Double Inhibitory Actions on WC Grains of Microwave Sintered WC-12wt%Co-VC Alloy

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It is well known that grain-refinement has a positive impact on the mechanical properties of WC-Co cemented carbide. The effect of VC inhibitor and microwave on density, microstructure and mechanical properties of the sintered WC–12wt%Co alloy was investigated in the present study. The ball milled WC-12wt%Co-xVC composites were compressed and fabricated by using microwave sintering method. The experimental results indicate that the microwave sintering cycle was significantly shorter to that of vacuum processing, and the density of bulk alloys increased with VC inhibitor contents and microwave sintering temperatures. Moreover, the microstructure observation of the sintered samples suggests that VC inhibitor had prominent inhibitory action on WC grains in microwave exposure, and the WC average grain size of alloy with 0.7wt%VC inhibitor was 0.43μm when the sintering temperature reached 1420°C. It is also evident that WC-12wt% alloys with an appropriate proportion of VC inhibitor exhibited higher hardness (92.1HRA) and better transverse rupture strength (2380MPa). And finally the mechanism of inhibitory effects on WC grains under microwave irradiation was discussed.

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April 2015

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[1] Z.Z. Fang, X. Wang, T. Ryu, K.S. Hwang, H.Y. Sohn, Synthesis, sintering and mechanical properities of nanocrystailline cemented tungste carbide-A review, International Journal of Refractory Metals and Hard Materials. 27(2009) 288-299.

DOI: 10.1016/j.ijrmhm.2008.07.011

Google Scholar

[2] B.R. Sunil, D. Sivaprahasam, R. Subasri, Microwave sintering of nanocrystalline WC–12Co: Challenges and perspectives, International Journal of Refractory Metals and Hard Materials, 28(2010) 180-186.

DOI: 10.1016/j.ijrmhm.2009.08.005

Google Scholar

[3] X. Song, Y. Gao, X. Liu, C. Wei, H. Wang, W. Xu, Effect of interfacial characteristics on toughness of nanocrystalline cemented carbides, Acta Materialia, 61(2013) 2154-2162.

DOI: 10.1016/j.actamat.2012.12.036

Google Scholar

[4] R. Bao, J. Yi, Densification and alloying of microwave sintering WC–8wt. %Co composites, International Journal of Refractory Metals and Hard Materials, 43(2014) 269-275.

DOI: 10.1016/j.ijrmhm.2013.12.010

Google Scholar

[5] C.M. Fernandes, A. M. R. Senos, Cemented carbide phase diagrams: A review, International Journal of Refractory Metals and Hard Materials, 29(2011) 405-418.

DOI: 10.1016/j.ijrmhm.2011.02.004

Google Scholar

[6] L. Gu, J. Huang, C. Xie, Effects of carbon content on microstructure and properties of WC–20Co cemented carbides, International Journal of Refractory Metals and Hard Materials, 42(2014) 228-232.

DOI: 10.1016/j.ijrmhm.2013.09.010

Google Scholar

[7] R. Bao, J. Yi, Effect of sintering atmosphere on microwave prepared WC-8wt. %Co cemented carbide, International Journal of Refractory Metals and Hard Materials, 41(2013) 315-321.

DOI: 10.1016/j.ijrmhm.2013.05.003

Google Scholar

[8] K.I. Rybakov, E. A. Olevsky, V. E. Semenov, The microwave ponderomotive effect on ceramic sintering, Scripta Materialia, 66(2012) 1049-1052.

DOI: 10.1016/j.scriptamat.2012.02.043

Google Scholar

[9] R. Bao, J. Yi, H. Zhang, Y. Peng, A research on WC–8Co preparation by microwave sintering, International Journal of Refractory Metals and Hard Materials, 32(2012) 16-20.

DOI: 10.1016/j.ijrmhm.2012.01.001

Google Scholar

[10] M. Oghbaei, O. Mirzaee, Microwave versus conventional sintering: A review of fundamentals, advantages and applications, Journal of Alloys and Compounds, 494(2010) 175-189.

DOI: 10.1016/j.jallcom.2010.01.068

Google Scholar

[11] A. Mondal, D. Agrawal, A. Upadhyaya, Microwave sintering of refractory metalsalloysW Mo Re W-Cu W-Ni-Cu and W-Ni-Fe alloys, Journal of Microwave Power and Electromagnetic Energy, 44(2010) 28-44.

DOI: 10.1080/08327823.2010.11689768

Google Scholar

[12] L. Sun, T. e. Yang, C. Jia, J. Xiong, VC, Cr3C2 doped ultrafine WC–Co cemented carbides prepared by spark plasma sintering, International Journal of Refractory Metals and Hard Materials, 29(2011) 147-152.

DOI: 10.1016/j.ijrmhm.2010.09.004

Google Scholar

[13] L. Yiwen, S. Ronglu, W. Enxi, T. Ying, Effects of Codoped VC/Cr3C2 on Microstructure and Properities of Ultrafine Cenmented carbides, Rare Metal Materials and Engineering, 38(2009) 229-235.

Google Scholar

[14] V. Bonache, M. D. Salvador, V. G. Rocha, A. Borrell, Microstructural control of ultrafine and nanocrystalline WC–12Co–VC/Cr3C2 mixture by spark plasma sintering, Ceramics International, 37(2011) 1139-1142.

DOI: 10.1016/j.ceramint.2010.11.026

Google Scholar

[15] X.Q. Ou, M. Song, T.T. Shen, D.H. Xiao, Y.H. He, Fabrication and mechanical properties of ultrafine grained WC–10Co–0. 45Cr3C2–0. 25VC alloys, International Journal of Refractory Metals and Hard Materials, 29(2011) 260-267.

DOI: 10.1016/j.ijrmhm.2010.11.004

Google Scholar

[16] G.S. Upadhyaya, Materials science of cemented carbides - an overview, Materials and Design, 22(2001) 483-489.

DOI: 10.1016/s0261-3069(01)00007-3

Google Scholar