholar

[7] E. O. Opare, E. Struhs, and A. Mirkouei, "A comparative state-of-technology review and future directions for rare earth element separation," Jun. 01, 2021, Elsevier Ltd.

DOI: 10.1016/j.rser.2021.110917

Google Scholar

[8] M. Moghimi Dehkordi, Z. Pournuroz Nodeh, K. Soleimani Dehkordi, H. salmanvandi, R. Rasouli Khorjestan, and M. Ghaffarzadeh, "Soil, air, and water pollution from mining and industrial activities: Sources of pollution, environmental impacts, and prevention and control methods," Sep. 01, 2024, Elsevier B.V.

DOI: 10.1016/j.rineng.2024.102729

Google Scholar

[9] T. Dinh, Z. Dobo, and H. Kovacs, "Phytomining of rare earth elements – A review," Jun. 01, 2022, Elsevier Ltd.

DOI: 10.1016/j.chemosphere.2022.134259

Google Scholar

[10] H. Bogorodytska, S. Voitov, and I. Petrenko, "analyze of modern commodity market for jewelry," Business Navigator, no. 1(68), 2022.

DOI: 10.32847/business-navigator.68-1

Google Scholar

[11] M. Balcerzak, "Quantification of noble metals in biological and environmental samples," in Handbook of Trace Analysis: Fundamentals and Applications, Springer International Publishing, 2016, p.371–402.

DOI: 10.1007/978-3-319-19614-5_13

Google Scholar

[12] D. R. Wilburn and D. I. Bleiwas, "Platinum-Group Metals-World Supply and Demand".

Google Scholar

[13] M. M. Nkiawete and R. L. Vander Wal, "Rare earth elements: Sector allocations and supply chain considerations," Journal of Rare Earths, Feb. 2024.

DOI: 10.1016/j.jre.2024.01.020

Google Scholar

[14] M. Mcglone Mike Mcglone, "Precious Metals, Gold, and Emerging Markets," 2015. [Online]. Available: www.iijournals.com

Google Scholar

[15] J. Burlakovs et al., "Platinum group elements in geosphere and anthroposphere: Interplay among the global reserves, urban ores, markets and circular economy," Jun. 01, 2020, MDPI AG.

DOI: 10.3390/min10060558

Google Scholar

[16] H. U. Sverdrup and K. V. Ragnarsdottir, "A system dynamics model for platinum group metal supply, market price, depletion of extractable amounts, ore grade, recycling and stocks-in-use," Resour Conserv Recycl, vol. 114, p.130–152, Nov. 2016.

DOI: 10.1016/j.resconrec.2016.07.011

Google Scholar

[17] G. Gaustad, E. Williams, and A. Leader, "Rare earth metals from secondary sources: Review of potential supply from waste and byproducts," Apr. 01, 2021, Elsevier B.V.

DOI: 10.1016/j.resconrec.2020.105213

Google Scholar

[18] A. Yuksekdag, B. Kose-Mutlu, B. Kaya, M. Kumral, M. R. Wiesner, and I. Koyuncu, "Comprehensive characterization of secondary sources originating from Turkey in terms of rare earth elements and scandium," Science of the Total Environment, vol. 777, Jul. 2021.

DOI: 10.1016/j.scitotenv.2021.146033

Google Scholar

[19] T. Dinh, Z. Dobó, and H. Kovács, "Enrichment of rare earth elements from contaminated biomass before extraction," Analecta Technica Szegedinensia, vol. 16, no. 1, p.77–82, Aug. 2022.

DOI: 10.14232/analecta.2022.1.77-82

Google Scholar

[20] R. K. Jyothi, T. Thenepalli, J. W. Ahn, P. K. Parhi, K. W. Chung, and J. Y. Lee, "Review of rare earth elements recovery from secondary resources for clean energy technologies: Grand opportunities to create wealth from waste," Sep. 10, 2020, Elsevier Ltd.

DOI: 10.1016/j.jclepro.2020.122048

Google Scholar

[21] M. K. Jha, A. Kumari, R. Panda, J. Rajesh Kumar, K. Yoo, and J. Y. Lee, "Review on hydrometallurgical recovery of rare earth metals," Hydrometallurgy, vol. 161, p.77–101, May 2016.

