Improving the Characteristics of Wear-Resistant Coatings Obtained by HDTV-Boration, their Modification by Intermetallic Compounds of Fe-Al and Ni-Al Systems

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Innovative technology of HDTV-borating, that is distinguished by high hardness, strength, wear resistance and corrosion resistance occupies a special place among the hardening processes for steels and construction materials. During the new technology process HDTV-boration of structural steel 65Mn (65Г in Russian) under a mix layer of charge mixture based on fused borate fluxing agent P-0.66, boron carbide and intermetallic compounds FexAly, NixAly. Using the methods of X-ray phase analysis, spectrography and metallography, the composition and structure of coatings were determined, the microhardness distribution over the coating thickness was studied. In the coatings, new phases of intermetallic compounds, the double superhard boride Fe2AlB2, were found; in the coatings, the base iron boride is FeB, what leads to an increase in their hardness and wear resistance. Modification of boride coatings formed by intermetallic compounds with melting temperatures close to the process temperature of HFC surfacing leads to a decrease in the cracks number and the appearance of new consumer qualities of the material.

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640-646

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May 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] V.P. Lyalyakin, On the restoration of machine parts and mechanisms, Vestnik RASKhN. 5 (2012) 9-10.

Google Scholar

[2] Chemical heat treatment of metals and alloys, edited by L.S. Lyakhovich, M.: Metallurgiya, (1981).

Google Scholar

[3] L.G. Voroshnin, L.S. Lyakhovich, Borating of steel, M.: Metallurgy, (1978).

Google Scholar

[4] A.V. Ishkov, N.M. Mishustin, V.V. Ivanayskiy, Physical-chemical and engineering bases of creating functional boride coatings on steels during HFC heating, Nauchno-tekhnicheskiy vestnik Povolzh'ya. 2 (2010) 92-97.

Google Scholar

[5] A.V. Ishkov, N.T. Krivochurov, N.M. Mishustin et al., Wear resistant boride coatings for soil tillage organs of agricultural machinery, Vestnik AGAU.71, 9 (2010) 71-75.

Google Scholar

[6] N.M. Mishustin, V.V. Ivanayskiy, A.V. Ishkov, Composition, structure and properties of wear resistant coatings obtained on 65G and 50HGA grade steels during high-speed HFC borating, Izvestiya TPU. 320, 2 (2012) 68-72.

Google Scholar

[7] V.F. Aulov, V.V. Ivanayskiy, A.V. Ishkov et al., Obtaining wear resistant composite coatings on 65G grade steel during HFC heating, Engineering technology. 2 (2015) 30-34.

Google Scholar

[8] A.V. Ishkov, N.M. Vlasov, V.V. Ivanyskiy, N.T. Krivochurov, High-speed HFC borating of steels 38HN3MA and 30CrMoV9, Prospects for the development of socio-cultural and technical services: Materials of the I All-Rus. sci. pract. conf., Biysk, Publishing house AGTU, 2013, pp.35-39.

Google Scholar

[9] V.N. Tkachev, B.Ch. Fishteyn, N.V. Kazintsev, D.A. Aldyrev, Inductive hard surfacing, М.: Engineering, (1970).

Google Scholar

[10] V.I. Itin, Yu.S. Nayborodenko, High-temperature synthesis of intermetallic compounds, Tomsk: Publishing house of Tomsk University, (1989).

Google Scholar

[11] S.D. Desterfani, Advances in intermetallics. Advanced Materials and Processes. 135, 2 (1989) 37-41.

Google Scholar

[12] B.A. Kolachev, A.A. Il'in, P.D. Drozdov, Composition, structure and mechanical properties of double intermetallic compounds, Izvestiya VUZov, Non-ferrous metallurgy. 6 (1997) 41-52.

Google Scholar

[13] D.E. Alman, Wear of iron-aluminide intermetallic-based alloys and composites by hard particles, Wear. 251, 1-12 (2001) 875-884.

DOI: 10.1016/s0043-1648(01)00745-1

Google Scholar

[14] S.C. Deevi, V.K. Sikka, Nickel and iron aluminides: an overview on properties, processing, and applications, Intermetallics. 4, 5 (1996) 357–375.

DOI: 10.1016/0966-9795(95)00056-9

Google Scholar

[15] M. Toshio, H. Toshiyuki, Effects of unidirectional solidification conditions on the microstructure and tensile properties of Ni3 Al. Intermetallics. 3, 1 (1995) 23-33.

Google Scholar

[16] O.A. Bazyleva, O.G. Ospennikova, E.G. Arginbaeva et al., Trends in the development of nickel-based intermetallic alloys, Aviation materials and technologies. (2017) 104-115.

Google Scholar

[17] V.E. Ovcharenko, O.B. Perevalova, The evolution of the grain structure during the extrusion of the intermetallic compound Ni3Al during the high-temperature synthesis under pressure, II. Experimental data, Physics and chemistry of materials processing. 4 (2007) 78-82.

Google Scholar

[18] L.I. Shevtsova, Structure and mechanical properties of intermetallic compound Ni3Al obtained by spark plasma sintering technology of mechanically activated powder blend Ni–Al, Processing of metals. 3(64) (2014) 21-27.

Google Scholar

[19] O.A. Bannykh, P.B. Budberg, S.P. Alisova et al., State diagrams of binary and multicomponent iron-based systems: reference book, М.: Metallurgy, (1986).

Google Scholar

[20] O.B. Kovalev, V.A. Neronov, Metallochemical analysis of the reaction interaction in a mixture of nickel and aluminum powders, Physics of combustion and explosion. 40, 2 (2004) 52-60.

DOI: 10.1023/b:cesw.0000020139.07061.9e

Google Scholar

[21] O.I. Fomichev, V.F. Katkov, A.K. Kushnereva, The study of the triple diagram Fe-Fe2B-Fe3C, Zhurnal fizicheskoy khimii. 52, 9 (1978) 2240-2243.

Google Scholar