Synthesis, Short-Range Structure and Hydration Processes of Oxyhalides Ba2InO3X (X = F, Cl, Br) with Ruddlesden-Popper Structure

Nataliia Tarasova; Irina Animitsa

doi:10.4028/www.scientific.net/MSF.916.130

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Synthesis, Short-Range Structure and Hydration Processes of Oxyhalides Ba₂InO₃X (X = F, Cl, Br) with Ruddlesden-Popper Structure

Abstract:

The oxyhalides Ba₂InO₃F, Ba₂InO₃Cl, and Ba₂InO₃Br were synthesized using the solid state method. It was found that the increasing of halide ion radius leads to the increase of lattice parameters and also caused to redistribution of indium-oxygen bond lengths. The possibility of water uptake was proved by thermogravimetry measurements. The presence of different forms of oxygen-hydrogen groups in the structure of hydrated oxyhalides was indicated by infrared spectroscopy.