Effect on the Characteristic and Properties of Carbon Coated LiFePO4/C Composite

Article Preview

Abstract:

LiFePO4/C composite with different types of organic carbon sources has been synthesized by carbon thermal reduction technique. The physical characteristics and electrochemical properties of LiFePO4/C composite have been studied compared with commercial products. It is shown that good carbon-coated LiFePO4/C composite can be obtained with 13wt.% glucose as carbon source, which has effected on the good processing performance due to its suitable specific surface area of 26.3m2/g and high tap density of 1.3g/cm3. Furthermore, it has contributed to the high-rate electrochemical property with discharge capacity of 128mAh/g at 1C (1C=170 mAh/g).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

367-371

Citation:

Online since:

June 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Padhi A K. Nanjundawamy K S. Goodenou gh J B. Electrochem Soc J, 1997, 4, 1188-1194.

Google Scholar

[2] Islam, M. DRiscoll, D. Fisher, C.A. J, Slater, P.R. Chem. Mater. 2005, 17: 5085.

Google Scholar

[3] Laffont,L. Delacourt,C.; Gibot,P.; Wu,M.Y.; Kooyman,P.; Masquelier,C.; Tarascon, J.M. Chem. Mater. 2006, 18: 5520.

DOI: 10.1021/cm0617182

Google Scholar

[4] Sides C.R. Croce,F. Young V.Y. Martin, Electrochem. Solid-State Lett. 2005, 8: A484.

Google Scholar

[5] Li,X.L. Kang F.Y. Bai X.D. Shen W.C. Commun., 2007, 9: 663.

Google Scholar

[6] Kang, B. Ceder, G. Nature, 2009, 458: 190.

Google Scholar

[7] Delacourt,C. Poizot,P. Levasseur,S. Masquelier,C. Electrochem. Solid-State Lett., 2006, 9: A352.

DOI: 10.1149/1.2201987

Google Scholar

[8] Ravet,N.; Chouinard,Y.; Magnan J.F.; Besner,S.; Gauthier,M.; Armand M.J. Power Sources, 2001, 97-98: 503.

DOI: 10.1016/s0378-7753(01)00727-3

Google Scholar

[9] Prosini, P.P.; Zane, D.; Pasquali, M. Electrochim. Acta, 2001, 46: 3517.

Google Scholar

[10] Mi, C.H.; Cao, G.S.; Zhao, X.B. Mater. Lett., 2005, 59: 127.

Google Scholar

[11] Ravet,N.; Gauthier,M.; Zaghib,K.; Goodenough J.B. Mauger,A.; Gendron,F.; Julien C.M. Chem. Mater. 2007, 19: 2595.

DOI: 10.1021/cm070485r

Google Scholar