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HomeSolid State PhenomenaSolid State Phenomena Vol. 170Phase Relation of FeS2-VS2 System and New Phase of...

Phase Relation of FeS₂-VS₂ System and New Phase of Defect Troilite Structure

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Abstract:

A large defective troilite (Fe0.9V0.1)0.82S is prepared by a sealed silica-tube method at 800oC and characterized by a powder X-ray diffraction method and using a magnetic property measurement system. The crystal structures of a defective troilite and non defective troilite are analyzed by Rietveld method. The large defect enhances the Fe-Fe pairing and suppresses the waving of Fe-chain along c-direction. The antiferromagnetic property is observed on both troilites. The spin-flip transition temperature of the large defective troilite is 9K.

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Solid State Phenomena (Volume 170)

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92-96

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https://doi.org/10.4028/www.scientific.net/SSP.170.92

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Online since:

April 2011

Authors:

Yoshihisa Miyata, Koya Hayashi, Genta Sakane, Takaaki Arimoto, Yasuhiro Katayama, Mamoru Shimakawa

Keywords:

Crystal Structure, Defect, FeS, Magnetic Property, Phase Relation, Troilite

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. I. Matveenko, Int.J. Mod. Phys. B, Vol. 23 (2009), p.4297.

[2] Y. Kamihara, H. Hiramatsu, M. Hirano, R. Kawamura, H. Yanagi, T. Kamiya and H. Hosono, J. Am. Chem. Soc., Vol. 128 (2006), p.10012.

DOI: 10.1021/ja063355c

[3] B. Predel, Phase equilibria of binary alloys, p.1103, (Springer-Verlag, Berlin 2003).

[4] B.J. Skinner, R.C. Erd and F.S. Grimaldi, Am. Mineral., Vol. 49 (1964), p.543.

[5] A.V. Powell, P. Vaqueiro, K.S. Knight, L.C. Chapon and R.D. Sanchez, Phys. Rev. B, Vol. 70 (2004), pp.014415-1.

[6] N. Morimoto, A. Gyobu, H. Mukaiyama and E. Izawa, Econ. Geol. Bull. Soc. Econ. Geol., Vol. 70 (1975), p.824.

[7] H.E. King Jr. and C.T. Prewitt, Acta Cryst., B, Vol. 38 (1982) , P. 1877.

[8] M. Tokonami, K. Nishiguchi and N. Morimoto, Am. Mineral., Vol. 57 (1972) , p.1066.

[9] K. Adachi, Solid State Phys., Vol. 3, (1968) p.446. (Japanese journal).

[10] F. Keller-Besrest and G. Collin, J. Solid State Chem., Vol. 84 (1990), p.211.

[11] F. Keller-Besrest and G. Collin,J. Solid State Chem., Vol. 84 (1990), p.194.

[12] Y. Oka, K. Kosuge and S. Kachi, J. Solid State Chem., Vol. 23 (1978), p.11.

[13] Y. Oka, K. Kosuge and S. Kachi, Mater. Res. Bull., Vol. 12 (1977), p.1117.

[14] Y. Oka, K. Kosuge and S. Kachi, Mater. Res. Bull., Vol. 15 (1980), p.521.

[15] H. Wada, Bull. Chem. Soc. Jpn., Vol. 52 (1979) , p.2918.

[16] H. Nozaki and H. Wada. J. Solid State Chem., Vol. 47 (1983), p.69.

[17] F. I zumi and K. Momma, Solid State Phenom., Vol. 130 (2007), p.15.

[18] K. Momma and F. Izumi, J. Appl. Crystallogr. Vol. 41 (2008), p.653.

[19] J.L. Horwood, M.G. Townsend and A.H. Webster, J. Solid State Chem., Vol. 17 (1976), p.34.

[20] H. Nakazawa and N. Morimoto, Mater. Res. Bull., Vol. 6 (1971), p.345.