DOI: 10.1016/j.hydromet.2016.01.003

Google Scholar

[22] S. K. Sarker, S. Sultana, N. Haque, A. E. Hughes, W. Bruckard, and B. K. Pramanik, "Rare earth elements recovery from secondary sources," in Environmental Technologies to Treat Rare Earth Element Pollution: Principles and Engineering, IWA Publishing, 2022, p.117–129.

DOI: 10.2166/9781789062236_0117

Google Scholar

[23] T. Dinh, H. Kovács, and Z. Dobó, "The fate of noble metals and rare earth elements during pelletized biomass combustion," Heliyon, vol. 10, no. 3, Feb. 2024, doi: 10.1016/j.heliyon. 2023.e23546.

DOI: 10.1016/j.heliyon.2023.e23546

Google Scholar

[24] T. Dinh Phi, Z. Dobó, and H. Kovács, "Elemental Analysis of Contaminated Biomass Ashes for Phytomining of Rare Earth Elements," Analecta Technica Szegedinensia, vol. 17, no. 3, p.26–32, Jul. 2023.

DOI: 10.14232/analecta.2023.3.26-32

Google Scholar

[25] D. Koutsonikolas et al., "Membrane and Electrochemical Based Technologies for the Decontamination of Exploitable Streams Produced by Thermochemical Processing of Contaminated Biomass," Apr. 01, 2022, MDPI.

DOI: 10.3390/en15072683

Google Scholar

[26] Z. Han, Z. Guo, Y. Zhang, X. Xiao, and C. Peng, "Metals recovery from biomass," 2018.

Google Scholar

[27] I. A. Adegoke, A. R. Ige, O. R. Adejoba, D. A. Aruwajoye, and J. James, "Roles of Biomass in the Absorption of Heavy Metals," European Journal of Energy Research, vol. 2, no. 2, p.9–13, Apr. 2022.

DOI: 10.24018/ejenergy.2022.2.2.47

Google Scholar

[28] H. Kovacs, "Extraction of noble metals and rare earth elements using plants," Dec. 01, 2025, Elsevier Ltd.

DOI: 10.1016/j.coche.2025.101192

Google Scholar

[29] S. S. V. Vuppaladadiyam, B. S. Thomas, C. Kundu, A. K. Vuppaladadiyam, H. Duan, and S. Bhattacharya, "Can e-waste recycling provide a solution to the scarcity of rare earth metals? An overview of e-waste recycling methods," May 10, 2024, Elsevier B.V.

DOI: 10.1016/j.scitotenv.2024.171453

Google Scholar

[30] A. Gonzalez Baez, L. Pantoja Muñoz, H. Garelick, and D. Purchase, "Characterization of industrially pre-treated waste printed circuit boards for the potential recovery of rare earth elements," Environ Technol Innov, vol. 27, Aug. 2022.

DOI: 10.1016/j.eti.2022.102481

Google Scholar

[31] B. Liang et al., "A Review of the Occurrence and Recovery of Rare Earth Elements from Electronic Waste," Oct. 01, 2024.

DOI: 10.3390/molecules29194624

Google Scholar

[32] Y. Sagrillo Pimassoni, M. T. Weitzel Dias Carneiro Lima, L. H. Yamane, and R. Ribeiro Siman, "The recovery of rare earth elements from waste electrical and electronic equipment: A review," Oct. 01, 2023, Elsevier B.V.

DOI: 10.1016/j.hydromet.2023.106156

Google Scholar

[33] E. S. Moran, P. Shrotriya, and B. Chang, "Rare-earth elements recovery from electronic waste."

Google Scholar

[34] V. Balaram, "Potential Future Alternative Resources for Rare Earth Elements: Opportunities and Challenges," Mar. 01, 2023, MDPI.

DOI: 10.3390/min13030425

Google Scholar

[35] S. Zhang, X. He, Y. Ding, Z. Shi, and B. Wu, "Supply and demand of platinum group metals and strategies for sustainable management," Oct. 01, 2024, Elsevier Ltd.

