Reactions of Limestone on the Slaking Process under Different Conditions of Parameters

Article Preview

Abstract:

The reaction of limestone in the slaking process has been studied under different conditions of parameters such as calcination times, soaking times and particle sizes. The reactivity of quicklime was determined by recording temperature rise and the rate of temperature rise during the slaking process. The obtained ‘milk of lime’ is characterized using instrumental measurements such as X-ray fluorescence (XRF) to identify the chemical composition that exists in the sample. In this paper, the quicklime used during slaking test indicates the differential of temperature pattern which influences by quicklime particle sizes, calcination temperatures and soaking times. Results indicate that the optimum and efficient distribution of heat transfer and thermal decomposition onto quicklime can be obtained by calcining at 1100 °C with 60 minutes of soaking time samples which produced a highly porous structure towards higher reactivity of quicklime.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

393-398

Citation:

Online since:

June 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Kemperl, J. Macek, Precipitation of Calcium Carbonate from Hydrated Lime of Variable Reactivity, Granulation and Optical Properties., Int. J. Miner. Process., 93 (2009), pp.84-88.

DOI: 10.1016/j.minpro.2009.05.006

Google Scholar

[2] F.C. Meldrum, H. Colfen, Controlling Mineral Morphologies and Structures in Biological and Synthetic Systems., Chem. Rev., 108 (2008), pp.4332-4432.

DOI: 10.1021/cr8002856

Google Scholar

[3] L. Xiang, Y. Xiang, Z.G. Wang, Y. Jin, Influence of Chemical Additives on the Formation of Super-Fine Calcium Carbonate., Powder Technology, 126 (2002), pp.129-133.

DOI: 10.1016/s0032-5910(02)00047-5

Google Scholar

[4] Y.S. Han; G. Hadiko, M. Fuji, M. Takahashi, Effect of Flow Rate and CO2 Content on the Phase and Morphology of CaCO3 Prepared by Bubbling Method., Journal of Crystal Growth, 276 (2005), pp.541-548.

DOI: 10.1016/j.jcrysgro.2004.11.408

Google Scholar

[5] W.M. Jung, S.H. Kang, W.S. Kim, C.K. Choi, Particle Morphology of Calcium Carbonate Precipitated by Gas-Liquid Reaction in a Couette-Taylor Reactor., Chemical Engineering Science., 55 (2000), pp.733-747.

DOI: 10.1016/s0009-2509(99)00395-4

Google Scholar

[6] M. Matsumoto, T. Fukunaga, K. Onoe, Polymorph Control of Calcium Carbonate by Reactive Crystallization using Microbubble Technique., Chemical Engineering Research and Design, 88 (2010), pp.1624-1630.

DOI: 10.1016/j.cherd.2010.02.007

Google Scholar

[7] S. Teir, S. Eloneva, R. Zevenhoven, Production of Precipitated Calcium Carbonate from Calcium Silicates and Carbon Dioxide, Energy Conversion and Management, 46 (2005), pp.2954-2979.

DOI: 10.1016/j.enconman.2005.02.009

Google Scholar

[8] M.M.M.G.P.G. Mantilaka, D.G.G.P. Karunaratne, R.M.G. Rajapakse, H.M.T.G.A. Pitawala, Precipitated Calcium Carbonate/Poly(Methyl Methacrylate) Nanocomposite using Dolomite: Synthesis, Characterization and Properties., Powder Technology, 235 (2013).

DOI: 10.1016/j.powtec.2012.10.048

Google Scholar

[9] H.A. Jakobsen, M. Mork, A. Grislingas, Stirred Tank Reactors.

Google Scholar

[10] A.W. Nienow, On Impeller Circulation and Mixing Effectiveness in the Turbulent Flow Regime, Chemical Engineering Science, 52 (1997), pp.2557-2565.

DOI: 10.1016/s0009-2509(97)00072-9

Google Scholar

[11] T. Kumaresan, J.B. Joshi, Effect of Impeller Design on the Flow Pattern and Mixing in Stirred Tanks, Chemical Engineering Journal, 115 (2006), pp.173-193.

DOI: 10.1016/j.cej.2005.10.002

Google Scholar

[12] J. Aubin, C. Xuereb, Design of Multiple Impeller Stirred Tanks for the Mixing of Highly Viscous Fluids using CFD, Chemical Engineering Science, 61 (2006), pp.2913-2920.

