CO2 Rich Natural Gas Processing: Technical, Power Consumption and Emission Comparisons of Conventional and Supersonic Technologies

Article Preview

Abstract:

Supersonic separator is investigated via process simulation for treating CO2 rich (>40%) natural gas in terms of dew-points adjustment and CO2 removal for enhanced oil recovery. These applications are compared in terms of technical and energetic performances with conventional technologies, also comparing CO2 emissions by power generation. The context is that of an offshore platform to treat raw gas with 45%mol of CO2, producing a lean gas stream with maximum CO2 composition of ≈20%mol, suitable for use as fuel gas, and a CO2 rich stream that is compressed and injected to the oil and gas fields. The conventional process comprises dehydration by chemical absorption in TEG, Joule-Thomson expansion for C3+ removal, and membrane permeation for CO2 capture. The other alternatives use supersonic separation for dew-points adjustment, and membranes or another supersonic separation unit for CO2 capture. Simulations are carried out in HYSYS 8.8, where membranes and supersonic separation are modeled via unit operation extensions developed in a previous work: MP-UOE and SS-UOE. A full technical and power consumption analysis is performed for comparison of the three cases. The results show that the replacement of conventional dehydration technology by supersonic separators decreases power demand by 8.5%, consequently reducing 69.66 t/d of CO2 emitted to the atmosphere. The use of supersonic separation for CO2 capture is also superior than membranes, mainly due to the production of a high-pressure CO2 stream, that requires much less power for injection compression than the low-pressure permeate stream from membranes. Therefore, the case with two supersonic separator units in series presents the best results: lowest power demand (-23.9% than conventional case), directly impacting on CO2 emissions, which are reduced by 2598 t/d (-27.82%).

You might also be interested in these eBooks

Info:

* - Corresponding Author

[1] P.B. Machado, J.G.M Monteiro, J.L. de Medeiros, H.D. Epsom, O.Q.F. Araújo, Supersonic separation in onshore natural gas dew point plant, J. of Nat. Gas Sci. and Eng. 6 (2012) 43–9, doi 10.1016/j.jngse.2012.03.001.

DOI: 10.1016/j.jngse.2012.03.001

Google Scholar

[2] R.S.H. Shooshtari, A. Shahsavand, Reliable prediction of condensation rates for purification of natural gas via supersonic separators, Sep. Purif. Technol. 116 (2013) 458–470.

DOI: 10.1016/j.seppur.2013.06.009

Google Scholar

[3] M. Castier, Modeling and simulation of supersonic gas separations, J. Nat. Gas Sci. Eng. 18 (2014) 304–311.

DOI: 10.1016/j.jngse.2014.03.014

Google Scholar

[4] L.O. Arinelli, J.L. de Medeiros, O.Q.F. Araújo, Performance Analysis and Comparison of Membrane Permeation Versus Supersonic Separators for CO2 Removal From a Plausible Natural Gas of Libra Field , Brazil, in: Offshore Technology Conference Brazil, Rio de Janeiro, Brazil, oct., (2015).

DOI: 10.4043/26164-ms

Google Scholar

[5] R. Secchi, G. Innocenti, D. Fiaschi, Supersonic Swirling Separator for natural gas heavy fractions extraction: 1D model with real gas EOS for preliminary design, J. Nat. Gas Sci. Eng. 34 (2016) 197–215.

DOI: 10.1016/j.jngse.2016.06.061

Google Scholar

[6] L.O. Arinelli, T.A.F. Trotta, A.M. Teixeira, J.L. de Medeiros, O.Q.F. Araújo, Offshore Processing of CO2 Rich Natural Gas with Supersonic Separator versus Conventional Routes, J. of Nat. Gas Sci. and Eng. 46 (2017) 199-221, doi 10.1016/j.jngse.2017.07.010.

DOI: 10.1016/j.jngse.2017.07.010

Google Scholar

[7] R.A. Samawe, K. Rostani, A.M. Jalil, M. Esa, N. Othman, Concept proofing of supersonic nozzle separator for CO2 separation from natural gas using a flow loop, in: Offshore Technology Conference Asia, Offshore Technology Conference, Kuala Lumpur, Malaysia, 2373–2376, (2014).

DOI: 10.2118/24953-ms

Google Scholar

[8] W. Sun, X. Cao, W. Yang, X. Jin, Numerical simulation of CO2 condensation process from CH4-CO2 binary gas mixture in supersonic nozzles, Sep. Purif. Technol. 188 (2017), Accepted Manuscript.

DOI: 10.1016/j.seppur.2017.07.023

Google Scholar

[9] J. Bian, W. Jiang, D. Hou, Y. Liu, J. Yang, Condensation characteristics of CH4-CO2 mixture gas in a supersonic nozzle, Powder Technology 329 (2018) 1-11.

DOI: 10.1016/j.powtec.2018.01.042

Google Scholar

[10] W. Jiang, J. Bian, A. Wu, S. Gao, P. Yin, D. Hou, Investigation of supersonic separation mechanism of CO2 in natural gas applying the Discrete Particle Method, Chemical Engineering & Processing: Process Intensification 123 (208) 272-279.

DOI: 10.1016/j.cep.2017.11.019

Google Scholar

[11] J.L. de Medeiros, L.O. Aeinelli, O.Q.F. Araújo, Speed of Sound of Multiphase and Multi-Reactive Equilibrium Streams: A Numerical Approach for Natural Gas Applications, J. of Nat. Gas Sci. and Eng. 46 (2017) 222-241, doi 10.1016/j.jngse.2017.08.006.

DOI: 10.1016/j.jngse.2017.08.006

Google Scholar

[12] A.M. Teixeira, L.O. Arinelli, J.L. de Medeiros, O.Q.F. Araújo, Exergy Analysis of monoethylene glycol recovery processes for hydrate inhibition in offshore natural gas fields, J. of Nat. Gas Sci. and Eng. 35 (2016) 798-813, doi 10.1016/j.jngse.2016.09.017.

DOI: 10.1016/j.jngse.2016.09.017

Google Scholar

[13] O.Q.F. Araújo, A.C. Reis, J.L. de Medeiros, J.F. Nascimento, W.M. Grava, A.P.S. Mussi, Comparative analysis of separation technologies for processing carbon dioxide rich natural gas in ultra-deepwater oil fields, J. of Clean. Production 155 (2017) 12-22, doi 10.1016/j.jclepro.2016.06.073.

DOI: 10.1016/j.jclepro.2016.06.073

Google Scholar