Influence of Temperature Independent Contribution of Magnetic Susceptibility on the Curie-Weiss Law

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Abstract:

A fitting procedure of the Curie-Weiss law, eliminating the temperature independent contribution (0) from the experimental susceptibility data, was used for determination of the magnetic parameters, i.e. a Curie constant, a Curie-Weiss temperature and an effective magnetic moment, because the theoretical considerations showed that the Curie-Weiss law is invalid for 0  0, even small. This method revealed for the HgCo(NCS)4 paramagnet, commonly accepted as a magnetic susceptibility standard, 0 = 2.43710-6 cm3/g, while for the ZnCr2Se4 antiferromagnet, known as a matrix of various diluted systems, – 0 = -2.56610-6 cm3/g, for comparison.

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Solid State Phenomena (Volume 170)

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213-218

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April 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.H. Morrish: Physical Principles of Magnetism (John Wiley & Sons, Inc., New York, 1965).

Google Scholar

[2] B.N. Figgis and R. S. Nyholm: J. Chem. Soc. Vol. 11 (1958), p.4190.

Google Scholar

[3] S.A. Kuzaiev, P.W. Usatchiev and W.M. Ubin: Fiz. Tver. Tela Vol. 13 (1971), p.2829.

Google Scholar

[4] D.B. Brown, V.H. Crawford, J.W. Hall and W.E. Hatfield: J. Phys. Chem. Vol. 81 (1977), p.1303.

Google Scholar

[5] D. Nelson and W. ter Haar: Inorg. Chem. Vol. 32 (1993), p.182.

Google Scholar

[6] T. Groń, E. Malicka and A.W. Pacyna: Physica B Vol. 404 (2009), p.3554.

Google Scholar

[7] R. Plumier, M. Lecomte, A. Miedan-Gros and M. Sougi: Phys. Lett. A Vol. 55 (1975), p.239.

DOI: 10.1063/1.29998

Google Scholar

[8] M. Nogues and J.L. Dormann: J. Magn. Magn. Mater. Vol. 54-57 (1986), p.87.

Google Scholar

[9] J. Krok, J. Spałek, S. Juszczyk and J. Warczewski: Phys. Rev. B Vol. 28 (1983), p.6499.

Google Scholar

[10] J. Hemberger, H. -A. Krug von Nidda, V. Tsurkan and A. Loidl: Phys. Rev. Lett. Vol. 98 (2007), p.147203.

Google Scholar

[11] F.K. Lotgering: J. Phys. Chem. Solids Vol. 29 (1968), p.699.

Google Scholar

[12] K. Motida and S. Miyahara: J. Phys. Soc. Jpn. Vol. 29 (1970), p.516.

Google Scholar

[13] P.K. Baltzer, P.J. Wojtowicz, M. Robbins and E. Lopatin: Phys. Rev. Vol. 151 (1966), p.367.

Google Scholar

[14] F. Yokaichiya, A. Krimmel, V. Tsurkan, I. Margiolaki, P. Thompson, H. N. Bordallo, A. Buchsteiner, N. Stüßer, D. N. Argyriou and A. Loidl: Phys. Rev. B Vol. 79 (2009), p.064423.

Google Scholar