DOI: 10.1016/j.ces.2005.10.075

Google Scholar

[13] W.N. Al Nasser, A.H. Al Ruwaie, M.J. Hounslow, A.D. Salman, Influence of Electronic Antifouling on Agglomeration of Calcium Carbonate, Powder Technology, 206 (2011), pp.201-207.

DOI: 10.1016/j.powtec.2010.07.010

Google Scholar

[14] H.V. Tran, L.D. Tran, H.D. Vu, H. Thai, Facile Surface Modification of Nanoprecipitated Calcium Carbonate by Adsorption of Sodium Stearate in Aqueous Solution., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 366 (2010).

DOI: 10.1016/j.colsurfa.2010.05.029

Google Scholar

[15] Helmut Colfen, Precipitation of Carbonates: Recent Progress in Controlled Production of Complex Shapes., Current Opinion in Colloid and Interface Science, 8 (2003), pp.23-31.

DOI: 10.1016/s1359-0294(03)00012-8

Google Scholar

[16] R. Isopescu, C. Mateescu, M. Mihai, G. Dabija, The Effects of Organic Additives on Induction Time and Characteristics of Precipitated Calcium Carbonate, Chemical Engineering and Design, 88 (2010), pp.1450-1454.

DOI: 10.1016/j.cherd.2009.10.002

Google Scholar

[17] J.G. Carmona, J.G. Morales, J.F. Sainz, R.R. Clemente, Morphological Characteristics and Aggregation of Calcite Crystal Obtained by Bubbling CO2 through a Ca(OH)2 Suspension in the Presence of Additives, Powder Technology, 130 (2003), pp.307-315.

DOI: 10.1016/s0032-5910(02)00209-7

Google Scholar

[18] W.K. Park, S.J. Ko, S.W. Lee, K.H. Cho, J.W. Ahn, C. Han, Effects of Magnesium Chloride and Organic Additives on the Synthesis of Aragonite Precipitated Calcium Carbonate, Journal of Crystal Growth, 310 (2008), pp.2593-2601.

DOI: 10.1016/j.jcrysgro.2008.01.023

Google Scholar

[19] H. Wei, Q. Shen, Y. Zhao, D.J. Wang, D.F. Xu, Influence of Polyvinylpyrrolidone on the Precipitation of Calcium Carbonate and on the Transformation of Vaterite to Calcite, Journal of Crystal Growth, 250 (2003), pp.516-524.

DOI: 10.1016/s0022-0248(02)02484-3

Google Scholar

[20] S.Y. Park, W.S. Choi, Effects of Operating Factors on the Particle Size Dstribution and Particle Shape of Synthesized Precipitation CaCO3: Effect of Reaction Temperature, Blowing Rate of CO2 Gas and Initial Slurry Concentration of Ca(OH)2 on Reaction Completion Time., Advanced Powder Technology, 15 (2004).

DOI: 10.1163/15685520460740034

Google Scholar

[21] J. Chen, L. Xiang, Controllable Synthesis of Calcium Carbonate Polymorphs at Different Temperatures., Powder Technology, 189 (2009), pp.64-69.

DOI: 10.1016/j.powtec.2008.06.004

Google Scholar

[22] D. Carran, J. Hughes, A. Leslie, C. Kennedy, The Effect of Calcination Time upon the Slaking Properties of Quicklime, in Historic Mortars: Characterisation, Assessment and Repair. vol. 7, J. Valek et. al., ed RILEM Bookseries, (2012), pp.283-295.

DOI: 10.1007/978-94-007-4635-0_22

Google Scholar

[23] H.G. Shin, H. Kim, Y. N. Kim, H.S. Lee, Effect of Reactivity of Quick Lime on the Properties of Hydrated Lime Sorbent for SO2 Removal., Journal Material Science Technology, 25 (2009), pp.229-332.

Google Scholar

[24] J.R. Rosell, L. Haurie, A. Navarro, I.R. Cantalapiedra, Influence of the traditional slaking process on the lime putty characteristics, Construction and Building Materials, 55 (2014), pp.423-430.

DOI: 10.1016/j.conbuildmat.2014.01.007

Google Scholar

[25] J. Lanas, J.I. Alvarez, Dolomitic Limes: Evolution of the Slaking Process under Different Conditions, Thermochimica Acta, 423 (2004), pp.1-12.

DOI: 10.1016/j.tca.2004.04.016

Google Scholar