Novel Methodology for the Selection, Dosing and On-Line Control of Corrosion Inhibitors for Industrial Acid Pickling

Massimo de Sanctis; Gianfranco Lovicu; Randa Ishak; Maria Richetta; Alessandra Varone

doi:10.4028/www.scientific.net/MSF.941.1698

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HomeMaterials Science ForumMaterials Science Forum Vol. 941Novel Methodology for the Selection, Dosing and...

Novel Methodology for the Selection, Dosing and On-Line Control of Corrosion Inhibitors for Industrial Acid Pickling

Abstract:

A novel methodology based on electrochemical hydrogen permeation tests is proposed to study the efficiency of commercial inhibitors for industrial acid pickling of iron and mild steels. Weight loss measurements and hydrogen permeation tests have been carried out in order to compare the sensitivity of different techniques to variations of low inhibitor dosages. It has been found a close dependence between low amounts of filming inhibitors and hydrogen uptake in the metallic surface with related permeation currents. The high sensitivity of permeation currents may be very useful to establish and also control the optimum amount of active substances in industrial pickling baths, with related cost savings. The implementation of the proposed methodology to improve the control of industrial pickling plants is also envisaged, since it would be possible to improve both sensitivity and time response of experimental permeation curves.

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Periodical:

Materials Science Forum (Volume 941)

Pages:

1698-1704

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.941.1698

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Online since:

December 2018

Authors:

Massimo de Sanctis*, Gianfranco Lovicu, Randa Ishak, Maria Richetta, Alessandra Varone

Keywords:

Acid Pickling, Hydrogen Permeation, Inhibitors

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References

[1] J. Crahay, A. Kolstov, A. Osta; V. Colla, R. Wolters, R. Pandorf, Optimized productivity and quality by on-line control of pickled surface (HIGHPICK), Luxembourg: Publication Office of the European Union, (2014).

Google Scholar

[2] S. Muralidharan, R. Chandrasekhar, S.V.K. Iyer, Effect of piperidones on hydrogen permeation and corrosion inhibition of mild steel in acidic solutions. In Proceedings of the Indian Acad. Sci. (Chem.Sci.), April 2000, 2, 127-136.

DOI: 10.1007/bf02704314

Google Scholar

[3] K. N. Srinivasan, V. Iyer, Trans. Soc. Adv. Electrochem. Sci. Technol., 1989, 24, 205.

Google Scholar

[4] Devanathan, M.A.; Stachurski, V.Z. The Adsorption and Diffusion of Electrolytic Hydrogen in Palladium', Proceedings of the Royal Society A. Mathematical and Physical Sciences 270 (1962) 90–102.

Google Scholar

[5] Devanathan, M.A.V.; Stachurski, Z. The Mechanism of Hydrogen Evolution on Iron in Acid Solutions by Determination of Permeation Rates. Journal of The Electrochemical Society 111(1964) 619–623.

DOI: 10.1149/1.2426195

Google Scholar