Synthesis of “Main – Chain” Type Polyimide Matrix with a Chemically Bound Azo Group

Anton Georgiev; Velichka Strijkova; Dean Dimov; Erinche Spassova; Jacob Assa; Gencho Danev

doi:10.4028/www.scientific.net/SSP.159.141

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HomeSolid State PhenomenaSolid State Phenomena Vol. 159Synthesis of “Main – Chain” Type Polyimide Matrix...

Synthesis of “Main – Chain” Type Polyimide Matrix with a Chemically Bound Azo Group

Abstract:

A method for obtaining thin vacuum deposited azopolyimide layers is established. On the basis of the thermogravimetric and differential thermal analyses, the chemical reaction in the solid state between the initial precursors - 4,4’-diaminoazobenzene and pyromellitic dianhydride is discussed. Also, the preparation parameters allowing for a condensation of films of desired composition are determined. Fourier Transform Infrared Spectroscopy analyses confirm that the azo group is chemically bound in a thin polyimide layer matrix. This is a solution to the task of preparing a “Main – Chain” type polyimide matrix with a chemically bound azo- group.

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Periodical:

Solid State Phenomena (Volume 159)

Pages:

141-144

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.159.141

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Online since:

January 2010

Authors:

Anton Georgiev, Velichka Strijkova, Dean Dimov, Erinche Spassova, Jacob Assa, Gencho Danev

Keywords:

Azopolyimide, Nanocomposite, Polyimide

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