Synthesis of Dimethyl Carbonate from Methanol and Carbon Dioxide by Heteropolyacid/Metal Oxide Catalysts

Abstract:

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CexTi1-xO2 and H3PW12O40/CexTi1-xO2 catalysts were prepared by sol-gel method, and they were applied to the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide in a batch reactor. The reaction was carried out in an autoclave reactor at 170oC and 5 MPa. It was found that CexTi1-xO2 exhibited a higher catalytic performance than pure CeO2 and TiO2. The catalytic performance of CexTi1-xO2 was the maximum when x=0.1. It was also revealed that H3PW12O40/CexTi1-xO2 catalysts showed a remarkably enhanced catalytic performance than the corresponding CexTi1-xO2 catalysts. The amount of DMC produced by 15 wt% H3PW12O40/ Ce0.1Ti0.9O2 catalyst was six times higher than that produced by Ce0.1Ti0.9O2 catalyst. It is concluded that both Brönsted acid sites provided by H3PW12O40 and base sites in CexTi1-xO2 played an important role in improving the catalytic performance of H3PW12O40/CexTi1-xO2.

Info:

Periodical:

Solid State Phenomena (Volume 119)

Edited by:

Chang Kyu Rhee

Pages:

287-290

DOI:

10.4028/www.scientific.net/SSP.119.287

Citation:

K. W. La et al., "Synthesis of Dimethyl Carbonate from Methanol and Carbon Dioxide by Heteropolyacid/Metal Oxide Catalysts", Solid State Phenomena, Vol. 119, pp. 287-290, 2007

Online since:

January 2007

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$35.00

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