Synthesis and Characterization of Ternary Terbium Luminescence Complexes with Phthalic Acid and 1, 10-Phenanthroline

Hui Juan Ren; De Hui Sun; Zhen Feng Cui; Hua Yang; Guang Yan Hong

doi:10.4028/www.scientific.net/MSF.663-665.211

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HomeMaterials Science ForumMaterials Science Forum Vols. 663-665Synthesis and Characterization of Ternary Terbium...

Synthesis and Characterization of Ternary Terbium Luminescence Complexes with Phthalic Acid and 1, 10-Phenanthroline

Abstract:

Ternary rare earth luminescence complexes composed of Tb (III)-phthalic acid (H2L)-1,10-phenanthroline (phen) were synthesized using precipitation method. The elemental analysis, plasma atomic emission spectra, infrared spectra were measured the composition of obtained samples and the chemical composition deduced is TbL3/2(phen)0.5. XRD patterns show that the obtained coordination compound is new crystal different from that of two ligands. SEM results indicate that the coordination compound is a floral crystal with the size about 1-2 µm and has better dispersity. The TG-DTA result showed that the luminescence complex has good stability below 478 oC. Photoluminescence analysis indicated that the coordination compound emits Tb3+ characteristic green luminescence under ultraviolet excitation.

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Materials Science Forum (Volumes 663-665)

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211-214

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.663-665.211

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Online since:

November 2010

Authors:

Hui Juan Ren, De Hui Sun, Zhen Feng Cui, Hua Yang, Guang Yan Hong

Keywords:

1.10-Phenanthroline, Luminescence Complex, Phthalic Acid, Teribium

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DOI: 10.1021/ja064902x

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