The carbon dioxide (R-744) as a natural refrigerant has been an attractive alternative refrigerant to replace HFC (hydrofluorocarbon) refrigerants currently used in air conditioning systems, due to the environmental concerns. Because new compressors with CO2 are going to be operated under the high pressure, the tribology of sliding surfaces in the compressor becomes very important. To develop new compressor, especially scroll type, the friction and wear characteristics of sliding surfaces between a fixed scroll and an orbiting scroll in the scroll compressor were investigated in this paper. The sliding tests of pin-on-disk type were carried out between scroll surfaces under various sliding speeds, normal loads, surface roughness, and refrigerant pressures. Two types of lubricants were used, namely POE (polyol ester) oil and PAG (polyalkylene glycol) oil. The friction forces, wear amounts and surface temperatures were monitored during the tests. Test results showed that the wear amounts increased with increasing normal load and rotating speed, and also decreased with decreasing surface roughness. Also, the results of the sliding tests showed that using PAG oil has an advantage over POE oil in CO2 environment. As the pressure of CO2 refrigerant became higher, the amount of wear and coefficient of friction became larger in CO2/POE mixed environment, but wear and friction remained constant in CO2/PAG mixed environment. The wear coefficients in CO2/PAG and CO2/POE mixed environment were 8.60×10-9 ㎣/N·m and 2.35×10-8 ㎣/N·m, respectively.