DOI: 10.1016/j.rser.2024.114821

Google Scholar

[36] Y. Yang, W. Liu, X. Weng, Z. Chen, G. Owens, and Z. Chen, "Highly selective recovery of rare earth elements from mining wastewater using phyto-synthesized biochar dispersed iron nanoparticles," Sep Purif Technol, vol. 353, Jan. 2025.

DOI: 10.1016/j.seppur.2024.128491

Google Scholar

[37] X. Xu, Z. Zhang, X. Weng, and Z. Chen, "What are the different biomolecules involved in the selective recovery of REEs from mining wastewater using FeNPs synthesized from two plant extracts?" Science of the Total Environment, vol. 947, Oct. 2024.

DOI: 10.1016/j.scitotenv.2024.174571

Google Scholar

[38] P. H. N. Vo et al., "Biomining for sustainable recovery of rare earth elements from mining waste: A comprehensive review," Jan. 15, 2024, Elsevier B.V.

DOI: 10.1016/j.scitotenv.2023.168210

Google Scholar

[39] N. Dushyantha et al., "Recovery Potential of Rare Earth Elements (REEs) from the Gem Mining Waste of Sri Lanka: A Case Study for Mine Waste Management," Minerals, vol. 12, no. 11, Nov. 2022.

DOI: 10.3390/min12111411

Google Scholar

[40] M. Jouini et al., "Sustainable Production of Rare Earth Elements from Mine Waste and Geoethics," Jul. 01, 2022, MDPI.

DOI: 10.3390/min12070809

Google Scholar

[41] B. Qin et al., "Vacuum pyrolysis method for reclamation of rare earth elements from hyperaccumulator Dicranopteris dichotoma grown in contaminated soil," J Clean Prod, vol. 229, p.480–488, Aug. 2019.

DOI: 10.1016/j.jclepro.2019.05.031

Google Scholar

[42] Ž. Kamberović et al., "Hydrometallurgical process for selective metals recovery from waste-printed circuit boards," Metals (Basel), vol. 8, no. 6, Jun. 2018.

DOI: 10.3390/met8060441

Google Scholar

[43] Y. Chai et al., "Valorization of heavy metal contaminated biomass: Recycling and expanding to functional materials," Sep. 15, 2022, Elsevier Ltd.

DOI: 10.1016/j.jclepro.2022.132771

Google Scholar

[44] A. Tuncuk, V. Stazi, A. Akcil, E. Y. Yazici, and H. Deveci, "Aqueous metal recovery techniques from e-scrap: Hydrometallurgy in recycling," Miner Eng, vol. 25, no. 1, p.28–37, Jan. 2012.

DOI: 10.1016/j.mineng.2011.09.019

Google Scholar

[45] H. Wang, "Noble metals," in Membrane-Based Separations in Metallurgy: Principles and Applications, Elsevier, 2017, p.249–272.

DOI: 10.1016/B978-0-12-803410-1.00009-8

Google Scholar

[46] M. Wang, Q. Tan, J. F. Chiang, and J. Li, "Recovery of rare and precious metals from urban mines—A review," Front Environ Sci Eng, vol. 11, no. 5, Oct. 2017.

DOI: 10.1007/s11783-017-0963-1

Google Scholar

[47] L. O. Quinones, J. D. Forero, and G. V. Ochoa, "A summary of the literature on leaching: contributions and tendencies," Contemporary Engineering Sciences, vol. 11, no. 63, p.3101–3108, 2018.

DOI: 10.12988/ces.2018.87313

Google Scholar

[48] L. Lombardi, E. Carnevale, and A. Corti, "A review of technologies and performances of thermal treatment systems for energy recovery from waste," Waste Management, vol. 37, p.26–44, Mar. 2015.

DOI: 10.1016/j.wasman.2014.11.010

Google Scholar

[49] D. Lindberg, C. Molin, and M. Hupa, "Thermal treatment of solid residues from WtE units: A review," Waste Management, vol. 37, p.82–94, Mar. 2015, doi:10.1016/j.wasman. 2014.12.009.

