Synthesis, Properties and Characterisation of Manganeous Layered Double Hydroxides Using In Situ X-Ray Techniques

Uwe König; Herbert Pöllmann

doi:10.4028/www.scientific.net/MSF.443-444.307

Paper Titles

Kinetics of the Decomposition of Crocidolite Asbestos: A Preliminary Real-Time X-Ray Powder Diffraction Study
p.291

Sorbate Rearrangement and Cation Migration in HFC-134 Loaded NaY Zeolite: a Temperature Dependent Synchrotron Powder Diffraction Study
p.295

Kinetical Investigations on Lamellar CalciumAluminateChromateHydrates with High Speed Detector
p.299

Features of Crystal Structure and Ferroelectric Phase Transitions of KTiOPO₄ Doped with Nb and Sb
p.303

Synthesis, Properties and Characterisation of Manganeous Layered Double Hydroxides Using In Situ X-Ray Techniques
p.307

Phase Transformations in Li-Mn-O Spinels Synthesized by Sol-Gel Method
p.311

Influence of the Dehydration on Location of Both Sodium and Calcium Cations in 5A Zeolite – An In Situ X-Ray Diffraction Study
p.315

Calcination of ZSM-5. An In Situ Synchrotron Powder Diffraction Study
p.319

Structural Studies of the Spinel System Ga_xCoFe_1-xCrO₄ (0 ≤ x ≤ 1) by Neutron Powder Diffraction
p.325

HomeMaterials Science ForumMaterials Science Forum Vols. 443-444Synthesis, Properties and Characterisation of...

Synthesis, Properties and Characterisation of Manganeous Layered Double Hydroxides Using In Situ X-Ray Techniques

Abstract:

Synthetic manganeous Layered Double Hydroxides of the Hydrotalcite- and Shigaite- type were prepared by the coprecipitation method. The thermal behaviour of two compounds, [Mn₆Al₃(OH)₁₈] [(SO₄)₂Na·12H₂O] and [Mn₆Al₃(OH)₁₈] [Cl·4H₂O] was investigated by several experimental techniques. Thermal analysis and in-situ X-ray diffractometry show several dehydration stages of the synthesis products in the temperature range of 25 < T < 170°C followed by decomposition at temperatures above 200°C.