Fabrication of W-ZrC Cermets by Reactive Melt Infiltration with Polycarbosilane as Preforms’ Adhesive

Article Preview

Abstract:

Polycarbosilane (PCS) was introduced into preforms to prepare W-ZrC cermets by reactive melt infiltration (RMI). Properties and microstructure of the preforms and cermets were analyzed with XRD, SEM and EDS. The preforms had an open porosity of 42.0 %, and the WC particles were cemented by the pyrolysate of PCS. W-ZrC cermets were prepared by heating Zr2Cu covered preforms to 1300 °C for 3 h. XRD revealed that the resulting cermets were made up of W, ZrC and W2C. The cermets had an open porosity of 3.5 %, a flexural strength of 354.0 MPa, a flexural modulus of 192.5 GPa and a flexural toughness of 5.72 MPa·m1/2 .

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 675-677)

Pages:

819-822

Citation:

Online since:

February 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. Koutsospyros, W. Braida, C. Christodoulatos, D. Dermatas and N. Strigul: J. Hazard. Mater. Vol. 136 (2006), pp.1-19.

DOI: 10.1016/j.jhazmat.2005.11.007

Google Scholar

[2] G.M. Song, Y.J. Wang and Y. Zhou: J. Mater. Sci. Vol. 36 (2001), pp.4625-4631.

Google Scholar

[3] K.H. Sandhage and P. Kumar, US Patent 6, 407, 022. (2003).

Google Scholar

[4] K.H. Sandhage, R. Unocic, M. Dickerson, K. Guerra and M. Timberlake, US Patent 6, 598, 656. (2003).

Google Scholar

[5] Z. Grzesik, M.B. Dickerson and K.H. Sandhage: J. Mater. Res., Vol. 18 (2003), pp.2135-2140.

Google Scholar

[6] M.B. Dickerson, R.L. Snyder and K.H. Sandhage: J. Am. Ceram. Soc. Vol. 85 (2002), pp.730-732.

Google Scholar

[7] M.B. Dickerson, P.J. Wurm, J.R. Schorr, W.P. Hoffman, P.G. Wapner and K.H. Sandhage: J. Mater. Sci. Vol. 39 (2004), pp.6005-6015.

Google Scholar

[8] S.M. Zhu, S.Q. Ding, H.A. Xi and R.D. Wang: Mater. Lett. Vol. 59 (2005), pp.595-597.

Google Scholar

[9] Y. Ma, Q.S. Ma and Z.H. Chen: Rare Metal Mat. Eng. Vol. 36, Suppl. 1 (2007), pp.531-533.

Google Scholar

[10] M. Monthioux and O. Delverdier: J. Euro. Ceram. Soc. Vol. 16 (1996), pp.721-737.

Google Scholar

[11] K. Bhanumurthy and R. Schmid-fetzer: Scripta Mater. Vol. 45 (2001), pp.547-553.

Google Scholar

[12] H.M. Chen, Y. Xiang and S. Wang: J. Alloy. Comp. Vol. 474 (2009), pp.76-80.

Google Scholar