Reassessment of Crystal Growth Theory of Graphite in Cast Iron

Abstract:

The problem of graphite crystallization and growth in cast iron has recently received increased attention. As most of the published literature describe analysis of room temperature graphite, there is a legitimate concern that the crystallization of graphite is concealed by recrystallization and growth in solid state occurring after solidification. To avoid confusion in the interpretation of room temperature graphite morphology, the authors used Field Emission Gun SEM on deep-etched interrupted solidification (quenched) specimens to reveal the morphology of graphite at the very beginning of solidification, when the graphite is in contact with the liquid. Information from related phenomena, such as crystallization of hexagonal structure snowflakes and metamorphic graphite, as well as of diamond cubic structure silicon crystals in aluminum alloys is incorporated in the analysis. Research discussing graphite produced through gas-solid and solid-solid transformations is also examined. Because the faceted growth of graphite is the result of diffusion-limited crystal growth in the presence of anisotropic surface energy and anisotropic attachment kinetics, a variety of solidification morphologies are found. The basic building blocks of the graphite aggregates are hexagonal faceted graphite platelets generated through the growth of graphene layers. As solidification advances, the platelets thicken through layer growth, and then aggregate through mechanisms that may include foliated/tiled-roof crystals and dendrites, curved-circumferential, cone-helix, helical, and columnar or conical sectors growth.

• Periodical: Materials Science Forum (Volume 925)
• Pages: 36-44
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.925.36
• Online since: June 2018
• Authors: Doru Michael Ştefănescu*, Gorka Alonso, Pello Larrañaga, Esther de La Fuente, Ramón Suárez
• Keywords: Cast Iron, Foliated Dendrites, Graphite Growth, Graphite Morphology

References

[1] A.K. Geim, K.S. Novoselov: Nat. Mater. Vol 6 (2007) 183-191.

[2] U. Nakaya, Snow Crystals: Natural and Artificial (Cambridge Univ. Press, Cambridge 1954).

[3] A. Hellawell: Prog. Mater. Sci. 15 (1970) 3-78.

[4] C.R. Loper, C.B. Kim, K.M. Htun, R.W. Heine: in Recent Research on Cast Iron, H.D. Merchant ed. (Gordon and Breach, New York, N.Y., 1968) 363-387.

[5] D.A. Granger, R. Elliott: in ASM Handbook Vol.15 Casting, D.M. Stefanescu ed. (ASM International, 1988) 159-168.

[6] B. Lux, F. Mollard, I. Minkoff: in The Metallurgy of Cast Iron, B. Lux, I. Minkoff, F. Mollard eds. (Georgi Publishing Co., St Saphorin, Switzerland, 1974) 371-401.

DOI: 10.1002/mawe.19760070712

[7] H Fredriksson, M Hillert, N Lange: J. Inst. Met. 101 (1973) 285-299.

[8] E. Tillová, M. Chalupová, L. Hurtalová: in: V. Kazmiruk ed., Scanning Electron Microscopy, (InTech, Chapters published March 09, 2012).

[9] D.D. Saratovkin: Dendritic Crystallization (Consultants Bureau, New York, NY, 1959).

[10] A.N. Roviglione, J.D. Hermida: Metall. Mater. Trans. Vol 35B (2004) 313.

[11] D.M. Stefanescu, G. Alonso, P. Larrañaga, E. De la Fuente, R. Suarez: Acta mater. 107 (2016) 102-126.

DOI: 10.1016/j.actamat.2016.01.047

[12] D.M. Stefanescu, R. Huff, G. Alonso, P. Larrañaga, E. De la Fuente, R. Suarez: Metall. Mater. Trans. 47, (2016) 4012-4023.

DOI: 10.1007/s11661-016-3541-4

[13] D.H. St. John, L.M. Hogan: J. Crystal Growth 46 (1979) 387-398.

[14] V.N. Kvasnitsa, V.G. Yatsenko, J.A. Jaszczak: Can. Mineralogist 37 (1999) 951-960.

[15] D.D. Double, A. Hellawell: Acta Metall. 17 (1969) 1071-1083; 22 (1974) 481-487.

[16] D.D. Double, A. Hellawell: in: B. Lux, I. Minkoff, F. Mollard (Eds.), The Metallurgy of Cast Iron (Georgi Publishing Co., St Saphorin, Switzerland, 1975) 509-528.

DOI: 10.1002/mawe.19760070712

[17] S. Amelinckx, W. Luyten, T. Krekels, et al.: J. Crystal Growth 121 (1992) 543-558.

[18] J.A. Jaszczaka, G.W. Robinson, S. Dimovskic, Y. Gogotsic: Carbon 41 (2003) 2085-(2092).

[19] B. Lux, I. Minkoff, F. Mollard, E. Thury: in: B. Lux, I. Minkoff, F. Mollard (Eds.), The Metallurgy of Cast Iron (Georgi Publishing Co., St Saphorin, Switzerland, 1975) 495-508.

DOI: 10.1002/mawe.19760070712

[20] S. Amini, R. Abbaschian: Carbon 51 (2013) 110-123.

[21] J.P. Sadocha, J.E. Gruzleski: in B. Lux, I. Minkoff, F. Mollard (Eds.), The Metallurgy of Cast Iron (Georgi Publishing Co., St Saphorin, Switzerland, 1975) 443-459.

DOI: 10.1002/mawe.19760070712

[22] K. He, H.R. Daniels, A. Brown, et al.: Acta Mater. 55 (2007) 2919-2927.

[23] D.D. Li, R.X. Tan, J.X. Gao, et al.: Carbon 111 (2017) 428-438.

[24] K.M. Fang, G.C. Wang, X. Wang, et al.: Science and Processing of Cast Iron VIII (Beijing, China, Tsinghua Univ. Press, 2006) 181-187.

[25] T. Hara, T. Kitagawa, K. Kuroki, et al.: Material Trans. JIMM 55(9) (2014) 1500-1505.

[26] I. Minkoff, I. Einbinder, Official Exchange Paper - Israel, Int. Foundry Congress (1963) 139143.

[27] M. Hamasumi, Trans. JIM, Vol 6 (1965) pp.234-239.

[28] M.J. Lalich, J.R. Hitchings: AFS Trans. 84 (1976) 653-664.

[29] G.R. Purdy, M. Audier: in: H. Fredriksson and M. Hillert (Eds.), The Physical Metallurgy of Cast Iron, Stockholm (Mat. Res. Soc. Symposia Proc., North-Holland, NY, 1985), 13-23.

[30] B. Miao, D.O. Northwood, W. Bian, K. Fang, M. Fan: J Mater Sci 29 (1994) 255-261.

[31] K. Theuwissen, J. Lacaze, L. Laffont: Carbon 96 (2016) 1120-1128.

[32] P.C. Liu, C.R. Loper, T. Kimura, H.K. Park: AFS Trans. 88 (1980) 97-118.

[33] D. Ugarte: Nature, London 359 (1992) 707-709.