Thermomechanical Stability and Damping Mechanisms in Multifunctional 3D-Printed PCL-Based Composites

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Abstract:

Three-dimensional (3D) printing enables the fabrication of smart composite materials by embedding ferromagnetic shape memory alloy (FSMA) microparticles into a ductile polymer matrix, thus overcoming the intrinsic brittleness of most FSMA materials. In this work, the effects of thermal treatments near the melting temperature upon the damping mechanism in the low-temperature region are studied both in the 3D-printed PCL samples and in the 3D-printed (PCL/Ni45Mn36.7In13.3Co5) composites, focusing on the interactions processes between the microparticles and the polymer chains. 3D-printed PCL and 3D-printed composites were obtained by means Fused Deposition Modelling (FDM) and were studied by mechanical spectroscopy (MS). The deconvolution of the damping spectra revealed the appearance of two relaxation mechanisms in 3D-printed PCL samples and three relaxation mechanisms in 3D-printed composites.

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Materials Science Forum (Volume 1198)

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43-52

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August 2026

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© 2026 Trans Tech Publications Ltd. All Rights Reserved

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[1] V.K. Sharma, M.K. Chattopadhyay, K.H.B. Shaeb, A. Chouhan, S.B. Roy, Large magnetoresistance in Ni50Mn34In16 alloy, Appl. Phys. Lett. 89 (2006) 222509.

DOI: 10.1063/1.2399365

Google Scholar

[2] S.Y. Yu, Z.H. Liu, G.D. Liu, J.L. Chen, Z.X. Cao, G.H. Wu, B. Zhang, X.X. Zhang, Large magnetoresistance in single-crystalline Ni50Mn50-xInx alloys (x=14-16) upon martensitic transformation, Appl. Phys. Lett. 89 (2006) 162503.

DOI: 10.1063/1.2362581

Google Scholar

[3] A. Planes, L. Mañosa, M. Acet, Recent progress and future perspectives in magnetic and metamagnetic shape-memory Heusler alloys, Mater. Sci. Forum 738-739 (2013) 391-399.

DOI: 10.4028/www.scientific.net/MSF.738-739.391

Google Scholar

[4] J. Liu, T. Gottschall, K.P. Skokov, J.D. Moore, O. Gutfleisch, Giant magnetocaloric effect driven by structural transitions, Nat. Mater. 11 (2012) 620-626.

DOI: 10.1038/nmat3334

Google Scholar

[5] T. Gottschall, K.P. Skokov, B. Frincu, O. Gutfleisch, Large reversible magnetocaloric effect in Ni-Mn-In-Co, Appl. Phys. Lett. 106 (2015) 21901.

DOI: 10.1063/1.4905371

Google Scholar

[6] F.D. Lambri, F.G. Bonifacich, O.A. Lambri, D. Khanna, J.I. Pérez-Landazábal, V. Recarte, V. Sánchez-Alarcos, M.L. Lambri, G.I. Zelada, High functional 3D printed PCL/FSMA magnetic composites, Smart Mater. Struct. 33 (2024) 055039.

DOI: 10.1088/1361-665X/ad3d9f

Google Scholar

[7] F.D. Lambri, F.G. Bonifacich, O.A. Lambri, B. Weidenfeller, V. Recarte, V. Sánchez-Alarcos, J.I. Pérez-Landazábal, Modified rule of mixtures and Halpin-Tsai models applied to PCL/NiMnInCo 4D printed composites. Internal stresses study during the martensitic transformation, Compos. Sci. Technol. 265 (2025) 111153.

DOI: 10.1016/j.compscitech.2025.111153

Google Scholar

[8] F.G. Bonifacich, O.A. Lambri, V. Recarte, V. Sánchez-Alarcos, J.I. Pérez-Landazábal, Magnetically tunable damping in composites for 4D printing, Compos. Sci. Technol. 201 (2021) 108538.

DOI: 10.1016/j.compscitech.2020.108538

Google Scholar

[9] F.G. Bonifacich, O.A. Lambri, F.D. Lambri, P.B. Bozzano, V. Recarte, V. Sánchez-Alarcos, J.I. Pérez-Landazábal, Analysis of the strain misfit between matrix and inclusions in a magnetically tunable composite, Mech. Mater. 162 (2021) 104045.

DOI: 10.1016/j.mechmat.2021.104045

Google Scholar

[10] S. Rashidi, M.H. Ehsani, M. Shakouri, N. Karimi, Potentials of magnetic shape memory alloys for energy harvesting, J. Magn. Magn. Mater. 537 (2021) 168112.

DOI: 10.1016/j.jmmm.2021.168112

Google Scholar

[11] W. Zhao, F. Zhang, J. Leng, Y. Liu, Personalized 4D printing of bioinspired tracheal scaffold concept based on magnetic stimulated shape memory composites, Compos. Sci. Technol. 184 (2019) 107866.

DOI: 10.1016/j.compscitech.2019.107866

Google Scholar

[12] M. Lahelin, I. Aaltio, O. Heczko, O. Söderberg, Y. Ge, B. Löfgren, S.P. Hannula, J. Seppälä, DMA testing of Ni–Mn–Ga/polymer composites, Compos. Part A: Appl. Sci. Manuf. 40 (2009) 125–129.

DOI: 10.1016/j.compositesa.2008.10.011

Google Scholar

[13] K.B. Mustapha, K.M. Metwalli, A review of fused deposition modelling for 3D printing of smart polymeric materials and composites, Eur. Polym. J. 156 (2021) 110591.

DOI: 10.1016/j.eurpolymj.2021.110591

Google Scholar

[14] J. Wang, H. Xie, Z. Weng, T. Senthil, L. Wu, A novel approach to improve mechanical properties of parts fabricated by fused deposition modelling, Mater. Des. 105 (2016) 152-159.

