Magnetic and Piezoelectric Properties of the Fe3+ Doped PLZT Electroceramics

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Abstract:

For the growing interest in developing of more attractive multiferroic and magnetoelectric ceramics an alternative is a double-doped Pb(Zr1-xTix)O3- material with trivalent lanthanum and iron ions. Such material has a structure based on ABO3 perovskite and properties depending on the chemical and structural composition. In the present work the results of the preparation and characterization of Fe3+- modified 9/65/35 PLZT ceramics have been reported. Two samples of Pb0,91(La1-zFez)0,09(Zr0,65Ti0,35)0,9775O3 ceramics, for different Fe ions concentration (z = 0,0 and 0,5 at.%), were prepared from the MOM derived powders and sintered by the hot uniaxial pressing methods. To analyze the obtained ceramics properties the XRD, SEM and also application oriented dielectric and magnetic measurements were performed. The Fe3+ substitution at the La-site of PLZT has shown many interesting and unusual dielectric, piezoelectric and magnetic properties. The obtained material was proposed to implement into Piezoelectric Transformer structure to change gain characteristics proportionally to magnetic field intensity.

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Materials Science Forum (Volumes 730-732)

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117-122

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November 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] I. A. Sergienko, E. Dagotto: Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites, Phys. Rev. B 73 (2006) pp.094434-9.

DOI: 10.1103/physrevb.73.094434

Google Scholar

[2] W. W. Li, J. J. Zhu, J. D. Wu, J. Gan, Z. G. Hu, M. Zhu, J. H. Chu: Temperature dependence of lectronic transitions and optical properties in multiferroic BiFeO3 nanocrystalline film determined from transmittance spectra. Appl. Phys. Lett. 97 ( 2010) 121102 - 121102-3.

DOI: 10.1063/1.3489926

Google Scholar

[3] V. K. Wadhawan: Introduction to Ferroic Materials, Gordon and Breach Science Publishers, Singapore, 2000.

Google Scholar

[4] W. Eerenstein, N. D. Mathur, J. F. Scott: Multiferroic and magnetoelectric materials, Nature 442 (2006) p.759–765.

DOI: 10.1038/nature05023

Google Scholar

[5] N.A. Hill: Why are there so few magnetic ferroelectrics?, J. Phys. Chem. 104 (2000) 6694-6709.

DOI: 10.1021/jp000114x

Google Scholar

[6] R. A. Islam, H. Kim, S. Priya, H. Stephanou: Piezoelectric transformer based ultrahigh sensitivity magnetic field sensor, Applied Physics Letters 89 (2006) pp.2357941-2357944.

DOI: 10.1063/1.2357941

Google Scholar

[7] V. V. Efimov, E. A. Efimova, K. Iakoubovskii, S. Khasanov, D. I. Kochubey, V. V. Kriventsov, A. Kuzmin, B. N. Mavrin, M. Sakharov, V. Sikolenko, A. N. Shmakov, S. I. Tiutiunnikov, EXAFS, X-ray diffraction and Raman studies of (Pb1-xLax)(Zr0.65Ti0.35)O3 (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam, J. Phys. Chem. Solids 67 (2006) pp.2007-2012.

DOI: 10.1016/j.jpcs.2006.05.034

Google Scholar

[8] V. V. Efimov, S. S. Khasanov, B. N. Mavrin, N. N. Novikova, A. V. Shilnikov, A. I. Burkhanov, V. V. Sikolenko, A. Sternberg, S. I. Tiutiunnikov, D. M. Toumlbbens, V. A. Yakovlev: Structure and lattice dynamics in PLZT 8/65/35 ceramics irradiated by high-current pulsed electron beam, Ferroelectrics 302 (2004) pp.327-333.

DOI: 10.1080/00150190490456321

Google Scholar

[9] S. Dutta, R. N. P. Choudhary: Effect of trivalent iron substitution on structure and properties of PLZT ceramics, Appl. Phys. A 90 (2008) p.323–328.

DOI: 10.1007/s00339-007-4276-2

Google Scholar

[10] S. Priya, R. Islam, S. Dong, D. Viehland: Recent advancement in magnetoelectric particulate and laminate composites, 19 (2007) pp.147-164.

DOI: 10.1007/s10832-007-9042-5

Google Scholar