Electrochemical Properties of Glyme Based Plasticizer on Gel Polymer Electrolytes Doped with Lithium Bis(Trifluoromethanesulfonyl)Imide

Abstract:

In this study, gel polymer electrolytes (GPEs) system is prepared by the solution cast technique. The system consists of cellulose acetate (CA) as a host polymer, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) as a dopant salt and diethylene glycol dibutylether (BDG) from glyme based family as a plasticizer. GPEs (65 wt. % CA–25 wt. % LiTFSI–10 wt. % BDG) sample is the highest conductivity of 2.88×10^-3 S.cm⁻¹ at room temperature. The lithium-electrolyte interfaced stability is established and the highest ionic conducting electrolyte is able to withstand up to 3.8V vs Li/Li⁺.

• Periodical: Materials Science Forum (Volume 846)
• Pages: 534-538
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.846.534
• Online since: March 2016
• Authors: S.M.M. Razalli, S.I.Y.S.M. Saaid, Tengku Ishak Tengku Kudin, Muhd Zu Azhan Yahya, Oskar Hasdinor Hassan, Abdul Malik Marwan Bin Ali*
• Keywords: Cellulose Acetate, Diethylene Glycol Dibutylether, Electrochemical Impedance Spectroscopy, Lithium Bis(Trifluoromethanesulfonyl)Imide

References

[1] P.V. Wright: British Polym, J. 7 (1975) 319.

[2] M.B. Armand, J.M. Chabagno, M.J. Dulcot, In: J.N. Mundy and G.K. Shenoy, eds.P. Vashishta, North-Holland, Amsterdam (1979) 131-136.

[3] S.Z.Z. Abidin, A.M.M. Ali, O.H. Hassan, M.Z.A. Yahya: Int. J. Electrochem. Sci., 8 (2013) 7320 – 7326.

[4] Y.S. Yun, S.W. Song S.Y. Lee, S.H. Kim, D.W. Kim: Current Applied Physics 10 (2010) 17-20.

[5] G.G. Kumar, N. Munichandraiah: Solid State Ionics, 128 (2000). 203-210.

[6] P. Chiodelli, G. Ferloni, P. Magistris, A. Sanesi, Solid States Ionics, 28-30, (1988), 1009-1013.

[7] N.A. Johari, T.I.T. Kudin, A.M. M Ali, M.Z.A. Yahya, Proceedings of the National Academy of Sciences India Section A - Physical Sciences, 82, (2012), 49-52.

[8] A.S. Kamisan, T.I. T Kudin, A.M.M. Ali, M.Z.A. Yahya: Electrochimica Acta 57, (2011) 207-211.

[9] S.M.M. Razalli, S.I.Y.S.M. Saaid, A.M.M. Ali, O.H. Hassan, M.Z.A. Yahya: Functional Materials Letter, 8(2015)1-4.

[10] S. Ramesh, R. Shanti, Ezra Morris: Carbohydrates Polymers 91, (2013)14-21.

[11] C. Zhang, K. Ueno, A. Yamazaki, K. Yoshida, H. Moon, T. Mandai, Y. Umebayashi, K. Dokko, and M. Watanabe: The Journal of Physical Chemistry B118, (2014) 5144-5153.

DOI: 10.1021/jp501319e

[12] M.R. Johan, O.H. Shy, S. Ibrahim, S.M.M. Yassin, T.Y. Hui: Solid States Ionics, 196 (2011), 41-47.

[13] C.W. Liew, S. Ramesh, K. Ramesh, A.K. Arof: J Solid State Electrochem, 16 (2012), 1869-1875.

[14] S. I. Y. Saaid, T. I. T. Kudin, A.M.M. Ali, A.H. Ahmad, M.Z.A. Yahya: Materials Research Innovations, 13 (2009), 252 - 254.

[15] A.S.A. Khiar, R. Puteh and A.K. Arof: Physica B: Condensed Matter, 373 (2006), 23-27.

DOI: 10.1016/j.physb.2005.10.104

[16] N.K. Idris, N.A.N. Aziz, M.S.M. Zambri, N.A. Zakaria and M.I.N. Isa: Ionics, 15 (2009), 643-646.

[17] C.O. Avellaneda, D.F. Vieira, A. Al-Kahlout, E.R. Leite, A. Pawlicka and M.A. Aegerter: Electrochimica Acta, 53 (2007), 1648-1654.

DOI: 10.1016/j.electacta.2007.05.065