DOI: 10.1016/j.wasman.2014.12.009

Google Scholar

[50] E. G. Polyakov and A. S. Sibilev, "Recycling Rare-Earth-Metal Wastes by Pyrometallurgical Methods," Metallurgist, vol. 59, no. 5–6, p.368–373, Sep. 2015.

DOI: 10.1007/s11015-015-0111-8

Google Scholar

[51] J. Shanthi Bhavan, J. Joy, and A. Pazhani, "Identification and recovery of rare earth elements from electronic waste: Material characterization and recovery strategies," Mater Today Commun, vol. 36, Aug. 2023.

DOI: 10.1016/j.mtcomm.2023.106921

Google Scholar

[52] M. Danouche et al., "Advances in bio/chemical approaches for sustainable recycling and recovery of rare earth elements from secondary resources," Feb. 20, 2024, Elsevier B.V.

DOI: 10.1016/j.scitotenv.2023.168811

Google Scholar

[53] Y. Singh, "Society of Earth Scientists Series."

Google Scholar

[54] A. H. Alaedini, H. K. Tourani, and M. Saidi, "A review of waste-to-hydrogen conversion technologies for solid oxide fuel cell (SOFC) applications: Aspect of gasification process and catalyst development," Mar. 01, 2023, Academic Press.

DOI: 10.1016/j.jenvman.2022.117077

Google Scholar

[55] Z. Cherkezova-Zheleva, M. Burada, A. E. Sobetkii, D. Paneva, S. A. Fironda, and R. R. Piticescu, "Green and Sustainable Rare Earth Element Recycling and Reuse from End-of-Life Permanent Magnets," Jun. 01, 2024, Multidisciplinary Digital Publishing Institute (MDPI).

DOI: 10.3390/met14060658

Google Scholar

[56] R. Krishna, A. D. Dhass, A. Arya, R. Prasad, and I. Colak, "An assessment of the strategies for the energy-critical elements necessary for the development of sustainable energy sources," Environmental Science and Pollution Research, vol. 30, no. 39, p.90276–90297, Aug. 2023.

DOI: 10.1007/s11356-023-28046-2

Google Scholar

[57] M. Laubertová, O. Velgosova, M. Sisol, and T. Vindt, "Study of Hydrometallurgical Treatment of Metal-Bearing Material from Environmental Burdens Containing Iron, Chromium, Nickel, and Cobalt," Minerals, vol. 14, no. 10, Oct. 2024.

DOI: 10.3390/min14100968

Google Scholar

[58] N. Vieceli, R. Casasola, G. Lombardo, B. Ebin, and M. Petranikova, "Hydrometallurgical recycling of EV lithium-ion batteries: Effects of incineration on the leaching efficiency of metals using sulfuric acid," Waste Management, vol. 125, p.192–203, Apr. 2021.

DOI: 10.1016/j.wasman.2021.02.039

Google Scholar

[59] A. Marra, A. Cesaro, and V. Belgiorno, "Recovery opportunities of valuable and critical elements from WEEE treatment residues by hydrometallurgical processes," Environmental Science and Pollution Research, vol. 26, no. 19, p.19897–19905, Jul. 2019.

DOI: 10.1007/s11356-019-05406-5

Google Scholar

[60] L. Castro, M. L. Blázquez, and J. Á. Muñoz, "Leaching/bioleaching and recovery of metals," Nov. 01, 2021, MDPI.

DOI: 10.3390/met11111732

Google Scholar

[61] A. Memic et al., "Bioleaching of Industrial Metallic Steel Waste by Mixed Cultures of Thermoacidophilic Archaea," Processes, vol. 12, no. 11, Nov. 2024.

DOI: 10.3390/pr12112327

Google Scholar

[62] M. Golzar-Ahmadi et al., "Pathway to industrial application of heterotrophic organisms in critical metals recycling from e-waste," Dec. 01, 2024, Elsevier Inc.

DOI: 10.1016/j.biotechadv.2024.108438

Google Scholar

[63] R. Nopriantoko, "Green Approaches to Extractive Metallurgy: A Novel Synthesis of Sustainable Practices," Metalurgi, vol.39, no.1, p.37, Sep.2024.

DOI: 10.55981/metalurgi.2024.748

Google Scholar