Trace Al-Ti-C-Ce on Solidification Structure Transformation and Fracture Properties of Al-Cu-Mn Alloy

Article Preview

Abstract:

As a kind of refining agent, Al-Ti-C-Ce intermediate alloy is widely used in the field of nonferrous alloy smelting. The effect of Al-Ti-C-Ce contents on microstructure and properties of Al-Cu-Mn alloy was studied by OM, SEM, EDS and other test methods. The results show that the as-cast microstructure of Al-Cu-Mn alloy is obviously refined after adding 0.1% Al-Ti-C-Ce, and the θ phase is characterized with the shape of point or strip. With the increase of the addition amounts, parts of the grains coarsened. When the addition amount reached to 0.3%, the refinement effect of the alloy microstructure was further reduced, and the number of intergranular precipitates TiC and Al3Ti increased. Ductile fracture is the main failure mode of the alloy. After T6 heat treatment, the grain size changed little, and the number of θ phase, TiC and Al3Ti decreased, changed from the mesh to the point or needle or strip structure, and the proportion of alloy ductile fracture increased. The addition of Al-Ti-C-Ce has positive effect on improving the microstructure and properties of Al-Cu-Mn alloy.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

69-76

Citation:

Online since:

February 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] B. Liu, C.Q. Peng, R.C. Wang, Recent development and prospects for giant plane aluminum alloys, Chin J Nonferrous Met. 20 (2010) 1705-1715.

Google Scholar

[2] M. Nakai, T. Eto, New aspect of development of high strength aluminum alloys for aerospace applications, Mater. Sci. Eng. A. 285 (2000) 62-68.

DOI: 10.1016/s0921-5093(00)00667-5

Google Scholar

[3] B.S. Murty, S.A. Kori, M. Chakraborty, Grain refinement of aluminium and its alloys by heterogeneous nucleation and alloying, Int Mater Rev. 47 (2002) 3-29.

DOI: 10.1179/095066001225001049

Google Scholar

[4] Z. Tan, Y.F. Xue, X.W. Cheng, Effect of element fitting on composition optimization of Al–Cu–Ti amorphous alloy by mechanical alloying, T Nonferr Metal Soc. 25 (2015) 3348-3353.

DOI: 10.1016/s1003-6326(15)63969-3

Google Scholar

[5] F. Gazanion, X.G. Chen, C. Dupuis, Studies on the Sedimentation and Agglomeration Behavior of Al-Ti-B and Al-Ti-C Grain Refiners, Mater Sci Forum. 396-402 (2002) 45-52.

DOI: 10.4028/www.scientific.net/msf.396-402.45

Google Scholar

[6] B.S. Murty, S.A. Kori, M. Chakraborty, Grain refinement of aluminium and its alloys by heterogeneous nucleation and alloying, Int Mater Rev. 47 (2002) 3-29.

DOI: 10.1179/095066001225001049

Google Scholar

[7] A.M. Bunn, P. Schumacher, M.A. Kearns, Grain refinement by Al-Ti-B alloys in aluminium melts: a study of the mechanisms of poisoning by zirconium, Mater Sci Technol-lond. 15 (1999) 1115-1123.

DOI: 10.1179/026708399101505158

Google Scholar

[8] W.W. Ding., T.D. Xia, W.J. Zhao, Refining performances of TiC and TiAl3 phases in master alloys on pure aluminum, Chin J Nonferrous Met. 19 (2009) 1025-1031.

Google Scholar

[9] T.D. Xia, W.W Ding., W.W. Zhao, Effect of TiAl3 on distribution of TiC particles in aluminum matrix and nucleation of α(Al) grain, Chin J Nonferrous Met. 19 (2009) 1948-(1955).

Google Scholar

[10] J.G. Li, M. Huang, M. Ma, Performance comparison of AlTiC and AlTiB master alloys in grain refinement of commercial and high purity aluminum, T Nonferr Metal Soc. 16 (2006) 242-253.

DOI: 10.1016/s1003-6326(06)60042-3

Google Scholar

[11] G.Y. Hu, S.Y. Chen, H.L. Jiang, Effect of RE Ce on microstructure and properties of 7A52 aluminum alloy, Chin J Nonferrous Met. 26(2016) 1372-1382.

Google Scholar

[12] G.R. Li, H.M. Wang, Y.T. Zhao, Effect Mechanism of Yttrium on Melting and Solidification of 7055 Aluminum Alloy, Rare Metal Mat Eng. 39 (2010) 80-84.

Google Scholar

[13] X.M. Zhang, J. Liu, L.Y. Ye, Influence of Cerium Addition on the Impact Resistance of 2519A Aluminum Alloy, Rare Metal Mat Eng. 42 (2013) 120-125.

Google Scholar

[14] J.Y. Liu, F. Xu, Z. Miao, Influence of Cerium-Rich Mischmetal on the Microstructure and Mechanical Properties of Al-4.5Cu Binary Alloys, Rare Metal Mat Eng. 2011 (S2) 573-576.

Google Scholar

[15] Y. Birol, A novel Al-Ti-B alloy for grain refining Al-Si foundry alloys, J. Alloys Comp. 486 (2009) 219-222.

DOI: 10.1016/j.jallcom.2009.07.064

Google Scholar

[16] Y.L. Li, H.K. Feng, F.R. Cao, Effect of high density ultrasonic on the microstructure and refining property of Al-5Ti-0.25C grain refiner alloy, Mater. Sci. Eng. A. 487 (2008) 518-523.

DOI: 10.1016/j.msea.2007.11.067

Google Scholar

[17] G.S. Kumar, B.S. Murty, M. Chakraborty, Development of Al-Ti-C grain refiners and study of their grain refining efficiency on Al and Al-7Si alloy, J. Alloys Comp. 396 (2005) 143-150.

DOI: 10.1016/j.jallcom.2004.12.039

Google Scholar

[18] H.L. Zhao, J.S. Yue, Y. Gao, Grain and dendrite refinement of A356 alloy with Al-Ti-C-RE master alloy, Rare Metals. 32 (2013) 12-17.

DOI: 10.1007/s12598-013-0021-5

Google Scholar

[19] L.D. Wang, D.Y. Zhu, Z.L. Wei, The Refinement Effect of Al-Ti-C-RE Master Alloy Prepared by Adding Ce2O3 on Pure Al, Adv Mater Res. (2010) 139-141 227-234.

DOI: 10.4028/www.scientific.net/amr.139-141.227

Google Scholar

[20] H.Zhao, Y.Song, M.Li, Grain refining efficiency and microstructure of Al-Ti-C-RE master alloy, J. Alloys Comp. 508 (2010) 206-211.

DOI: 10.1016/j.jallcom.2010.08.047

Google Scholar

[21] P.S. Mohanty, J.E. Gruzleski, Grain refinement of aluminium by TiC, Scripta Mater. 31 (1994) 179-184.

DOI: 10.1016/0956-716x(94)90171-6

Google Scholar

[22] A. Banerji, W. Reif, Metallographic investigation of TiC nucleants in the newly developed Al-Ti-C grain refiner, J Mater Sci. 29 (1994) 1958-(1965).

DOI: 10.1007/bf00351320

Google Scholar

[23] M. Johnsson, L. Bäckerud, The Influence of Composition on Equiaxed Crystal Growth Mechanisms and Grain Size in Al Alloys, Z Metallkd. 87 (1996) 216-220.

DOI: 10.1515/ijmr-1996-870312

Google Scholar