Screen-Printed NiO-YSZ Thin Film Electrode for Solid Oxide Electrochemical Cell and Subsequent Reduction to Ni-YSZ

Agnes L. Manalo; Rinlee Butch M. Cervera

doi:10.4028/www.scientific.net/MSF.950.123

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HomeMaterials Science ForumMaterials Science Forum Vol. 950Screen-Printed NiO-YSZ Thin Film Electrode for...

Screen-Printed NiO-YSZ Thin Film Electrode for Solid Oxide Electrochemical Cell and Subsequent Reduction to Ni-YSZ

Abstract:

Nickel and yttria-stabilized zirconia (Ni-YSZ) ceramic-metal composite electrodes are commonly used for solid oxide electrochemical cells because of their good ionic and electronic conductivity. In this study, a thin film of NiO-YSZ was prepared via screen-print method and subsequently reduced to Ni-YSZ. The precursor powder for screen-printing was prepared via glycine-nitrate combustion process. The effect of precursor particle size and of the use of PVP as binder on film uniformity and quality were investigated. For the NiO-YSZ film, scanning electron microscopy (SEM) micrographs and X-ray diffraction (XRD) patterns confirmed that size reduction and the use of binder both improved the quality and uniformity of the deposit without changing the composition of the sintered film. SEM with energy-dispersive spectroscopy (EDS) showed elemental mapping of unreduced and reduced films, revealing micro grain size faceted particles of NiO and Ni, while smooth and much larger YSZ grains were also observed. XRD of reduced Ni-YSZ film revealed that the NiO peaks had been replaced by Ni.

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Periodical:

Materials Science Forum (Volume 950)

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123-127

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.950.123

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Online since:

April 2019

Authors:

Agnes L. Manalo*, Rinlee Butch M. Cervera

Keywords:

NiO-YSZ, Ni-YSZ, Screen-Printing, Solid Oxide Electrochemical Cell

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References

[1] H. Korkmaz, B. Timurkutluk, and C. Timurkutluk: Int. J. Hydrogen Energy, Vol. 41 (2016), pp.9723-9730.

DOI: 10.1016/j.ijhydene.2016.02.005

Google Scholar

[2] T. Fukui, K. Murata, S. Ohara, H. Abe, M. Naito, and K. Nogi: J. Power Sources, Vol. 125 (2004), pp.17-21.

DOI: 10.1016/s0378-7753(03)00817-6

Google Scholar

[3] N.A. Baharuddin, A. Muchtar, A.B. Sulong, and H. Abdullah: Adv. Mat. Res., Vol. 662 (2013), pp.396-401.

Google Scholar

[4] Y. Zhang, X. Huang, Z. Lu, X. Ge, J. Xu, X. Xin, X. Sha, and W. Su: Solid State Ionics, Vol. 177 (2006), pp.281-287.

DOI: 10.1016/j.ssi.2005.11.008

Google Scholar

[5] S.P. Jiang, P.J. Callus, and SPS Badwal: Solid State Ionics, Vol. 132 (2000), pp.1-14.

Google Scholar

[6] W.F. Chu: Solid State Ionics, Vol. 52 (1992), pp.243-248.

Google Scholar

[7] K.J. Yoon, G. Ye, S. Gopalan, and U.B. Pal: J. Fuel Cell Sci. Technol., Vol. 7 (2010), pp.021010-5.

Google Scholar

[8] M.R. Somalu, A. Muchtar, W.R.W. Daud, and N.P. Brandon: Renew. Sust. Energ. Rev., Vol. 75 (2017), pp.426-439.

Google Scholar

[9] M. Aslan, D. Weingarth, N. Jackel, J.S. Atchison, I. Grobelsek, and V. Presser: J. Power Sources, Vol. 266 (2014), pp.374-383.

DOI: 10.1016/j.jpowsour.2014.05.031

Google Scholar

[10] F.R. Bueta, J.F. Imperial, and R.B. Cervera: Ceram. Int. Vol. 43 (2017), pp.16174-16177.

Google Scholar

[11] J.F.L. Imperial and R.B.M. Cervera: Mater. Sci. Forum Vol. 917 (2018), pp.83-87.

Google Scholar

[12] N.B. Kakade, S. Ramanathan, D. Das: Ceram. Int. Vol. 37 (2011), pp.195-200.

Google Scholar