Environment-Assisted Cracking of Super-Elastic TiNi Alloy Depending on Solution pH and Electrochemical Potential

Article Preview

Abstract:

The behavior of environment-assisted cracking (EAC) for super-elastic TiNi alloy was investigated as functions of solution pH and electrochemical potential. The specimen was immersed in sulfate solutions at various pHs, and subjected to a potentiostatic slow strain rate tensile test. As a result, the EAC map for the TiNi alloy as functions of the solution pH and the applied potential was successfully produced, and it was revealed that larger EAC susceptibility was obtained in the region of lower potential and lower pH. The tendency was quite typical for hydrogen embrittlement, but not similar to that of TiAl. The EAC susceptibility was classified by cathodic charge density, irrespective to pH nor potential: The charge density larger than 0.025 MC.m-2 induced a maximum EAC susceptibility.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

709-713

Citation:

Online since:

November 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] E. F. Harris, S. M. Newman and J. A. Nicholson, Am. J. Orthod. Dentofacial. Orthop., 93 (1988), 508-513.

Google Scholar

[2] C. Heintz, G. Riepe, L. Birken, E. Kaiser, N. Chakfe, M. Morlock, G. Delling and H. Imig, J. Endovasc. Ther., 8 (2001), 248-253.

DOI: 10.1177/152660280100800303

Google Scholar

[3] M. Kh. Shorshorov, I. A. Stepanov, Yu. M. Flomenblit and V. V. Travkin, Fiz. Met. Metall., 60 (1985), 326-333.

Google Scholar

[4] N. Wade, Y. Hosoi and Y. Adachi, J. Jpn. Inst. Metals, 54 (1990), 525-531.

Google Scholar

[5] T. Asaoka, H. Yamashita, H. Saito and Y. Ishida, J. Jpn. Inst. Metals, 57 (1993), 1123-1129.

Google Scholar

[6] K. Yokoyama, T. Ogawa, K. Takashima, K. Asaoka and J. Sakai, Mater. Sci. Eng. A, 466 (2007), 106-113.

Google Scholar

[7] T. Haruna, T. Shibata, T. Iwata and T. Sundararajan, Intermetallics, 8 (2000), 929-935.

Google Scholar

[8] T. Haruna, T. Iwata, T. Sundararajan and T. Shibata, Mater. Sci. Eng. A, 329-331 (2002), 745-749.

Google Scholar

[9] M. Pourbaix, Atlas of electrochemical equilibria in aqueous solutions (Oxford, UK, Pergamon Press, 1966).

Google Scholar

[10] M. Pourbaix, (RT-146 Rapports Techniques CEBELCOR, 1968) 107.

Google Scholar

[11] M. Pourbaix and J. C. Scully, The theory of stress corrosion cracking in alloys, ed. J. C. Scully (Brussels, Belgium, North Atlantic Treaty Organization 1971), 17.

Google Scholar

[12] T. Haruna, M. Hamasaki and T. Shibata, Mater. Trans., 46 (2005), 2190-2196.

Google Scholar

[13] T. Haruna and M. Fuseya, Proc. of JSCE Mater. Environments. 2004 (Tokyo, Japan, Japan Society of Corrosion Engineering 2004), 289-290.

Google Scholar

[14] M. A. V. Devanathan and Z. Stachurski, Proc. R. Soc. Lond. A., 270 (1962), 90-102.

Google Scholar

[15] S. Yoshizawa, T. Tsuruta and K. Yamakawa, Boshoku-Gijutsu, 24 (1975), 511-515.

Google Scholar