Magnetic Properties of Cyano-Bridged Compound Co [Fe(CN)5NO]·5H2O

Cheng Long Lei; Qing Lin; Hai Fu Huang; Yun He; Rui Jun Wang

doi:10.4028/www.scientific.net/MSF.789.415

Paper Titles

Investigation on the Micro-Structures and Properties of the P20 Steel Surface after Electrical Discharge Machining
p.391

Development and Application of Multivariable Composite Controller Based on Fuzzy Switching for Ultra Fast Cooling System
p.396

Effect of Ti Content on the Microstructure and Properties of TiC/TiB₂-FeNiCr Composite Prepared by Thermite Reaction
p.403

Hot Compression Deformation Behaviors and Microstructure Evolution for Brittle Au-20Sn Eutectic Alloy
p.409

Magnetic Properties of Cyano-Bridged Compound Co [Fe(CN)₅NO]·5H₂O
p.415

Magnetic and Mössbauer Studies on Mixed-Metal Cyano-Bridged Compounds Gu_nM_1.5-n[Fe(CN)₆]·xH₂O(M=Ni, Gu)
p.419

Microstructure and Mechanical Properties of Plasma Arc Welding Joint for Laser Melting-Deposited AerMet100 Ultrahigh-Strength Steel
p.424

Fabrication of Cu Heat Sink on Silicon Substrate Using Direct Laser Sintering
p.431

Microstructure Evolution of Laser Direct Deposited Ti-5Al-2Sn-2Zr-4Mo-4Cr Titanium Alloy
p.436

HomeMaterials Science ForumMaterials Science Forum Vol. 789Magnetic Properties of Cyano-Bridged Compound Co...

Magnetic Properties of Cyano-Bridged Compound Co [Fe(CN)₅NO]·5H₂O

Abstract:

The cyano-bridged complex Co [Fe (CN)₅NO]·5H₂O has been synthesized. According to the reaction of cyanide-based unsaturated ligand precursor (molecular fragments)[BL_y(CN)_x]^n-with the metal ions or complex unsaturated ligand, it is easy to control the structure of molecular magnets and tune up the magnetic properties. Hetero binuclear complex Co [Fe (CN)₅NO]∙5H₂O was prepared through [Fe (CN)₅NO]^2-ion. The room temperature Mossbauer spectrum revealed a doublet with the isomer shift parameter (-0.44(7) mm/s) and quadrupole splitting (QS = 1.91(3) mm / s) characteristic for low-spin Fe (III) ions. The low-spin (S = 1/2) of the Fe (III) ion of valence electrons on the electric field gradient (EFG) was caused by non-zero contribution. DC and AC magnetic measurements showed that the complexes belonged to the anti-ferromagnetic material, with a magnetic phase transition temperature below 2K.