Improved Gel Electrolyte by Layered α-Zirconium Phosphate for Quasi-Solid-State Dye-Sensitized Solar Cells

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In this article, we present a new composite gel electrolyte for dye-sensitized solar cells (DSSC), with butylamine (BA) and propylene carbonate (PC) intercalated α-Zirconium phosphate (ZrP-BA-PC) as solid fillers dispersed in polyethlene oxide (PEO) polymer. The ionic electrical conductivity was markedly improved with the ZrP-BA-PC additive at ambient temperature. The DSSC with 5 wt% ZrP addition into the electrolyte obtained the maximum photovoltaic conversion efficiency of 6.61 % under 100 mW/cm-2 irradiation.

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71-75

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June 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] B. O'Regan M. Grätzel, Nature 353, 737 (1991).

Google Scholar

[2] S. Ito, T. N. Murakami et. al. Thin Solid Films 516, 4613-4619. (2008).

Google Scholar

[3] P. Wang, S.M. Zakeeruddin, P. Comie, I. Exnar, and M. Gratzel, J. Am. Chem. Soc. 125, 1166. (2003).

Google Scholar

[4] H. Usui, H. Matsui, N. Tanabe, S. Yanagida, Journal of Photochemistry and Photobiology A: Chemistry, 164(1-3), 97-101. (2004).

Google Scholar

[5] N. Wang, H. Lin, J. Li, and X. Li, J. App. Phy. Lett 89, 194104. (2006).

Google Scholar

[6] C. Nan, L. Fan, Y. Lin, and Q. Cai, J. Phy. Rev. Lett 91, 61041. (2003).

Google Scholar

[7] L.T. Kubota, L. Gorton, J. Electroanalysis 11, 1011. (1999).

Google Scholar

[8] Clearfield A, Alberti G, Costantino U. Inorganic Ion Exchange Materials. Chapter 1~4. (1984).

Google Scholar

[9] N. Papageorgiou, Y. Athanassov, M. Armand, P. Bonhôte, H. Pettersson, A. Azam, and M. Grätzel, J. Electrochem. Soc. 143, 3099. (1996).

DOI: 10.1149/1.1837171

Google Scholar

[10] H. Han, W. liu, J. Zhang, et. al. Adv. Funct. Mater. 15, 1940-1944. (2005).

Google Scholar

[11] S.H. Anastasiadis et al., phys . Rev. Lett. 84, 915. (2000).

Google Scholar

[12] F. Croce et al., Nature (London) 394, 456. (1998).

Google Scholar