Orthogonal Experimental Study on Preparation Conditions of V2O5/TiO2 Catalysts for the SCR of NO with NH3

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The optimal preparation condition of V2O5/TiO2 catalyst was investigated by the orthogonal experimental method. Five factors were chosen including A(molar ratio of NH4VO3 to oxalic acid),B(aging time of solution),C(active component content),D(impregnation temperature) and E(impregnation time). Every factor had four levels. The levels of A were1:2, 1:1, 3:2 and 2:1. The levels of B were 12h, 14h, 16h and 18h. The levels of C were 2%, 4%, 6% and 8%. The levels of D were 45°C, 55°C, 65°C, 75°C. The levels of E were 2h, 3h, 4h and 5h.The orthogonal experiment table was L16(45). Then the de-NOx rate of V2O5/TiO2 catalysts was tested in SCR catalytic reactor. The results showed that the influence of chosen factors decreased in the following order: C> B> E> D> A. The optimal plan of preparation experiments, obtained from the orthogonal experiment, is C3B1E3D3A4. So the optimal condition of preparation experiments are that active component content is 6%,aging time of solution is 12h,impregnation time is 4h,impregnation temperature is 65°C,molar ratio of ammonium metavanadate and oxalic acid is 2:1.

Info:

Periodical:

Materials Science Forum (Volumes 675-677)

Edited by:

Yi Tan and Dongying Ju

Pages:

1031-1034

DOI:

10.4028/www.scientific.net/MSF.675-677.1031

Citation:

B. N. Ren et al., "Orthogonal Experimental Study on Preparation Conditions of V2O5/TiO2 Catalysts for the SCR of NO with NH3", Materials Science Forum, Vols. 675-677, pp. 1031-1034, 2011

Online since:

February 2011

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$35.00

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