Unusual Effect of Oxygen on the Mechanical Behavior of a β-Type Titanium Alloy Developed for Biomedical Applications

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Abstract:

Oxygen enhances the strength of titanium alloys in general; however, excess oxygen can make titanium alloys brittle. On the other hand, oxygen enhances the precipitation of the α phase and suppresses the formation of the ω phase. Thus, using the optimal amount of oxygen is important to improve the mechanical properties of titanium alloys. The role of oxygen in titanium alloys is still not well understood. The effect of oxygen on the mechanical behavior of a β-type titanium alloy, Ti-29Nb-13Ta-4.6Zr (referred to as TNTZ), which is used for biomedical applications, was investigated in this study. Oxygen was found to stabilize the ω phase in TNTZ. This behavior of oxygen is unusual considering the known behavior of oxygen in titanium alloys: oxygen is known to suppress the formation of the ω phase in titanium alloys. A small amount of oxygen increases the tensile strength but decreases the ductility of TNTZ. On the other hand, a large amount of oxygen, of around 0.7 mass%, increases both the tensile strength and the ductility of TNTZ. This phenomenon is unexpected.

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Materials Science Forum (Volumes 706-709)

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135-142

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. C. Williams, B. S. Hickman and D. H. Leslie, The effect of ternary additions on the decomposition of detestable beta phase titanium alloys, Metall. Mater. Trans. B 2 (1971), 477–484.

DOI: 10.1007/bf02663337

Google Scholar

[2] H. Fujii, K. Fujisawa, M. Ishii and Y. Yamashita, Development of low-cost high strength Ti-Fe-O-N alloy series, Shinnittetsu Giho 375 (2001) , 94-98.

Google Scholar

[3] J. I. Kim, H. Y. Kim, H. Hosoda and S. Miyazaki, Shape memory behavior of Ti-22Nb-(0. 5-2. 0)O(at%) biomedical alloys, Mater. Trans. 46 (2005), 852-857.

DOI: 10.2320/matertrans.46.852

Google Scholar

[4] M. Niinomi, T. Akahori, M. Nakai and H. Tsutsumi, Towards developing ubiquitous titanium alloys, Proc. PFAMXIII: Eighteenth International Conference on Processing and Fabrication of Advanced Materials, Proc. 2 (2009), 645-665.

Google Scholar

[5] D. Kuroda, M. Niinomi, M. Morinaga, Y. Kato and T. Yashiro, Design and mechanical properties of new beta type titanium alloys for implant materials, Mater. Sci. Eng. A. 243 (1998), 244-249.

DOI: 10.1016/s0921-5093(97)00808-3

Google Scholar

[6] F. Geng, M. Niinomi, and M. Nakai, Remarkable yielding and strain hardening in Ti-29Nb-13Ta-4. 6Zr with high oxygen content, submitted to Acta Mater.

Google Scholar

[7] M. Niinomi, H. Fukui, T. Takeuchi and S. Katsura, Precision casting of titanium and its alloys, J. Japan Found. Soc. 73 (2001), 798-804.

Google Scholar

[8] M. Nakai, M. Niinomi, T. Akahori H. Tsutsumi and M. Ogawa, Effect of oxygen content on microstructure and mechanical properties of biomedical Ti-29Nb-13Ta-4. 6Zr alloy under soliutionized and aged conditions, Mater. Trans. 50 (2009), 2716-2720.

DOI: 10.2320/matertrans.ma200904

Google Scholar

[9] H. Kim, H. Hosoda and S. Miyazaki, Beta-titanium shape memory alloys, J. Jap. Inst. Light Metals. 55 (2005), 613-617.

Google Scholar