Effect of Deputy Group Metal Ions on the Fluorescent Properties of the CPPO-H₂O₂-Rhodamine B System

Abstract:

The influence of metal ions on the peroxyoxalate chemiluminescence reaction was investigated. A number of metal ions showed the quenching effect of the chemiluminescence reaction of bis (3, 5, 6- trichloro-2-carbopentyloxy) oxalate with hydrogen peroxide in the presence of Rhodamine B as the fluorophore. Copper ion gave the highest quenching effect. The reason for the decrease in the chemiluminescence intensity by metal ions is probably a change in the conjugative structure of Rhodamine B due to combination of metal ions and Rhodamine B

• Periodical: Materials Science Forum (Volumes 663-665)
• Pages: 527-531
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.663-665.527
• Online since: November 2010
• Authors: Hai Yan Du, Wei Da Xu, Wei Zhou, Jia Yue Sun
• Keywords: Chemiluminescence, Metal Eon, Peroxyoxalate, Rhodamine B (RhB)

References

[1] J. W. Choi, C. Y. Kang, S. J. Yoon, H. J. Kim and H. J. Jung: J. Mater. Res. Vol. 14 (1999), p.3567.

[1] A. Nishitan, Y. Tsukamoto and S. Kanda et al, Anal. Chim. Acta Vol. 251 (1991), p.247.

[2] B. Yan, S. W. Lewis and P. J. Worsfold et al, Anal. Chim. Acta Vol. 250 (1991), p.145.

[3] P. J. Kwakman and U. A. Brinkman: Anal. Chim. Acta Vol. 266 (1992), p.175.

[4] A. R. Bowic, M. G. Sanders and P. J. Worsefold: J. Biolumin. Chemilumin. Vol. 11 (1996), p.61.

[5] C. Gooijer and M. Volthorst: Biomed. Chromatogr. Vol. 4 (1990), p.92.

[6] M. M. Nakamura, S. A. Saraiva and N. Coichev: Anal. Lett. Vol. 33 (2000), p.391.

[7] M. Shamsipur and M.J. Chaichi: Spectrochim. Acta A Vol. 57 (2001), p.2355.

[8] K. Nakashima, M. Wada and N. Kuroda et al, J. Liq. Chromatogr. Vol. 17 (1994), p.2111.

[9] M. Stigbrand, E. Ponten and K. Irgum: Anal. Chem. Vol. 66 (1994), p.1766.

[10] C. L. R. Catherall, T. F. Palmer and R. B. J. Cundall: J. Chem. Soc. Faraday Trans. Vol. 280 (1984), p.823.

[11] A. G. Hadd, A. L. Robinson and K. L. Rowlen et al, J. Org. Chem. Vol. 63 (1998) , p.3023.

[12] T. Wilson: Photochem. Photobiol. Vol. 62 (1995), p.601.

[13] S. Ahmed, S. Fujii and N. Kishikawa et al, J. Chromatogr. A Vol. 1133 (2006), p.76.

[14] M. Tsunoda, E. Uchino and K. Imai et al, Chromatogr. A Vol. 1164 (2007), p.162.

[15] M. Shamsipur and M. J. Chaichi: J. Photochem. Photobiol. A Vol. 155 (2003), p.69.

[16] M. Stigbrand, A. Karlsson and K. Irgum: Anal. Chem. Vol. 68 (1996), p.3945.

[17] M. Emteborg, K. Irgum and C. Gooijer et al, Anal. Chim. Acta Vol. 357 (1997), p.111.

[18] M. Shamsipur, A. Yeganeh-Faal and M. J. Chaichi et al, Dyes Pigments Vol. 72 (2007), p.113.