In Situ Growth of Mullite Whisker Using Different Aluminium Source and Properties of Mullite-Corundum Lightweight Refractory

Abstract:

In-situ growth of mullite whisker from waste coal gangue and different aluminium source mixtures by dry pressing were investigated aiming at the preparation of mullite - corundum lightweight refractory by controlling mullite whisker precursor pseudo particle size and quantity in corundum matrix. The phase composition and microstructure were studied using X-ray diffraction (XRD) and scanning electron microscope (SEM) techniques. Apparent porosity and bending strength were also measured. The samples exhibited characteristic alumina and mullite phases. The formation mechanism and influence factors for mullite whiskers materials were discussed. The experimental results showed that the whisker of the obtained sample changed from the accumulated short column to mesh cross acicular whisker shape, and the length to diameter ratio increases. When the aluminium source was aluminium hydroxide, the length to diameter ratio and apparent porosity reached the maximum of 17.6 and the minimum of 2.15%. The bending strength of all the samples was similar, that of the sample prepared by calcined bauxite was the largest (84 MPa), that of the sample prepared by calcined alumina was inferior, and the sample prepared by aluminum hydroxide was the lowest.

• Periodical: Materials Science Forum (Volume 848)
• Pages: 328-332
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.848.328
• Online since: March 2016
• Authors: Xin Hao Li, Xing Yong Gu*, Wei Xia Dong, Ting Luo
• Keywords: Aluminium Source, Coal Gangue, Dry Pressing, In Situ Growth, Mullite Whiskers

References

[1] A. Gungor, O. Celikcioglu, S. Sahin, The physical and mechanical properties of alumina-based ultralow cement castable refractories, Ceramics International, 38 (2012) 4189-4194.

DOI: 10.1016/j.ceramint.2012.02.001

[2] J. Yuan, Z. Liu, Y. Han, New growth technology and mechanism of mullite whiskers, Journal of Inorganic Materials，1 (1996) 101-106.

[3] Osayande L. Ighodaro, Okenwa I. Okoli, Fracture toughness enhancement for alumina Systems: A review, International Journal of Applied Ceramic Technology, 5(2008) 313–323.

DOI: 10.1111/j.1744-7402.2008.02224.x

[4] H. Schneidera, J. Schreuerb, B. Hildmanna, Structure and properties of mullite, Journal of the European Ceramic Society, 28 (2008) 329-344.

[5] T. M. Souza, A. P. Luz, M .A. M. Brito, V. C. Pandolfelli, In situ elastic modulus evaluation of Al2O3–MgO refractory castables, Ceramics International, 40 (2014) 699-1707.

DOI: 10.1016/j.ceramint.2013.07.066