The Influence of Gas Diffusion Media Morphology on Hydrogen Fuel Cell Performance

Article Preview

Abstract:

Gas diffusion media (GDM) is an integral part of all gas diffusion electrodes because it facilitates both the transport of reactants to the electrocatalyst surface and the removal of reaction products from the system. Proper reactant/product distribution is critical for high power operation in polymer electrolyte fuel cells (PEMFCs) because oxygen transport and water rejection determine the maximum current density that can be obtained from PEMFCs. This paper will discuss NRL’s research on how GDM morphology influences cell performance in both closed-cathode fuel cell and open-cathode fuel cell designs. The comprehensive study linking the influence of compression on the GDM micro and macro structure morphology will be presented using micro X-ray computed tomography (μ-CT), scanning electron microscopy (SEM), N2 Physisorption (BET) and traditional electrochemical characterization techniques (CV, Pol. Curves, etc.). Optimal GDM selection for the challenge of open-cathode operation will be presented and related to water retention through rational morphology selection. The relationship between high power performance and water transport will be elucidated and the goals for future GDM properties will be proposed for use in unmanned systems

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2226-2231

Citation:

Online since:

December 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] W. Merida, Porous Transport Layer Degradation, in: H. Wang, H. Li, X. Yuan (Eds.), PEM Fuel Cell Failure Mode Analysis, CRC Press, Boca Raton, 2012, p.110.

Google Scholar

[2] R.W. Atkinson III, Y. Garsany, B.D. Gould, K.E. Swider-Lyons, I. Zenyuk, The Role of Compressive Stress on Gas Diffusion Media Morphology and Fuel Cell Performance, ACS Appl. Energy Mater., Article ASAP.

DOI: 10.1021/acsaem.7b00077

Google Scholar

[3] M.B. Sassin, Y. Garsany, B.D. Gould, K.E. Swider-Lyons, Impact of Compressive Stress on MEA Pore Structure and Its Consequences on PEMFC Performance, JECS, 168 (2016) F808-F815.

DOI: 10.1149/2.0291608jes

Google Scholar

[4] R.W. Atkinson III, M.W. Hazard, J.A. Rodgers, R.O. Stroman, B.D. Gould, JECS, 163 (2017) F46-F54.

Google Scholar

[5] R. O'Hayre, T. Fabian, S. Litster, F.B. Prinz, J.G. Santiago, Engineering Model of a Passive Planar Air Breathing Fuel Cell Cathode, J. Power Sources, 167 (2007) 118-129.

DOI: 10.1016/j.jpowsour.2007.01.073

Google Scholar