Paper Titles

Synthesis of Pseudoboehmite - Aging Effect
p.5

Evaluation of Catalysts Mordenite and MoO₃/Mordenite in the Production of Biodiesel
p.11

Synthesis, Characterization and Evaluation of Organophilic Bofe Clay for Use in the Removal of Oil Effluents
p.17

Y-Type Zeolite Membranes: Synthesis by Secondary by Method and Application in Treatment of Oily Effluents
p.23

Characterization and Application of Catalysts Hard Green Clay and MoO₃/ Hard Green Clay in Transesterification Reaction of Soybean Oil
p.29

Comparative Study between ABNT/NBR 15270/2005 and a New Hollow Ceramic Block for Non-Load-Bearing Masonry Manufactured in Santarém - Pará (Brazil)
p.35

Decoration Cylinder Pressure and it’s Influence on the Hue Variation of Ceramic Tiles Decorated by the Laser Engraving Silicone Cylinder Method
p.41

Characterization of Gypsum Waste from Civil Construction to Obtain Polymer Composites
p.47

Determination Compressive and Bending Strength of Porous Bodies from Plaster Reinforced with Polyacetate of Vinila (PVAc)
p.53

HomeMaterials Science ForumMaterials Science Forum Vol. 958Characterization and Application of Catalysts Hard...

Characterization and Application of Catalysts Hard Green Clay and MoO₃/ Hard Green Clay in Transesterification Reaction of Soybean Oil

Article Preview

Abstract:

The present study describes the preparation of catalyst MoO₃ supported on smectite clay by the solution impregnation method and its evaluation as a heterogeneous catalyst in the production of biodiesel from soybean oil. The individual effects of catalyst (hard green clay and MoO₃/hard green clay) on kinematic viscosity of produced biodiesel and conversion were investigated. The samples were characterized by X-ray diffraction, X-ray fluorescence spectroscopy and N₂ adsorption-desorption. Conditions of soybean oil transesterification were: 5% catalyst by weight, 1:12 oil to methanol molar ratio, at 200 oC for 60 minutes. Patterns of X-ray diffraction showed the characteristic peaks of the structure of smectite. The results of X-ray diffraction suggests that MoO₃ species exist as highly dispersed surface species. Molybdenum metal identified as effective catalysts for the transesterification reaction of soybean oil with methanol. A preliminary design assessment show that this catalysts (MoO₃/HGC) is sufficiently active achieving conversion in excess of 62,07% at temperature below 200 oC.

You might also be interested in these eBooks

Biofuel

The 61st Brazilian Ceramic Conference

Info:

Periodical:

Materials Science Forum (Volume 958)

Pages:

29-34

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.958.29

Citation:

Cite this paper

Online since:

June 2019

Authors:

Fabiana Medeiros do Nascimento Silva, Erivaldo Genuíno Lima, Tellys Lins de Almeida Barbosa, Meiry Gláucia Freire Rodrigues

Keywords:

Biodiesel, Hard Green Clay, Methanol, Molybdenum, Renewable Energy

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K. Jacobson, R. Gopinath, L.C. Meher, A.K. Dalai: Appl. Catal. B Vol. 85 (2008), p.86.

[2] A.E.B. Cruz, J.A.M. Banda, H. Mendoza, C.E.R. Galvana, M.A.M. Melo, D. Esquivel: Catal. Today Vol. 166 (2011), p.111.

[3] J.J. Rodrigues, J.C. Marinho, R.S. Eduardo, E.G. Lima, M.G.F. Rodrigues: Braz. J. Pet. Gas Vol. 9 (2015), p.11.

[4] S.C.G. Rodrigues, M.G.F. Rodrigues, K.R.O. Pereira, F.R. Valenzuela-Díaz: Braz. J. Pet. Gas Vol. 4 (2010), p.49.

[5] M.B. Queiroz, S.C.G. Rodrigues, H.M. Laborde, M.G.F. Rodrigues: Mater. Sci. Forum Vols 660-661 (2010), p.1031.

[6] M.F. Mota, J.A. Silva, M.B. Queiroz, H.M. Laborde, M.G.F. Rodrigues: Braz. J. Pet. Gas Vol. 5 (2011), p.97.

[7] G.C. Oliveira, M.F. Mota, M.M. Silva, M.G.F. Rodrigues, H.M. Laborde: Braz. J. Pet. Gas Vol. 6 (2012), p.171.

[8] M.F. Mota, M.G.F. Rodrigues, F. Machado: Appl. Clay Sci. Vol. 99 (2014), p.237.

[9] K.R.O. Pereira, R.A. Hanna, M.M.G.R. Vianna, C. A. Pinto, M.G.F. Rodrigues, F.R. Valenzuela-Diaz: Mat. Res. Vol. 8 (2005), p.77.

[10] M.G.F. Rodrigues: Cerâmica Vol. 49 (2003), p.146.

[11] F. Bergaya, B.K.G. Theng, G. Lagaly: Handbook of Clay Science. (Elsevier New York, 2006).

[12] R.E. Grim: Clay Mineralogy. (International Series in the Earth and Planetary Sciences McGraw-Hill New York, 1968).

[13] S. Kumar, A.C. Pulikottil, A. Sharma, M. Sarkar, V. Kagdiyal, A. Yadav, A.K. Arora, S.K. Puri, M.B. Patel, M. Santra, R. Sarin, B. Kumar, A.A. Gupta, B. Basu, R.K. Malhotra, A. Kumar, 2010. WO 2010/020998 A2.

[14] P. Souza Santos. Ciência e Tecnologia de Argilas. (Volume 3, 2 eds. São Paulo, 1992).

[15] D. Lahcen, E.E. Hicham, S. Latifa, A. Abderrahmane, B. Jamal, W. Mohamed, E. Meriam, F. Nathalie: App. Clay Sci. Vol. 102 (2014), p.139.

DOI: 10.1016/j.clay.2014.09.029

[16] G.C. Oliveira, Utilização de adsorventes (carvão ativado e argilas organofílicas) no processo de separação de emulsões óleo/água. Mestrado (Dissertação). Campina Grande, 2012. Universidade Federal de Campina Grande (UFCG). (PB).

DOI: 10.24873/j.rpemd.2021.10.846

[17] R. Burch: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases Vol. 74 (1978), p.2982.

[18] G. Leofanti, M. Padovan, B. Venturelli: Catal. Today Vol. 41 (1998), p.207.

[19] J.M. Marchetti: Process Saf. Environ. Prot. Vol. 90 (2012), p.157.

[20] E.G. Lima, R.S. Eduardo, A.S. Barbosa, M.G.F. Rodrigues. XII European Congress on Catalysis (EuropaCat). Kazan, 30 August 2015 to 04 September 2015. Proceeding... Kazen 2015 (RUS).