Phase Transitions in Perovskite Phases of Strontium Silicoantimonates

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The paper presents the results of the study of phase transitions in the system Sr-Sb-Si-O by means of X-ray diffraction, thermal analysis, dielectric spectroscopy. Four effects are observed in the interval from room temperature to 800°C. The first and last are chemical transformations due to dehydration and loss of oxygen, respectively. The second is a transition from tetragonal to cubic perovskite structure, and the third is disordering transition in oxygen sublattice possibly due to the desorption of structural water molecules

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34-37

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March 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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