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Characterization and Application of Bayah Natural Zeolites for Ammonium Capture: Isotherm and Kinetic

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Abstract:

The aim of this study is to characterize Bayah natural zeolites and tested for ammonium capture. Characterization of Bayah natural zeolites were performed by X-ray diffraction (XRD), scanning electron microscope (SEM), and nitrogen physisorption. The natural zeolites were identified as mordenite and clinoptilolite. Non-zeolitic phase appeared on the XRD pattern was quartz. The morphology of clinoptilolite and mordenite were observed as platy and needle shape in the SEM images, respectively. Major cations were K+ and Ca2+ which were determined by energy dispersive X-ray. Nitrogen isotherm physisorption suggested that the natural zeolites was typical of type IV isotherm. Pore size distribution were determined using Barrett, Joyner, and Halenda model with mesopore size 3-5 nm. Ammonium exchange on Bayah natural zeolites were conducted in a batch experiment by varying the particle sizes, time and mass loading. Non-linear least squared method was applied to fit the experimental data with various kinetic and isotherm models. The kinetic data was well fitted with the Elovich equation with error 1.6 x 10-4. Isotherm adsorption of ammonium followed Langmuir-Vageler with error 4 x 10-2.

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Periodical:

Materials Science Forum (Volume 988)

Pages:

51-64

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.988.51

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Online since:

April 2020

Authors:

Teguh Kurniawan*, Nuryoto Nuryoto, Rahmayetty Rahmayetty

Keywords:

Ammonium Exchange, Isotherm, Kinetic Study, Natural Zeolites

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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