Preparation of Chitosan Grafting Acrylic Acid Supported Palladium Fibrous Catalyst and its Application in Hydrogenation

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Abstract:

Chitosan grafting acrylic copolymer (CTS-g-AA) supported Nano palladium catalyst was obtained in this paper. Chitosan grafting acrylic copolymer (CTS-g-AA) was prepared firstly and palladium was supported on CTS-g-AA; then nano fibrous catalyst was gained via electrospinning technique. The title catalysts were characterized by TEM, SEM and IR, the diameter of nanofiber was about 70~200 nm, the size of metal particles were in a range of 10~40 nm, and palladium particles dispersed on nanofibers homogeneously. The catalyst was applied to catalyze α-octene hydrogenation in normal temperature and pressure. The results showed that the conversion of α-octene was 99%, and the yield of octane was 65% by double-metal catalyst.

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Periodical:

Materials Science Forum (Volumes 620-622)

Pages:

537-540

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Online since:

April 2009

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© 2009 Trans Tech Publications Ltd. All Rights Reserved

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