Effect of Anionic Surfactants with Different Structure on the Fluorescent Properties of the CPPO-H2O2-Rhodamine B System

Hai Yan Du; Wei Da Xu; Wei Zhou; Jia Yue Sun

doi:10.4028/www.scientific.net/MSF.663-665.207

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HomeMaterials Science ForumMaterials Science Forum Vols. 663-665Effect of Anionic Surfactants with Different...

Effect of Anionic Surfactants with Different Structure on the Fluorescent Properties of the CPPO-H₂O₂-Rhodamine B System

Abstract:

The effect of anionic surfactants on the chemiluminescence (CL) properties of CPPO- H2O2-Rhodamine B system was researched, and the maximum fluorescent intensity of every system was found at the critical micelle concentration (CMC) of corresponding surfactant. The reduced vibration of Rhodamine B molecules induced by the combination of micelle was offered to explain the positive effect of anionic surfactants. Moreover, the structure of anionic surfactant was found to be relative to the enhanced fluorescent intensity, and the hydrophobic group’s structure and stereospecific blockade were considered as two main factors to the sensitization ability of anionic surfactant on CL.

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Periodical:

Materials Science Forum (Volumes 663-665)

Pages:

207-210

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https://doi.org/10.4028/www.scientific.net/MSF.663-665.207

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Online since:

November 2010

Authors:

Hai Yan Du, Wei Da Xu, Wei Zhou, Jia Yue Sun

Keywords:

Chemiluminescence, CPPO, Rhodamine B (RhB), Surfactant

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