High Temperature Oxidation Behavior of TiNi Alloys
The oxidation behavior of the equiatomic TiNi alloy was investigated at 600-900oC. The oxidation resistance of the TiNi alloy was better than the pure Ti alloy, but worse than the pure Ni alloy. The oxide scales consisted of TiO2, with and without embedded particles of TiNiO3 and Ni. The subscale matrix phase was (TiNi3+TiNi) at 600oC, TiNi3 at 700oC, (Ni+TiNi3) at 800oC, and Ni at 900oC. Oxidation was mainly governed by the inward diffusion of oxygen, and the outward diffusion of Ti and a bit of Ni. Detailed microstructures and the oxidation mechanism are proposed.
Z.Y. Zhong, H. Saka, T.H. Kim, E.A. Holm, Y.F. Han and X.S. Xie
J.H. Ko and D. B. Lee, "High Temperature Oxidation Behavior of TiNi Alloys", Materials Science Forum, Vols. 475-479, pp. 853-856, 2005