Effect of the Cooling Rate on the Graphite Nodule Count and Size Distribution in Nodular Cast Iron

Article Preview

Abstract:

The graphite nodule count, size distribution and homogenization of the nodules distribution are the factor which are of more significance for the properties of the material. By just increasing the inoculants or Mg will not help to get rid of problems like the un-even size distribution and or increasing the nodule count. The cooling conditions of the melt prior to solidification and during solidification can control these two parameters to a large extent. In this research, it is more emphasized on the nucleation sequence of MgO particles and on the cooling rates. The nucleation of MgO at different temperatures and at different cooling rates was found to have a great influence on the nodule size distribution and the homogenization of the microstructure. A mathematical model was derived to relate the Mg concentration in the liquid to the cooling rate, prior to solidification. The MgO particles count was calculated as a function of cooling rate. It was found that at higher cooling rates, MgO can be nucleated in multi steps during cooling process, which can increase the nodule count tremendously.

You have full access to the following eBook

Info:

* - Corresponding Author

[1] T. Kobayashi, Strength and Toughness of Materials, 171-172, 2004, Springer-Verlag Tokyo, Japan, ISBN 978-4-431-53973-5.

Google Scholar

[2] T. Skaland, Nucleation Mechanisms in Ductile Irons, Proc. AFS conf. Cast Iron Inoculation,, Schaumburg, Illinois, (2005).

Google Scholar

[3] H. M. Muhmond & H. Fredriksson: (PhD thesis), On the Inoculation and Graphite Morphologies of Cast Iron, 2014, Royal Institute of Technology, Stockholm, ISBN 978-91-7595-349-6.

Google Scholar

[4] H. M. Muhmond & H. Fredriksson, Graphite Growth Morphologies in Cast Iron, Mat. Sci. Forum, 790-791 (2014), 607-614.

DOI: 10.4028/www.scientific.net/msf.790-791.458

Google Scholar

[5] A. Tadesse: (PhD thesis), On the Volume Changes during the Solidification of Cast Irons and Peritectic Steels, 2017, Royal Institute of Technology, Stockholm, ISBN 978-91-7729-299-9.

Google Scholar

[6] I. L. Svensson and I. Dugic, Modelling of volumes in cast iron solidification to predict shrinkage and expansion defects, Int. J. Cast Met. Res., 11-6 (1999), 489-494.

DOI: 10.1080/13640461.1999.11819322

Google Scholar

[7] G. K. Sigworth & J. F. Elliott, The Thermodynamics of Liquid Dilute Iron Alloys, 8 (iss.1) (1974), 298-310, MIT.

DOI: 10.1179/msc.1974.8.1.298

Google Scholar

[8] J. F. Elliott, M. Gleiser and V. Ramakrishna, Thermochemistry for Steelmaking, 2 (1963), 547-567.

Google Scholar

[9] A. Ghosh and G. V. R. Murthy, An Assessment of Thermodynamic Parameters for Deoxidation of Molten Iron by Cr, V, Al, Zr and Ti, Transaction ISIJ, 26 (1986), 629-637.

DOI: 10.2355/isijinternational1966.26.629

Google Scholar

[10] V. Vondrák, J. Hampl, A. Hanus, Metallurgy of Cast Irons Out-of-Furnace Processing of Molten Cast Iron, 2014, 92-93, Technical University of Ostrava, Czech Republic.

Google Scholar

[11] F. Mampaey, D. Habets, J. Plessers, F. Seutens, The use of oxygen activity measurement to determine optimal properties of ductile iron during production, International Journal of Metalcasting, 4(2) (2010), 25-43.

DOI: 10.1007/bf03355464

Google Scholar