New Fluorescent Heterocyclic Materials: Synthesis, Solvatochromic and Fluorescence Properties

Article Preview

Abstract:

Thienyl- and bithienyl-1,3-benzothiazoles 1 and 2 were synthesised by reacting various formyl thienyl and bithienyl derivatives with o-aminobenzenethiol in moderate to excellent yields. Evaluation of the solvatochromic and fluorescence properties of these compounds was carried out. Due to their strong fluorescence and also the strong push-pull character, benzothiazole derivatives 1 and 2 can be used as potential NLO materials or as fluorescent markers.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 514-516)

Pages:

147-151

Citation:

Online since:

May 2006

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2006 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B.M. Krasovitski and B.M. Bolotin: Organic Luminescent Materials (VCH, Weinheim, 1988).

Google Scholar

[2] A.R. Katritzky and C.W. Rees, Eds.: Comprehensive Heterocyclic Chemistry, Vol. 6, p.235 (Pergamon Press, New York, 1984).

Google Scholar

[3] S. Tollari, S. Cenini, A. Rossi and G.J. Palmisano: Mol. Catal. A- Chem. Vol. 135 (1998), p.241.

Google Scholar

[4] X.H. Zhang, O.Y. Wong, Z.Q. Gao, C.S. Lee, H.L. Kwong, S.T. Lee and S.K. Wu: Mater. Sci. Eng. Vol. B85 (2001), p.182.

Google Scholar

[5] W.N. Leng, Y.M. Zhou, Q.H. Xu and J.Z. Liu: Polymer Vol. 42 (2001), p.9253.

Google Scholar

[6] S.P.G. Costa, J.A. Ferreira, G. Kirsch and A.M.F. Oliveira-Campos: J. Chem. Res. (1997), (S), p.314; (M), p. (2001).

Google Scholar

[7] X.H. Luan, N.M.F.S.A. Cerqueira, A.M.A.G. Oliveira, M.M.M. Raposo, L.M. Rodrigues, P. Coelho and A.M.F. Oliveira-Campos: Adv. Colour Sci. Tech. Vol. 5 (2002), p.18.

Google Scholar

[8] P.C.R. Soares-Santos, M.M.M. Raposo, S.P.G. Costa and A.M.F. Oliveira-Campos: Adv. Colour Sci. Tech. Vol. 5 (2002), p.94.

Google Scholar

[9] M.M.M. Raposo and G. Kirsch: Tetrahedron Vol. 59 (26) (2003), p.4891.

Google Scholar

[10] M.M.M. Raposo, A.M.C. Fonseca and G. Kirsch: Tetrahedron Vol. 60 (18) (2004), p.4071.

Google Scholar

[11] R.M.F. Batista, S.P.G. Costa and M.M.M. Raposo: Tetrahedron Lett. Vol. 45 (13) 2004, p.2825.

Google Scholar

[12] M.M.M. Raposo, A.M.C. Fonseca and G. Kirsch: Mater. Sci. Forum Vol. 455-446 (2004), p.157.

Google Scholar

[13] F. Costa, C.J.R. Silva, M.M.M. Raposo, A.M.C. Fonseca, I.C. Neves, A.P. Carvalho and J. Pires: Microporous Mesoporous Mat. Vol. 72 (1-3) (2004), p.111.

DOI: 10.1016/j.micromeso.2004.04.003

Google Scholar

[14] D.S. Zyss: Non linear optical properties of organic molecules and crystals, Vol 1 and 2 (Academic Press, Orlando, 1987).

Google Scholar

[15] M.J. Kamlet, J. -L. Abboud, M.H. Abraham and R.W. Taft: J. Org. Chem. Vol. 48 (1983), p.2877.

Google Scholar

[16] A. Gáplovsky, J. Donovalová, P. Magdolen, S. Toma and P. Zahradnik: Spectrochim. Acta A Vol. 58 (2002), p.363.

Google Scholar

[17] E.M. Breitung, C.F. Shu and R.J. McMahon: J. Am. Chem. Soc., Vol. 122 (2000), p.1154.

Google Scholar