DOI: 10.1016/j.matdes.2016.05.078

Google Scholar

[15] Q. Sun, G.M. Rizvi, C.T. Bellehumeur, P. Gu, Effect of processing conditions on the bonding quality of FDM polymer filaments, Rapid Prototyp J 14 (2008) 72-80.

DOI: 10.1108/13552540810862028

Google Scholar

[16] V. Sánchez-Alarcos, D.L.R. Khanna, P. La Roca, V. Recarte, F.D. Lambri, F.G. Bonifacich, O.A. Lambri, I. Royo-Silvestre, A. Urbina, J.I. Pérez-Landazábal, Polycaprolactone/MSMA composites for magnetic refrigeration applications, Polym. Compos. 46 (2024) 427-437.

DOI: 10.1002/pc.28997

Google Scholar

[17] O.A. Lambri, A review on the problem of measuring nonlinear damping and the obtainment of intrinsic damping, in: J. Martinez-Mardones, D. Walgraef, C.H. Wörner (Eds.), Materials Instabilities, World Scientific Publishing, New York, 2000, p.249–280.

DOI: 10.1142/9789812793317_0005

Google Scholar

[18] R. Schaller, G. Fantozzi, G. Gremaud (Eds.), Mechanical Spectroscopy Q-1, Trans Tech Publications, Zurich, 2001.

Google Scholar

[19] G.I. Zelada-Lambri, O.A. Lambri, J.A. García, Mechanical energy losses due to the movement of dislocations in molybdenum at high temperatures (0.3Tm), J. Nucl. Mater. 353 (2006) 127–134.

DOI: 10.1016/j.jnucmat.2006.02.086

Google Scholar

[20] B.J. Molinas, O.A. Lambri, M. Weller, Study of non-linear effects related to the Snoek-Köster relaxation in Nb, J. Alloys Comp. 211-212 (1994) 181.

DOI: 10.1016/0925-8388(94)90477-4

Google Scholar

[21] G.I. Zelada-Lambri, O.A. Lambri, G.H. Rubiolo, Amplitude dependent damping study in austenitic stainless steels 316H and 304H. Its relation with the microstructure, J. Nucl. Mater. 273 (1999) 248-256.

DOI: 10.1016/S0022-3115(99)00070-7

Google Scholar

[22] Peak Fit, V.4, Jandel Scientific Software, Germany, 1995.

Google Scholar

[23] J.D. Ferry, Viscoelastic Properties of Polymers, John Wiley & Sons, New York, 1980.

Google Scholar

[24] I.M. Ward, J. Sweeney, Mechanical Properties of Solid Polymers, 2nd ed., John Wiley & Sons, West Sussex, 2012.

Google Scholar

[25] J. Mark, K. Ngai, W. Graessley, L. Mandelkern, E. Samulski, J. Koenig, G. Wignall, Physical Properties of Polymers, 3rd ed., Cambridge University Press, Cambridge, 2004.

DOI: 10.1017/cbo9781139165167

Google Scholar

[26] Y. Wang, M.A. Rodriguez-Perez, R.L. Reis, J.F. Mano, Thermal and thermomechanical behaviour of polycaprolactone and starch/polycaprolactone blends for biomedical applications, Macromol. Mater. Eng. 290 (2005) 792-801.

DOI: 10.1002/mame.200500003

Google Scholar

[27] H.W. Starkweather Jr, Noncooperative relaxations, Macromol. 21 (1988) 1798-1802.

DOI: 10.1021/ma00184a043

Google Scholar

[28] L. Averous, L. Moro, P. Dole, C. Fringant, Properties of thermoplastic blends: starch–polycaprolactone, Polymer 41 (2000) 4157-4167.

DOI: 10.1016/S0032-3861(99)00636-9

Google Scholar

[29] C. Bastioli, A. Cerutti, I. Guanella, G.C. Romano, M. Tosin, Physical state and biodegradation behavior of starch-polycaprolactone systems, J. Environ. Polym. Degrad. 3 (1995) 81-95.

DOI: 10.1007/BF02067484

Google Scholar

[30] O.A. Lambri, F.G. Bonifacich, J.A. García, E.D.V. Giordano, G.I. Zelada, F.A. Sánchez, R.R. Mocellini, F. Plazaola, Mechanical energy losses in commercial crosslinked low-density polyethylene in the temperature range between 200 and 400 K, J. Appl. Polym. Sci. 136 (2019) 47605.

DOI: 10.1002/app.47605

Google Scholar

[31] B.J. Lazan, Damping of Materials and Members in Structural Mechanics, Pergamon, London, 1968.

Google Scholar

[32] O. Coussy, Poromechanics, John Wiley & Sons Ltd, Chichester, 2004.

Google Scholar

[33] A.V. Granato, K. Lücke, Theory of mechanical damping due to dislocations, J. Appl. Phys. 27 (1956) 583-593.

DOI: 10.1063/1.1722436

Google Scholar

[34] L. Gibson, M. Ashby (Eds.), Cellular solids: Structure and properties, Cambridge Solid State Science Series, 2nd ed., Cambridge University Press, Cambridge, 1997.

Google Scholar

[35] J.F. Mano, R.L. Reis, A.M. Cunha, Dynamic mechanical analysis in polymers for medical applications, in: R.L. Reis, D. Cohn (Eds.), Polymer Based Systems on Tissue Engineering, Replacement and Regeneration. Kluwer Academic Publishers, 2002, p.139–164.

DOI: 10.1007/978-94-010-0305-6_10

Google Scholar