An Analysis of the Physical Properties of Multicomponent Alloy on the Simulation Solidification by Phase-Field Model

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Abstract:

A phase-field model is proposed for the simulation of microstructure and solute concentration during the solidification of Fe-C-P-Mn quaternary alloys. In this paper, a study is presented to analyze both the effects of partition coefficient and solute diffusivity on the microstructural evolution during solidification simulation. Partition coefficient and diffusivity are very important from a practical standpoint, because both parameters exert a strong influence on the dendrite morphology. Additionally, the proposed model is applied for quaternary alloys to the analysis of the time-dependent solidified fraction. Simulations permit to conclude that the solidified fraction is proportional to the square root of time, as expected for any diffusion-controlled growth process. Phase-field simulations on non-isothermal dendrite growth are also examined. Two-dimensional simulation results exhibit different dendrites in multicomponent alloys for different solute concentrations. Changes in the carbon concentration seem to affect the dendrite morphology, due to its higher concentration and its lower equilibrium partition coefficient. Changes in the phosphorus concentration affect the dendrite morphology and the interface velocity, when its content is increased from 10-3mol%P. Higher manganese content slows down the solidification kinetic, while the dendrite morphology remains unchanged.

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Materials Science Forum (Volumes 730-732)

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703-708

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November 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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