Effect of Ce Addition on the Ignition-Proof Properties and Surface Tension of AZ91D-2.5Ca(Wt.%) Magnesium Alloy

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In order to develop ignition-proof magnesium alloys, the effect of alloying element Ce on the ignition-proof properties and surface tension of AZ91D-2.5Ca alloy were investigated. The results show that the addition of Ce can significantly raise the ignition temperature and change the structure of surface oxide film as well as the surface tension. When the Ce content increases to 1.2%, the ignition point reaches 1371K. Upon the addition of Ce, the oxide film of AZ91D-2.5Ca melt changes to fine and close structure from the porous structure before the Ce addition. The composite oxide film mainly composed of MgO, Al2O3, CaO and Ce2O3. The surface tension of AZ91D-2.5Ca decrease with the increasing Ce content, as the active-element Ce enriched at the melt surface.

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82-87

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April 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Suling Cheng, Gencang Yang,Effect of Ca and Y additions on oxidation behavior of AZ91 alloy at elevated temperatures, [J]. Transactions of Nonferrous Metaals Society of China,2009,19:299.

DOI: 10.1016/s1003-6326(08)60268-x

Google Scholar

[2] M.Sakamoto, S. Akiyama, Suppression of ignition and buring of molten Mg alloys by Ca bearing stable oxide film, [J]. Materials science letters,1997,16:1048.

Google Scholar

[3] F.Czerwinski, The oxidation behaviour of an AZ91D magnesium alloy at high temperatures,[J].Acta Materialia,2002,50:2639.

DOI: 10.1016/s1359-6454(02)00094-0

Google Scholar

[4] Xiaoqin zeng, Qudong Wang, Behavior of surface oxidation on molten Mg-9Al-0.5Zn-0.3Be alloy, [J].Materials Science and Engineering, 2001,A301:154.

Google Scholar

[5] Feng Xiao, Lanxiao Liu, Surface tension of molten Ni-(Cr,Co,W) alloys and segregation of elements, [J].Transactions of Nonferrous Metals Society of China,2008,18:1184.

DOI: 10.1016/s1003-6326(08)60202-2

Google Scholar

[6] N.Jha, A.K. Mishra, Thermodynamic and surface properties of liquid Mg-Zn alloys,[J].Alloys and Compounds,2001,329:224.

DOI: 10.1016/s0925-8388(01)01684-x

Google Scholar

[7] G.Loglio, P.Pandolfini, R.Miller, Drop and Bubble shape analysis as a tool for dilational rheological studies of interfacial layers, [J].Studies in Interface Science, 2001,11:439.

DOI: 10.1016/s1383-7303(01)80038-7

Google Scholar

[8] Deng Zhenghua, Li Huaji, Zhao Wanjun, and Li Weibin, Effect of Ce concentration on ignition temperature and surface tension of Mg-9wt.%Al alloy, [J]. China Foundry, 2013, 10:108.

Google Scholar