Role of Ionics Surfactant in Synthesizing Cerate-Zirconate Ceramic Powder

Nurul Asyikin Mazlan; Nafisah Osman; Abdul Mutalib Md Jani; Mohd Hafiz Yaakob

doi:10.4028/www.scientific.net/MSF.846.205

Paper Titles

Effect of Neodymium Concentration on Structural and Optical Properties of Tellurite Based Glass System
p.183

Preparation of SiO₂-Na₂O-CaO-P₂O₅ Glass-Ceramic from Waste Materials and Heat Treatment Effects on its Morphology
p.189

Optical Properties of Nd Doped Lead Borotellurite Glass
p.193

Microstructure of Barium Cerate-Zirconate Ceramics Prepared by a Two-Step Sintering Technique
p.199

Role of Ionics Surfactant in Synthesizing Cerate-Zirconate Ceramic Powder
p.205

Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃_-δ (BSCF) Perovskite Nanorods by Template Synthesis
p.210

The Suitability of Rice Straw Ash as a Precursor for Synthesizing β-Wollastonite
p.216

Composition Effect of Poly(3,4-Ethylenedioxythiophene):Poly(Styrene Sulphonic Acid) and Polyaniline to Dispersion and Optical Properties of Polymer Blends
p.225

Optimization of Silicon-Based Fabrication Process Modeling for Optical Modulator
p.230

HomeMaterials Science ForumMaterials Science Forum Vol. 846Role of Ionics Surfactant in Synthesizing...

Role of Ionics Surfactant in Synthesizing Cerate-Zirconate Ceramic Powder

Abstract:

BaCe_0.54Zr_0.36Y_0.1O_2.95(denoted as BCZY10) ceramic powder was synthesized by a modified sol-gel method using metal nitrate salts as precursors. The samples were prepared using two different types of surfactants which are cationic surfactant of hexadecyldimethylammonium bromide (HTAB), nonionic surfactant of polyoxyethylene (10) oleyl ether (Brij 97), and sample without surfactant as a control. All samples were labeled as S1, S2, and S3 respectively. They were dried and calcined at T=325 °C and T=1100 °C accordingly. Chemicals bonding of the compound were analyzed using Fourier transform infrared (FTIR) spectrometry and their phase formation was identified by X-Ray Diffractometer (XRD). All the dried samples showed the adsorption peak at 3200-3700 cm^-1that related to the overlapping of OH stretching originated from –OH terminal group and N-H stretching vibrations. The peaks appeared at 1620-1640 cm^-1 can be assigned to C=O stretching and at 1380-1450 cm^-1 can be attributed for N-H bending vibration. The adsorption peak ≈500 cm^-1of metal-oxygen bond for all the calcined samples became pronounces indicating that the metal complexes were transformed to metal oxides. XRD results confirmed that S2 and S3 formed a single-phase of Ba (Ce,Zr)O₃perovskite type-oxide and S1 consists of multi-phases compound which are dominated by BaCeO₃, and BaZrO₃. Therefore, the used of different type of surfactant was found to give a significant effect on the synthesizing single-phase of BCZY10 ceramics compound.

You might also be interested in these eBooks

Main Tendencies in Applied Materials Science

View Preview

Info:

Periodical:

Materials Science Forum (Volume 846)

Pages:

205-209

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.846.205

Citation:

Cite this paper

Online since:

March 2016

Authors:

Nurul Asyikin Mazlan, Nafisah Osman*, Abdul Mutalib Md Jani, Mohd Hafiz Yaakob

Keywords:

Cerate-Zirconate, Modified Sol-Gel Method, Surfactants

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] N. Osman, I.A. Talib, H.A. Hamid, Ionics. 16 (2010) 561-569.

Google Scholar

[2] N. Osman, N.A. Abdullah, S. Hasan, R.M. Nordin, APCBEE Procedia. 3 (2012) 28-32.

Google Scholar

[3] P. Sawant, S. Varma, B.N. Wani, S.R. Bharadwaj, International Journal of Hydrogen Energy. 37 (2012) 3848-3856.

Google Scholar

[4] J. Chandradass, and K.H. Kim, Journal of Crystal Growth, 311 (2009) 3631-3635.

Google Scholar

[5] S. Alamolhoda, S.A. Seyyed Ebrahimi, A. Badiei, Journal of Magnetism and Magnetic Materials, 303 (2006) 69-72.

Google Scholar

[6] G.Y. Zhang, Y.Y. Xu, D.Z. Gao, Y.Q. Sun, Journal of Alloys and Compounds 509 (2011) 885-890.

Google Scholar

[7] Y. Li, R. Guo, C. Wang, Y. Liu, Z. Shao, J. An, C. Liu, Electrochimica Acta. 95 (2013) 95-101.

Google Scholar

[8] S. Wang, L. Zhao, L. Zhang, F. Chen, Solid State Ionics. 213 (2012) 29-35.

Google Scholar

[9] S. Ricote, G. Caboche, O. Heintz, Journal of Applied Electrochemistry. 39 (2009) 553-557.

Google Scholar

[10] J. Cai, K. Laubernds, F.S. Galasso, S.L. Suib, J. Liu, X.F. Shen, E. Begge, H.R. Kunz, J.M. Fenton, Journal of American Ceramic Society 88(10) (2005) 2729.

Google Scholar

[11] R.R. T.C.S. Chien, V. Hugo Schmidt, S-C. Lee, C-C. Huang, Solid States Ionics. 181 (2010) 1251-1257.

Google Scholar

[12] S. Emami, H.R. Masaah Hosseini, A. Dolati, Russian Journal of Non-Ferrous Metals. 53 (2012) 308-314.

Google Scholar

[13] F. Ejehi, S.P.H. Marashi, M.R. Ghaani, D.F. Haghshenas, Ceramic International. 38 (2012) 6857-6863.

DOI: 10.1016/j.ceramint.2012.05.086

Google Scholar

[14] A. Chakroborty, A.D. Sharma, B. Maiti, H.S. Maiti, Material Letters. 57 (2002) 862.

Google Scholar

[15] M. Motta, C.V. Deimling, M.J. Saeki, Sol-gel Science and Technology. 46 (2008) 201-207.

Google Scholar