For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Device Performance of P3HT/C70-Methanofullerene Bulk-Heterojunction Polymer Photovoltaic Cells
p.935
Thermoelectric Properties of Co1-xFexSb3 Prepared by Encapsulated Induction Melting
p.939
Nano Composite Membranes of Branched Sulfonated Poly(Ether Ketone Sulfone) and SiO2 for Fuel Cell Application
p.943
Electrochemical Performance of Activated Carbon Electrode Added with LiCoO2 for Hybrid Capacitor
p.947
Catalytic Effect of Ti5Si3 on Dehydrogenation of NaAlH4
p.951
Novel Low-Temperature Synthesis and Characterization of Lithium Cobalt Dioxide for Lithium Rechargeable Batteries
p.955
Characterization of Cu(In,Ga)3Se5 Thin Film for Top Cell in CIGS Tandem Solar Cells
p.959
Application of Anodic Titanium Oxide to Dye-Sensitized Solar Cells
p.963
Electrodeposition of CdS Nanostructures for Solar Cells Using Nano Imprint Templates
p.967

Catalytic Effect of Ti5Si3 on Dehydrogenation of NaAlH4

Article Preview

Abstract:

Fine Ti5Si3 powder has been synthesized from a mixture of elemental Ti and Si powders using a mechanochemical method. It shows a good catalytic effect on NaAlH4 by reducing the dehydrogenation temperature and improving the dehydrogenation kinetics. Although the catalytic effect of Ti5Si3 is not better than that of TiCl3, the Ti5Si3 catalyst has an advantage over TiCl3 in terms of hydrogen capacity by releasing more hydrogen than TiCl3 during dehydrogenation. NaAlH4 catalyzed with Ti5Si3 shows reversible hydrogen storage by being hydrogenated at moderate conditions, although the hydrogenation kinetics is rather slow.

You might also be interested in these eBooks
Advances in Nanomaterials and Processing View Preview

Info:

Periodical:

Solid State Phenomena (Volumes 124-126)

Pages:

951-954

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.124-126.951

Citation:

Cite this paper

Online since:

June 2007

Authors:

Gil Jae Lee, Jae Hyeok Shim, Young Whan Cho, Kyung Sub Lee

Keywords:

Alanate, Catalyst, Hydrogen-Storage Material, Mechanical Milling, Ti5Si3

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2007 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] B. Bogdanović, M. Schwickardi: J. Alloys Compd. Vol. 253/254 (1997), p.1.

Google Scholar

[2] G. Sandrock, K. Gross, G. Thomas: J. Alloys. Compd. Vol. 339 (2002), p.299.

Google Scholar

[3] E.H. Majzoub and K.J. Gross: J. Alloys Compd. Vol. 356/357 (2003), p.363.

Google Scholar

[4] J. Graetz, J.J. Reilly, J. Johnson, A. Yu. Ignatov, T.A. Tyson: Appl. Phys. Lett. Vol. 85 (2004), p.500.

Google Scholar

[5] M. Resan, M.D. Hampton, J.K. Lomness, D.K. Slattery: Int. J. Hydrogen Energy Vol. 30 (2005), p.1417.

Google Scholar

[6] J. -H. Shim, G. -J. Lee, Y.W. Cho: J. Alloys Compd. Vol. 417 (2006), p.69.

Google Scholar

[7] C.J. Smithells (Ed. ): Metals Reference Book, (Butterworth, London, U.K., 1976).

Google Scholar

[8] B. K . Yen, T. Aizawa, J. Kihara: J. Am. Ceram. Soc. Vol. 81 (1998), p. (1953).

Google Scholar

[9] K. Kudaka, K. Iizumi, T. Sakai, H. Izumi: J. Am. Ceram. Soc. Vol. 83 (2000), p.288.

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.