The Effect of Mg Content on Intergranular Corrosion of Al-Mg-Mn Alloys after Annealing

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Abstract:

The Intergranular Corrosion (IGC) properties of Al-xMg-0.6Mn (x=3, 4, 5, 6 and 7) wt.% alloys were studied using the mass loss test. The mass loss test results of the alloys annealed at 100-300 ̊C for 1h indicated that the alloys with 3 and 4% Mg were resistant to IGC. While the mass loss values of the 6 and 7% Mg alloys were increased to IGC severe sensitive region, and then abruptly fallen to the IGC-resistant region with the increasing temperature. The mass loss-temperature curve of 5% Mg alloy was actually located between them. After isothermal annealing, the mass loss results indicated a stabilization temperature of the alloys with 5, 6 and 7% Mg appeared at the temperature beyond 220 ̊C, 250 ̊C and 270 ̊C, respectively. Furthermore, below the stabilization temperature 10-20 ̊C, it was observed a type of “special mass loss curve ” in so-called transition region that was showed a quick mass loss increasing to sensitization region and then a decrease to the IGC resistant region with a prolonged annealing time. To explore the “special curve” in transition region, the TEM observation of Al-7Mg alloy annealing at 250 ̊C was conducted, which indicated the sensitization resulted from the continuity of β phase, while the descending to the IGC might to be attributed to the spheroidization of β phase.

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November 2016

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[1] J. R. Davis, Aluminum and aluminum alloys, ASM International, (1993).

Google Scholar

[2] J. R. Davis, Corrosion of aluminum and aluminum alloys, Asm International, (1999).

Google Scholar

[3] Z. M. Yin, D. P. Zhu, F. Jiang, Recrystallization of Al-Mg-Mn and Al-Mg-Mn-Sc-Zr alloys, Cailiao Gongcheng (J. Mater. Eng. )(China), (2004) 3-6.

Google Scholar

[4] N. Sukiman, A. Hughes, G. Thompson, J. Mol, N. Birbilis, S. Garcia, X. Zhou, Durability and corrosion of aluminium and its alloys: overview, property space, techniques and developments, INTECH Open Access Publisher, (2012).

DOI: 10.5772/53752

Google Scholar

[5] E. Dix Jr, W. Anderson, M.B. Shumaker, Influence of service temperature on the resistance of wrought aluminum- magnesium alloys to corrosion, Corrosion, 15 (1959) 55-62.

DOI: 10.5006/0010-9312-15.2.19

Google Scholar

[6] G. Argade, N. Kumar, R. Mishra, Stress corrosion cracking susceptibility of ultrafine grained Al–Mg–Sc alloy, Materials Science and Engineering: A, 565 (2013) 80-89.

DOI: 10.1016/j.msea.2012.11.066

Google Scholar

[7] R. Goswami, G. Spanos, P. Pao, R. Holtz, Precipitation behavior of the ß phase in Al-5083, Materials Science and Engineering: A, 527 (2010) 1089-1095.

DOI: 10.1016/j.msea.2009.10.007

Google Scholar

[8] R. Goswami, R. L. Holtz, Transmission electron microscopic investigations of grain boundary beta phase precipitation in Al 5083 aged at 373 K (100 C), Metallurgical and Materials Transactions A, 44 (2013) 1279-1289.

DOI: 10.1007/s11661-012-1166-9

Google Scholar

[9] Y. Zhu, D. A. Cullen, S. Kar, M. L. Free, L.F. Allard, Evaluation of Al3Mg2 precipitates and Mn-rich phase in aluminum-magnesium alloy based on scanning transmission electron microscopy imaging, Metallurgical and Materials Transactions A, 43 (2012).

DOI: 10.1007/s11661-012-1354-7

Google Scholar

[10] W. D. Ren, J.F. Li, Z. Q. Zheng, W.J. Chen, Localized corrosion mechanism associated with precipitates containing Mg in Al alloys, Transactions of Nonferrous Metals Society of China, 17 (2007) 727-732.

DOI: 10.1016/s1003-6326(07)60164-2

Google Scholar

[11] D. H. Choi, B. W. Ahn, D. J. Quesnel, S. -B. Jung, Behavior of β phase (Al3Mg2) in AA 5083 during friction stir welding, Intermetallics, 35 (2013) 120-127.

DOI: 10.1016/j.intermet.2012.12.004

Google Scholar

[12] Y. K. Yang, T. Allen, Direct visualization of β phase causing intergranular forms of corrosion in Al–Mg alloys, Materials Characterization, 80 (2013) 76-85.

DOI: 10.1016/j.matchar.2013.03.014

Google Scholar

[13] L. Kramer, M. Phillippi, W. Tack, C. Wong, Locally reversing sensitization in 5xxx aluminum plate, Journal of materials engineering and performance, 21 (2012) 1025-1029.

DOI: 10.1007/s11665-011-9998-9

Google Scholar

[14] S. Jain, M. Lim, J. Hudson, J. Scully, Spreading of intergranular corrosion on the surface of sensitized Al-4. 4 Mg alloys: A general finding, Corrosion Science, 59 (2012) 136-147.

DOI: 10.1016/j.corsci.2012.02.018

Google Scholar

[15] A.S. f. Testing, Materials, Standard Test Method for Determining the Susceptibility to Intergranular Corrosion of 5XXX Series Aluminum Alloys by Mass Loss After Exposure to Nitric Acid (NAMLT Test), ASTM International, (2004).

DOI: 10.1520/g0067

Google Scholar

[16] Z.M. Yin, D.P. Zhu, F. Jiang, Recrystallization of Al-Mg-Mn and Al-Mg-Mn-Sc-Zr alloys, J. Mater. Eng. (2004) 3-6.

Google Scholar

[17] J. Searles, P. Gouma, R. Buchheit, Stress corrosion cracking of sensitized AA5083 (Al-4. 5 Mg-1. 0 Mn), Metallurgical and Materials Transactions A, 32 (2001) 2859-2867.

DOI: 10.1007/s11661-001-1036-3

Google Scholar