Optimized Conductivity of Anthraquinone-2-Sulfonic Acid Sodium, 5-Sulfosalicylic Acid and Toluene-4-Sulfonic Acid Co-Doped Polypyrrole

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Abstract:

By doping three complex dopants in different molar ratio, a series of polypyrroles doped with 9, 10-anthraquinone-2-sulfonic acid sodium, 5-sulfosalicylic acid and toluene-4-sulfonic acid were synthesized by polymerizing the monomer pyrrole in aqueous solution of ferric chloride. The resulting polypyrroles were characterized with the four-probe and laser light scattering, respectively. Our results indicate that optimized value of conductivity reached to 6683 S/m when the molar ratio of anthraquinone-2-sulfonic acid sodium to 5-sulfosalicylic acid to toluene-4-sulfonic acid was 2:1:3. For applications of polymer in optoelectronics, in lithium-ion battery and in electromagnetic shielding, to obtain optimized value of conductivity has great significance for us.

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Materials Science Forum (Volumes 663-665)

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702-705

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November 2010

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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